Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-19T08:17:37.290Z Has data issue: false hasContentIssue false

Oxidation of ion beam synthesised embedded indium nanoclusters in silica

Published online by Cambridge University Press:  22 February 2011

P. Santhana Raman
Affiliation:
Materials Science Centre, Department of Nuclear Physics, University of Madras, Chennai, 600025, India Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
K. G.M. Nair*
Affiliation:
Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
A. Rath
Affiliation:
Institute of Physics, Sachivalaya Marg, Bhubaneswar, 751 005, India
P. V. Satyam
Affiliation:
Institute of Physics, Sachivalaya Marg, Bhubaneswar, 751 005, India
B. K. Panigrahi
Affiliation:
Materials Science Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, 603102, India
V. Ravichandran
Affiliation:
Materials Science Centre, Department of Nuclear Physics, University of Madras, Chennai, 600025, India
Get access

Abstract

The paper discusses the results of a study on the formation of indium oxide nanoclusters in silica samples implanted with high energy indium ions. Trace quantities of indium oxide were found on as-implanted samples. On annealing in vacuum/oxygen atmosphere significant increase in the quantity of indium oxide phase was observed. A mechanism is proposed for the formation of indium oxide and is mainly attributed to the reaction of metallic indium with the oxygen released from the silica matrix by ballistic process. During annealing in oxygen atmosphere the oxygen diffusing into the silica also plays a role in the oxidation of indium NCs.

Type
Research Article
Copyright
© EDP Sciences, 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Granqvist, C., Appl. Phys. A 57, 19 (1993) CrossRef
Takada, T., Suzuki, K., Nakane, M., Sens. Actuat. B 13-14, 404 (1993) CrossRef
Cheng, G., Stern, E., Guthrie, S., Reed, M.A., Klie, R., Hao, Y., Meng, G., Zhang, L., Appl. Phys. A 85, 233 (2006) CrossRef
Kim, S.P., Lee, T.H., Lee, D.U., Kim, E.K., Koo, H.M., Cho, W.J., Kim, Y.H., Curr. Appl. Phys. 9, S43 (2009) CrossRef
Cheng, D.D., Zheng, M.J., Yao, L.J., He, S.H., Ma, L., Shen, W.Z., Kong, X.Y., Nanotechnology 20, 425302 (2009) CrossRef
Zheng, M., Zhang, L., Zhang, X., Zhang, J., Li, G., Chem. Phys. Lett. 334, 298 (2001) CrossRef
Meldrum, A., Haglund Jr, R.F.., L.A. Boatner, C.W. White, Adv. Mater. 13, 1431 (2001) 3.0.CO;2-Z>CrossRef
Maurizio, C., Nucl. Instrum. Meth. Phys. Res. B 218, 396 (2004) CrossRef
Saravanan, K., Panigrahi, B.K., Amirthapandian, S., Kalavathi, S., Srivastava, A.K., Nair, K.G.M., J. Nanosci. Nanotechnol. 9, 5523 (2009) CrossRef
Gonella, F., Nucl. Instrum. Meth. Phys. Res. B 166-167, 831 (2000) CrossRef
Caccavale, F., Pramana 50, 653 (1998) CrossRef
Sakurai, Y., J. Non-Cryst. Solids 271, 218 (2000) CrossRef
Kim, K., Suh, M.S., Kim, T.S., Youn, C.J., Suh, E.K., Shin, Y.J., Lee, K.B., Lee, H.J., An, M.H., Lee, H.J., Ryu, H., Appl. Phys. Lett. 69, 3908 (1996) CrossRef
Santhana Raman, P., Nair, K.G.M., Kesavamoorthy, R., Panigrahi, B.K., Dhara, S., Ravichandran, V., Appl. Phys. A 87, 709 (2007) CrossRef
King, P.D.C., Veal, T.D., Fuchs, F., Wang, Ch.Y., Payne, D.J., Bourlange, A., Zhang, H., Bell, G.R., Cimalla, V., Ambacher, O., Egdell, R.G., Bechstedt, F., McConville, C.F., Phys. Rev. B. 79, 205211 (2009) CrossRef
Kayanuma, Y., Phys. Rev. B 38, 9797 (1988) CrossRef
Hamberg, I., Granqvist, C.G., J. Appl. Phys. 60, R123 (1986) CrossRef
Amekura, H., Plaksin, O.A., Kishimoto, N., Buchal, Ch., Surf. Coat. Technol. 201, 8215 (2007) CrossRef
Williams, E.L., J. Am. Ceram. Soc. 48, 190 (1965) CrossRef
Hosono, H., Imagawa, H., Nucl. Instrum. Meth. Phys. Res. B 91, 510 (1994) CrossRef
O. Knacke, O. Kubaschewski, K. Hesselmann, Thermo-chemical Properties of Inorganic Substances, 2nd edn. (Springer, Berlin, 1991)
Hosono, H., Jpn J. Appl. Phys. 32, 3892 (1993) CrossRef
Hsieh, H., Rubia, T.D., Averback, R.S., Phys. Rev. B 40, 9986 (1989) CrossRef
Cattaruzza, E., Nucl. Instrum. Meth. Phys. Res. B 169, 141 (2000) CrossRef
Ren, F., Jiang, C.Z., Fu, D.J., Fu, Q., Jpn J. Appl. Phys. 44, 8512 (2005) CrossRef