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Auger Electron Analysis of Oxides Grown on a Dilute Zirconium/Nickel Alloy

Published online by Cambridge University Press:  22 February 2011

R. A. Ploc
Affiliation:
Atomic Energy of Canada Limited, Chalk River Nuclear Laboratories, Chalk River, Ontario, K0J 1J0 Canada
R. D. Davidson
Affiliation:
Atomic Energy of Canada Limited, Chalk River Nuclear Laboratories, Chalk River, Ontario, K0J 1J0 Canada
J. A. Roy
Affiliation:
Atomic Energy of Canada Limited, Chalk River Nuclear Laboratories, Chalk River, Ontario, K0J 1J0 Canada
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Abstract

Auger electron analysis of oxides grown at 573 K in dried oxygen on the matrix and on precipitates in a 0.5 wt% Ni in zirconium alloy, is part of a larger program to study the effect of second phase particles on the oxidation and hydriding behaviour of Zircaloy-2. The alloy consisted of a zirconium matrix containing randomly distributed Zr2Ni precipitates of up to 10 μM in diameter. Oxidation simultaneously proceeded about the whole periphery of the precipitate and after approximately 50 days exposure was completely oxidized and of nearly uniform composition. The chemical structure of the oxides grown on the matrix and on the free and internal surfaces of the precipitate were determined as a function of depth in the oxide film.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

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References

1 Ploc, R.A., J. of Nucl. Mater., 82, 411 (1979).Google Scholar
2 Ploc, R.A., J. of Nucl. Mater., 91, 322 (1980).Google Scholar
3 Cox, B., in Advances in Corrosion Science and Technology, edited by Fontana, M.G. and Staehle, R.W. (Plenum Press, New York and London, Vol.5, 1976) p.173.Google Scholar
4 Ramasubramanian, N. in Atomic Energy of Canada Limited report, AECL-3082, Chalk River Nuclear Laboratories, March 1968.Google Scholar
5 Ramasubramanian, N., J. of Nucl. Mater., 55, 134 (1975).Google Scholar
6 Urbanic, V.F. and Cox, B., in press, Canadian Met. Quarterly, presented at 23rd Annual CIM conference, Quebec City, Aug.1984.Google Scholar
7 Chemelle, P., Knorr, D.B., Van der Sande, J.B. and Pelloux, R.M., J. Nucl. Mater., 113, 58 (1983).Google Scholar
8 Ploc, R.A. and Davidson, R.D., in press, presented at 17th Annaul Technical Meeting of the International Metallographic Society, Philadelphia, July 1984.Google Scholar