Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-17T19:45:49.116Z Has data issue: false hasContentIssue false

Microstructure and wear resistance of Cuss-toughened Cr5Si3/CrSi metal silicide alloys

Published online by Cambridge University Press:  03 March 2011

Y.X. Yin
Affiliation:
Laboratory of Laser Materials Processing and Surface Engineering, School of Materials Science and Engineering, Beihang University (formerly Beijing University of Aeronautics and Astronautics), Beijing 100083, People's Republic of China
H.M. Wang*
Affiliation:
Laboratory of Laser Materials Processing and Surface Engineering, School of Materials Science and Engineering, Beihang University (formerly Beijing University of Aeronautics and Astronautics), Beijing 100083, People's Republic of China
*
a)Address all correspondence to this author. e-mail: wanghuaming@263.net
Get access

Abstract

Wear-resistant Cu-based solid-solution-toughened Cr5Si3/CrSi metal silicide alloy with a microstructure consisting of predominantly the dual-phase primary dendrites with a Cr5Si3 core encapsulated by CrSi phase and a small amount of interdendritic Cu-based solid solution (Cuss) was designed and fabricated by the laser melting process using Cr–Si–Cu elemental powder blends as the precursor materials. The microstructure of the Cuss-toughened Cr5Si3/CrSi metal silicide alloy was characterized by optical microscopy, powder x-ray diffraction, and energy dispersive spectroscopy. The Cuss-toughened silicide alloys have excellent wear resistance and low coefficient of friction under room temperature dry sliding wear test conditions with hardened 0.45% C carbon steel as the sliding–mating counterpart.

Type
Articles
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Akinc, M., Meyer, M.K., Kramer, M.J., Thom, A.J., Huebsch, J.J. and Cook, B.: Boron-doped molybdenum silicides for structural applications. Mater. Sci. Eng. A261, 16 (1999).CrossRefGoogle Scholar
2.Sadananda, K., Feng, C.R., Mitra, R. and Deevi, S.C.: Creep and fatigue properties of high temperature silicides and their composites. Mater. Sci. Eng. A261, 78 (1999).Google Scholar
3.Jokisaari, J.R., Bhaduri, S. and Bhaduri, S.B.: Processing of single phase Mo5Si3 by microwave activated combustion synthesis. Mater. Sci. Eng. A323, 478 (2002).CrossRefGoogle Scholar
4.Zhang, L. and Wu, J.: Ti5Si3 and Ti5Si3 based alloys: Alloying behavior, microstructure and mechanical property evaluation. Acta Mater. 46, 3535 (1998).CrossRefGoogle Scholar
5.Liu, C.T., Stringer, J., Mundy, J.N., Horton, L.L. and Angelini, P.: Ordered intermetallic alloys: An assessment. Intermetallics 5, 579 (1997).CrossRefGoogle Scholar
6.Yi, D.Q., Du, R.X. and Cao, Y.: Physical metallurgy of M5Si3-type silicides. Acta Metall. Sin. 37, 1121 2001, in Chinese.Google Scholar
7.Stoloff, N.S.: An overview of powder processing of silicides and their composites. Mater. Sci. Eng. A261, 169 (1999).CrossRefGoogle Scholar
8.Wang, H.M. and Liu, Y.F.: Microstructure and wear resistance of laser clad Ti5Si3/NiTi2 intermetallic composite coating on titanium alloy. Mater. Sci. Eng. A338, 126 (2002).CrossRefGoogle Scholar
9.Petrovic, J.J. and Vasudevan, A.K.: Key developments in high temperature structural silicides. Mater. Sci. Eng. A261, 1 (1999).CrossRefGoogle Scholar
10.Newkirk, J.W. and Hawk, J.A.: Abrasive wear properties of Cr–Cr3Si composites. Wear 251, 1361 (2001).CrossRefGoogle Scholar
11.Cruse, T.A. and Newkirk, J.W.: Evaluation of methods to produce tough Cr3Si based composites. Mater. Sci. Eng. A239(240), 410 (1997).CrossRefGoogle Scholar
12.Chu, F., Thoma, D.J., Mcclellan, K.J. and Peralta, P.: Mo5Si3 single crystals: physical properties and mechanical behavior. Mater. Sci. Eng. A261, 44 (1999).CrossRefGoogle Scholar
13.Duan, G. and Wang, H.M.: High-temperature wear resistance of a laser-clad γ/Cr3Si metal silicide composite coating. Scripta Mater. 46, 107 (2002).CrossRefGoogle Scholar
14.Wang, H.M. and Duan, G.: Microstructure and wear resistance of a laser clad reinforced Cr3Si metal silicide composite coating. Mater. Sci. Eng. A336, 117 (2002).CrossRefGoogle Scholar
15.Liu, C.T., Zhu, J.H., Brady, M.P. and Mckamey, C.G.: Oxidation resistance and mechanical properties of Laves phase reinforced Cr in-situ composites. Intermetallics 8, 1119 (2000).CrossRefGoogle Scholar
16.Sauthoff, G.: Multiphase intermetallic alloys for structural applications. Intermetallics 8, 1101 (2000).CrossRefGoogle Scholar
17.Schneibel, J.H., Liu, C.T., Easton, D.S. and Carmeichael, C.A.: Microstructure and mechanical properties of Mo–Mo3Si–Mo5SiB2 silicides. Mater. Sci. Eng. A261, 78 (1999).CrossRefGoogle Scholar
18.Tu, J.P., Meng, L. and Liu, M.S.: Friction and wear behavior of Cu–Fe3Al powder metallurgical composites in dry sliding. Wear 220, 72 (1998).CrossRefGoogle Scholar
19.Dehm, G., Medres, B., Shepeleva, L., Scheu, C., Bamberger, M., Mordike, B.L., Mordike, S., Ryk, G., Halperin, G. and Etsion, I.: Microstructure and tribological properties of Ni-based claddings on Cu substrates. Wear 225, 18 (1999).CrossRefGoogle Scholar
20.Tu, J.P., Rong, W., Guo, S.Y. and Yang, Y.Z.: Dry sliding wear behavior of in situ Cu–TiB2 nanocomposites against medium carbon steel. Wear 255, 832 (2003).CrossRefGoogle Scholar
21.Zhan, Y.Z. and Zhang, G.D.: The effect of interfacial modifying on the mechanical and wear properties of SiCp/Cu composites. Mater. Lett. 57, 4583 (2003).CrossRefGoogle Scholar
22.Manna, I., Majumdar, J.D., Chatterjee, U.K. and Nath, A.K.: Laser surface engineering of copper with chromium for enhanced wear resistance. Script. Mater. 35, 405 (1996).CrossRefGoogle Scholar
23.Wang, H.M. and Zhang, L.Y.: China Patent No. 02121496.4, June 26, 2002.Google Scholar
24.Wang, H.M., Luan, D.Y. and Zhang, L.Y.: Microstructure and wear resistance of laser melted W/W2Ni3Si metal silicides matrix in situ composites. Scripta Mater. 48, 1179 (2003).CrossRefGoogle Scholar
25.Wang, H.M. and Duan, G.: Wear and corrosion behavior of laser clad Cr3Si reinforced intermetallic composite coatings. Intermetallics 11, 755 (2003).CrossRefGoogle Scholar