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Microcontact Printing via a Polymer-Induced Liquid-Precursor (PILP) Process

Published online by Cambridge University Press:  01 February 2011

Yi-yeoun Kim  and
Laurie B. Gower
Yi-yeoun Kim
Affiliation:
Department of Materials Science and Engineering, University of Florida, Gainesville, FL, 32611, USA
Laurie B. Gower
Affiliation:
Department of Materials Science and Engineering, University of Florida, Gainesville, FL, 32611, USA
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Abstract

Our biomimetic approach for patterned crystallization is based on the combination of the Micro-Contact Printing technique and a novel mineralization process, called the Polymer-Induced-Liquid-Precursor (PILP) process, which enables the deposition of mineral films under low-temperature and aqueous-based conditions. We demonstrate that a liquid-phase mineral precursor is deposited onto specific areas templated with self-assembled monolayers of alkanethiolate on gold, and then the patterned calcitic films grow under constrained conditions via transformation of the PILP phase, leading to control over the location and morphology of calcitic films.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 724: Symposium N – Biological and Biomimetic Materials Properties to Function , 2002 , N9.4
Copyright
Copyright © Materials Research Society 2002

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References

1. Gower, L.A. and Tirrell, D.A., J. Cryst. Growth 191, 153–160 (1998).Google Scholar
2. Mann, S., J. Mater. Chem. 5, 935–946 (1995).Google Scholar
3. Mann, S., Archibald, D.D., Didymus, J.M., Douglas, T., Heywood, B.R., Meldrum, F.C., and Reeves, N.J., Science 261, 1286–1292 (1993).Google Scholar
4. Olszta, M. J., Douglas, E.P., Gower, L.B., Calcified Tissue International (submitted).Google Scholar
5. Gower, L.B. and Odom, D.J., J. Cryst. Growth 210, 719–734 (2000).Google Scholar
6. Gower, L., “The influence of polyaspartate additive on the growth and morphology of calcium carbonate crystals”, Dissertation, University of Massachusetts- Amherst (1997).Google Scholar
7. Olszta, M. J., Douglas, E.P., Gower, L.B., Connective Tissue Research (in Press).Google Scholar
8. Aizenberg, J., J. Cryst. Growth 211, 143–148 (2000).Google Scholar
9. Aizenberg, J., Black, A.J., and Whitesides, G.H., J. Am. Chem. Soc. 121, 4500–4509 (1999).Google Scholar
10. Aizenberg, J., Black, A.J., and Whitesides, G.M., Nature 398, 495–498 (1999).Google Scholar
11. Hosoda, N. and Kato, T., Chem. Mat. 13, 688–693 (2001).Google Scholar
12. Xu, G.F., Yao, N., Aksay, I.A., and Groves, J.T., J. Am. Chem. Soc. 120, 11977–11985 (1998).Google Scholar
13. Xia, Y.N. and Whitesides, G.M., Annu. Rev. Mater. Sci. 28, 153–184 (1998).Google Scholar