Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-18T09:06:12.597Z Has data issue: false hasContentIssue false
  • English
  • Français

Ammonia RF-Plasma on PTFE Surfaces: Quantification of the Species Created on the Surface by Vapor - Phase Chemical Derivatization

Published online by Cambridge University Press:  15 March 2011

Chevallier P. ,
Castonguay M. ,
Mantovani D.  and
Laroche G.
Chevallier P.
Affiliation:
Quebec Biomaterials Institute, 10 rue de l'Espinay, Quebec City, (Qc) G1L 3L5, Canada
Castonguay M.
Affiliation:
Quebec Biomaterials Institute, 10 rue de l'Espinay, Quebec City, (Qc) G1L 3L5, Canada
Mantovani D.
Affiliation:
Quebec Biomaterials Institute, 10 rue de l'Espinay, Quebec City, (Qc) G1L 3L5, Canada Department of Materials Engineering, Laval University, Quebec City, (Qc) G1K 7P4, Canada
Laroche G.
Affiliation:
Quebec Biomaterials Institute, 10 rue de l'Espinay, Quebec City, (Qc) G1L 3L5, Canada Department of Surgery, Laval University, Quebec City, (Qc) G1K 7P4, Canada
Get access

Abstract

A cylindrically-configured plasma treatment system in Radio Frequency Glow Discharges fed with ammonia was used with the aim of modifying the internal surface of ePTFE arterial prostheses to improve their biocompatibility. In order to understand the effects of this treatment on the PTFE polymer surface, we have first realized RF-plasma treatment experiments on PTFE films. Preliminary XPS analyses have shown that about 15% of the surface atoms were substituted by nitrogen (N/C ratio of 0.3) whereas the F/C ratio decreased from 2 to 0.6, therefore leading to the conclusion that several chemical species are created onto the surface upon an ammonia plasma treatment. As X-Ray Photoelectron Spectroscopy (XPS) analysis does not allow the direct determination of the nature of the N-species grafted on the surface (chemical shifts are not different enough), vapor phase chemical derivatization was carried out on PTFE films to quantify the concentration of these new surface moities grafted on the polymer surface.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 662: Symposia LL/MM/NN/OO – Biomaterials for Drug Delivery & Tissue Engineering , 2000 , MM1.7
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Mantovani, D., Castonguay, M., Pageau, J. F., Fiset, M. and Laroche, G., Plasma and Polymers, 4, 207 (1999).Google Scholar
2. Mantovani, D., Castonguay, M., Pageau, J. F., Fiset, M. and Laroche, G., Mat. Res. Soc. Symp. Proc., 544, 21(1999).Google Scholar
3. Hammond, J., Polymer Preprints, 21, 149 (1980).Google Scholar
4. Sutherland, I., Sheng, E., Brewis, D. and Heath, R.. J. Mater. Chem., 4, 683 (1994).Google Scholar
5. Ameen, A., Ward, R., Short, R., Beamson, G. and Briggs, D., Polymer, 34, 1795 (1993).Google Scholar
6. Chilkoti, A., Ratner, B., Surface and Interface Analysis, 17, 567 (1991).Google Scholar
7. Dickie, R., Hammond, J., Vries, J. de, Holubka, J., Anal.Chem., 54, 2045 (1982).Google Scholar
8. Terlingen, J., Brenneisen, L., Super, H., Pijpers, A. P., Hoffman, A. and Feijen, J., J. Biomat. Sci. Polymer Edn., 4, 165 (1993).Google Scholar
9. Everhart, D. and Reilley, C., Anal. Chem., 53, 665 (1981).Google Scholar
10. Favia, P., Stendardo, M. and d'Agostino, R., Plasmas and Polymers, 1, 91 (1996).Google Scholar
11. Nakayama, Y., Takahagi, T., Soeda, F., J. Polym. Sci.:Part A:Polym. Chem., 26, 559 (1988).Google Scholar
12. Everhart, D. and Reilly, C., Surface and Interface Analysis, 3, 126 (1981).Google Scholar
13. Popat, R., Sutherland, I. and Sheng, E., J. Mater. Chem., 5, 713 (1995).Google Scholar
14. Chilkoti, A., B, B. Ratner and Briggs, D., Chem. Mater., 3, 51 (1991).Google Scholar
15. Griesser, H. J., Materials Forum, 14, 192 (1990).Google Scholar