Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-17T21:36:17.116Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of Fullerols from an Aqueous Acid Method

Published online by Cambridge University Press:  25 February 2011

Long Y. Chiang ,
John. W. Swirczewski ,
Chang S. Hsu ,
S. K. Chowdhury ,
Steve Cameron  and
Andkathy Creegan
Long Y. Chiang
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
John. W. Swirczewski
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
Chang S. Hsu
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
S. K. Chowdhury
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
Steve Cameron
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
Andkathy Creegan
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
Get access

Abstract

An efficient aqueous acid chemistry for the preparation of fullerols, consisting of 14-15 hydroxyl moieties in an average structure, from C60 molecules is described.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 270: Symposium M – Novel Forms of Carbon , 1992 , 241
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES AND NOTES

1. Kratschmer, W., Lamb, L. D., Fostiropoulos, K. and Huffman, D. R., Nature, 1990, 347, 354.CrossRefGoogle Scholar
2. Haufler, R. E., Conceicao, J., Chibante, L. P. F., Chai, Y., Byrne, N. E., Flanagan, S., Haley, M. M., O'Brien, S. C., Pan, C., Xiao, Z., Billups, W. E., Ciufolini, M. A., Hauge, R. H., Margrave, J. L., Wilson, L. J., Curl, R. F. and Smalley, R. E., J. Phys. Chem., 1990, 94, 8634.CrossRefGoogle Scholar
3. Selig, H., Lifshitz, C., Peres, T., Fischer, J. E., McGhie, A. R., Romanow, W. J., McCauley, J. P. Jr. and Smith, A. B., J. Am. Chem. Soc., 1991, 113, 5475; J. H. Holloway, E. G. Hope, R. Taylor, G. J. Langley, A. G. Avent, J. T. Dennis, J. P. Hare, H. W. Kroto, D. R. M. Walton, J. Chem. Soc., Chem. Commun. 1991, 9666.CrossRefGoogle Scholar
4. Wood, J. M., Kahr, B., Hoke, S. H., Dejarme, L., Cooks, R. G. and Ben-Amotz, D., J. Am. Chem. Soc., 1991, 113, 5907; F. Diederich, R. Ettl, Y. Rubin, R. L. Whetten, R. Beck, M. Alvarez, S. Anz, D. Sensharma, F. Wudl, K. Khemani and A. Koch, Science, 1991, 252, 548.CrossRefGoogle Scholar
5. Bausch, J. W., Prakash, G. K. S. and Olah, G. A., J. Am. Chem. Soc., 1991, 113, 3205.CrossRefGoogle Scholar
6. Hawkins, J. M., Acc. Chem. Res., 1992, 25, 150.CrossRefGoogle Scholar
7. Krusic, P. J., Wasserman, E., Keizer, P. N., Morton, J. R. and Preston, K. F., Science, 1991, 254, 1183.CrossRefGoogle Scholar
8. Olah, G. A., Bucsi, I., Lambert, C., Aniszfeld, R., Trivedi, N. J., Sensharma, D. K. and Prakash, G. K. S., J. Am. Chem. Soc., 1991, 113, 9385; F. N. Tebbe, J. Y. Becker, D. B. Chase, L. E. Firment, E. R. Holler, B. S. Malone, P. J. Krusic and E. Wasserman, J. Am. Chem. Soc., 1991, 113, 9900.CrossRefGoogle Scholar
9. Suzuki, T., Li, Q., Khemani, K. C., Wudl, F. and Almarsson, O., Science, 1991, 254, 1186.CrossRefGoogle Scholar
10. Chiang, L. Y., Upasani, R., Swirczewski, J. W. and Creegan, K., Mar. Res. Soc. Symp. Proc., 1992, 247, 285.CrossRefGoogle Scholar
11. The fullerol sample was dissolved in H20 and filtered through celite prior to the mass spectrum measurement. 12. IR spectrum of 2 (KBr) U)max 3434, 2938, 1733 (C=O), 1629, 1411, and I162(br) cm−1. IR spectrum of 3 (KBr) Umax 3422, 2927, 2855, 1727 (C=O), 1613, 1503(w), 1450, and 1080(br) cm−1.Google Scholar
13. Beavis, R. C. and Chait, B. T., Rapid Commun., Mass Spect., 1989, 3, 233.CrossRefGoogle Scholar
14. Beavis, R. C. and Chait, B. T., Anal. Chem., 1990, 62, 1836.CrossRefGoogle Scholar