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Self-assembled Ordered Energetic Composites of CuO Nanorods and Nanowells and Al Nanoparticles with High Burn Rates

Published online by Cambridge University Press:  26 February 2011

Senthil Subramanium ,
Shameem Hasan ,
Shantanu Bhattacharya ,
Yuanfang Gao ,
Steve Apperson ,
Maruf Hossain ,
Rajesh Shende ,
Shubhra Gangopadhyay ,
Paul Redner  and
Deepak Kapoor
...Show all authors
Senthil Subramanium
Affiliation:
shender@missouri.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Shameem Hasan
Affiliation:
she99@mizzou.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Shantanu Bhattacharya
Affiliation:
sbn74@mizzou.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Yuanfang Gao
Affiliation:
ygfff@mizzou.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Steve Apperson
Affiliation:
sja895@mizzou.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Maruf Hossain
Affiliation:
hossainma@missouri.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Rajesh Shende
Affiliation:
shender@missouri.edu, University of Missouri, Electrical and Computer Engineering, 243, Engineering Building West, Columbia, MO, 65211, United States, 573-673-3669, 573-882-0397
Shubhra Gangopadhyay
Affiliation:
gangopadhyays@missouri.edu, University of Missouri, Columbia, Electrical and Computer Engineering, United States
Paul Redner
Affiliation:
paul.redner@us.army.mil, US army ARDEC, Picatinny,NJ, United States
Deepak Kapoor
Affiliation:
deepak.kapoor@us.army.mil, US army ARDEC, Picatinny,NJ, United States
Steven Nicolich
Affiliation:
steven.nicolich@us.army.mil, US army ARDEC, Picatinny,NJ, United States
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Abstract

Current approaches of mixing fuel and oxidizer nanoparticles or adding fuel nanoparticles to oxidizer gel lead to an overall reduced interfacial area of contact between them and thus, limit their burn rates severely. We have developed an approach of self-assembling fuel nanoparticles around an oxidizer matrix using a monofunctional polymer, poly(4)-vinyl pyridine (P4VP). The polymer has been used to accomplish binding of fuel and oxidizer in a molecularly engineered manner. We use composite of Al-nanoparticles and CuO nanorods for executing this self-assembly. TEM images of this composite confirms the self-assembly of Al-nanoparticles around the oxidizer nanorods. The burn rate of self-assembled composite has been found significantly higher than that of the composite prepared by simple mixing.

Keywords

energetic materialnanostructureself-assembly
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 896: Symposium H – Multifunctional Energetic Materials , 2005 , 0896-H01-05
Copyright
Copyright © Materials Research Society 2006

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