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Synthesis and Spectroellipsometric Characterization of Y2O3-stabilized ZrO2-Au Nanocomposite Films for Smart Sensor Applications

Published online by Cambridge University Press:  01 February 2011

George Sirinakis ,
Richard Sun ,
Rezina Siddique ,
Harry Efstathiadis ,
Michael A. Carpenter  and
Alain E. Kaloyeros
George Sirinakis
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany-State University of New York, Albany, NY 12203, USA
Richard Sun
Affiliation:
Sun International Inc, Acton, MA 01720, USA
Rezina Siddique
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany-State University of New York, Albany, NY 12203, USA
Harry Efstathiadis
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany-State University of New York, Albany, NY 12203, USA
Michael A. Carpenter
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany-State University of New York, Albany, NY 12203, USA
Alain E. Kaloyeros
Affiliation:
College of Nanoscale Science and Engineering, The University at Albany-State University of New York, Albany, NY 12203, USA
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Abstract

Noble metal nanoparticles exhibit significant potential in all-optical, smart-sensing applications due to their unique optical properties. In particular, gold (Au) nanoparticles exhibit a strong surface plasmon resonance (SPR) band, the spectral position and shape of which depends on the size, shape, and density of the nanoparticles and the physical and chemical properties of surrounding environment. Embedding the nanoparticles in an yttria-stabilized zirconia (YSZ) matrix is believed to expand their range of operation to temperatures above 500 °C. YSZ is a material that has been proven suitable for optical applications due to its high refractive index, low absorption coefficient and high transparency in the visible and infrared regions. Thus, its use as a base platform for nanocomposite thin films is expected to provide significant benefits in the development of harsh environment multifunctional sensors.

In this work YSZ-Au nanocomposite films were synthesized from a YSZ and a Au target by the radio frequency magnetron co-sputtering technique in combination with a post-deposition annealing treatment in an argon atmosphere, with the annealing temperature being varied from 500–1000 °C in steps of 100 °C. The microstructure and the optical properties of the resulting films were characterized by x-ray diffraction spectroscopy, scanning electron microscopy and spectroscopic ellipsometry. Results on the effect of the Au particle size on the real and the imaginary part of the refractive index of the nanostructured composites are presented. Future smart sensor systems utilizing these multifunctional material sets for harsh environment sensing applications will likewise be outlined.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 830: Symposium D – Materials and Processes for Nonvolatile Memories , 2004 , DD10.10
Copyright
Copyright © Materials Research Society 2005

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References

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