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Synthesis of solid-state complex organic molecules through accretion of simple species at low temperatures

Published online by Cambridge University Press:  12 October 2020

D. Qasim Open the ORCID record for D. Qasim [Opens in a new window] ,
G. Fedoseev ,
K.-J. Chuang Open the ORCID record for K.-J. Chuang [Opens in a new window] ,
V. Taquet ,
T. Lamberts ,
J. He ,
S. Ioppolo ,
E. F. van Dishoeck Open the ORCID record for E. F. van Dishoeck [Opens in a new window]  and
H. Linnartz Open the ORCID record for H. Linnartz [Opens in a new window]
D. Qasim
Affiliation:
Laboratory for Astrophysics, Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands email: dqasim@strw.leidenuniv.nl
G. Fedoseev
Affiliation:
INAF–Osservatorio Astrofisico di Catania, via Santa Sofia 78, 95123 Catania, Italy
K.-J. Chuang
Affiliation:
Laboratory for Astrophysics, Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands email: dqasim@strw.leidenuniv.nl Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands
V. Taquet
Affiliation:
INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Florence, Italy
T. Lamberts
Affiliation:
INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Florence, Italy
J. He
Affiliation:
Laboratory for Astrophysics, Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands email: dqasim@strw.leidenuniv.nl
S. Ioppolo
Affiliation:
School of Electronic Engineering and Computer Science, Queen Mary University of London, Mile End Road, London E1 4NS, UK
E. F. van Dishoeck
Affiliation:
Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands
H. Linnartz
Affiliation:
Laboratory for Astrophysics, Leiden Observatory, Leiden University, PO Box 9513, NL–2300 RA Leiden, the Netherlands email: dqasim@strw.leidenuniv.nl
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Abstract

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Complex organic molecules (COMs) have been detected in the gas-phase in cold and lightless molecular cores. Recent solid-state laboratory experiments have provided strong evidence that COMs can be formed on icy grains through ‘non-energetic’ processes. In this contribution, we show that propanal and 1-propanol can be formed in this way at the low temperature of 10 K. Propanal has already been detected in space. 1-propanol is an astrobiologically relevant molecule, as it is a primary alcohol, and has not been astronomically detected. Propanal is the major product formed in the C2H2 + CO + H experiment, and 1-propanol is detected in the subsequent propanal + H experiment. ALMA observations towards IRAS 16293-2422B are discussed and provide a 1-propanol:propanal upper limit of < 0.35–0.55, which are complemented by computationally-derived activation barriers in addition to the performed laboratory experiments.

Keywords

astrochemistryastrobiologymethods: laboratorytelescopesISM: abundancesISM: atomsISM: clouds(ISM:) dustextinctionISM: molecules
Type
Contributed Papers
Information
Proceedings of the International Astronomical Union , Volume 15 , Symposium S350: Laboratory Astrophysics: From Observations to Interpretation , April 2019 , pp. 46 - 50
Copyright
© International Astronomical Union 2020

Footnotes

†

Present address: Laboratory Astrophysics Group of the Max Planck Institute for Astronomy at the Friedrich Schiller University Jena, Institute of Solid State Physics, Helmholtzweg 3, D-07743 Jena, Germany

References

Boogert, A. C. A., Gerakines, P. A., & Whittet, D. C. 2015, ARA&A, 53, 541 CrossRefGoogle Scholar
Chuang, K.-J., Fedoseev, G., Ioppolo, S., van Dishoeck, E. F., & Linnartz, H. 2016, MNRAS, 455, 1702 CrossRefGoogle Scholar
Cuppen, H. M. & Herbst, E. 2007, ApJ, 668, 294 CrossRefGoogle Scholar
Fuchs, G. W., Cuppen, H. M., Ioppolo, S., Romanzin, C., Bisschop, S. E., Andersson, S., van Dishoeck, E. F., & Linnartz, H. 2009, A&A, 505, 629 Google Scholar
Herbst, E. & van Dishoeck, E. F. 2009, ARA&A, 47, 427 CrossRefGoogle Scholar
Ioppolo, S., Fedoseev, G., Lamberts, T., Romanzin, C., & Linnartz, H. 2013, Rev. Sci. Instrum., 84, 073112 CrossRefGoogle Scholar
Lykke, J. M., Coutens, A., Jørgensen, J. K., Van der Wiel, M. H. D., Garrod, R. T., Müller, H. S. P., Bjerkeli, P., Bourke, T. L., Calcutt, H., Drozdovskaya, M. N., & Favre, C. 2017, A&A, 597, A53 Google Scholar
Qasim, D., Fedoseev, G., Lamberts, T., Chuang, K.-J., He, J., Ioppolo, S., Kästner, J., & Linnartz, H. 2019a, ACS Earth and Space Chemistry, 3, 986 CrossRefGoogle Scholar
Qasim, D., Fedoseev, G., Chuang, K.-J., Taquet, V., Lamberts, T., He, J., Ioppolo, S., van Dishoeck, E. F., & Linnartz, H. 2019b, A&A, 627, A1 Google Scholar
Soma, T., Sakai, N., Watanabe, Y., & Yamamoto, S. 2018, ApJ, 854, 116 CrossRefGoogle Scholar
Watanabe, N. & Kouchi, A. 2002, ApJL, 571, L173 CrossRefGoogle Scholar
Zaverkin, V., Lamberts, T., Markmeyer, M. N., & Kästner, J. 2018, A&A, 617, A25 Google Scholar