Published online by Cambridge University Press: 28 February 2011
Experiments are described which illustrate that resonant neutralization of mass-selected cluster ions provides a universal method to produce neutral mass-selected metal cluster beams. Specifically, lead cluster ions, Pbn+ with n d 12, were neutralized by charge exchange reactions in atomic sodium and other target materials. Absolute charge exchange cross sections are on the order of 40 Å2 and up to 30% of the incident ions were neutralized. Possible fragmentation of the clusters associated with neutralization was investigated by translational spectroscopy. No indication of fragmentation was found for resonant electron transfer with atomic Na as target gas.. Thus, neutral metal cluster beams with ultra-narrow size distribution are produced. Deposition of such size-selected metal clusters on substrates opens new perspectives in materials science.