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Thermodynamics of the tetragonal-to-monoclinic phase transformation in fine and nanocrystalline yttria-stabilized zirconia powders

Published online by Cambridge University Press:  31 January 2011

Arun Suresh ,
Merrilea J. Mayo  and
Wallace D. Porter
Arun Suresh
Affiliation:
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802
Merrilea J. Mayo
Affiliation:
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802
Wallace D. Porter
Affiliation:
High Temperature Materials Laboratory, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
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Abstract

The current study uses high-temperature differential scanning calorimetry to document the shift in phase-transformation temperature with particle size throughout a series of alloys in the zirconia–yttria system (0–1.5 mol% yttria). The tetragonal-to-monoclinic (T→M) phase-transformation temperature is seen to vary inversely with particle size. It is shown that a simple thermodynamic approach first proposed by Garvie predicts this inverse linear relationship. Subsequent determination of the key thermodynamic parameters therein (e.g., the surface and volume free energy, enthalpy, and entropy changes involved in the phase transformation) allows a complete predictive equation for the T→M phase transformation in the yttria–zirconia system to be developed as a function of particle size and yttria dopant level. The yttria–zirconia phase diagram is then redrawn with grain size as a third variable. It should be stressed that the current analysis is valid for particulate systems only; a parallel paper tackles the problem for fine-grained yttria–zirconia solids, where the approach is similar, but additional strain energy terms come into play.

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Articles
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Journal of Materials Research , Volume 18 , Issue 12 , December 2003 , pp. 2912 - 2921
Copyright
Copyright © Materials Research Society 2003

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