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Fabrication of two-dimensional disordered copper 1,3,5-tricarboxylate film by vapor–solid method

Published online by Cambridge University Press:  29 October 2012

Chunjiao Chen ,
Yue Qi  and
Zhengping Qiao
Chunjiao Chen
Affiliation:
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Yue Qi
Affiliation:
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
Zhengping Qiao*
Affiliation:
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: cesqzp@mail.sysu.edu.cn
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Abstract

Two-dimensional (2D) disordered copper 1,3,5-tricarboxylate film on copper foil was first reported in this paper. In the x-ray powder diffraction pattern of the as-prepared film, there were only two diffraction peaks exist in d value of 6.60 and 3.32 Å, which were correspond to the (400) and (800) diffractions of bulk HKUST-1, respectively. And the d value of 6.60 Å in bulk HKUST-1 is very close to the thickness of one-layered Cu2+ plus one-layered C9H3O63− (6.59 Å). The structure of as-prepared film was proved to be 2D disordered copper 1,3,5-tricarboxylate film. The periodical stacking of Cu2+ and C9H3O63−is perpendicular to the substrate. There is no periodic structure within the layer. Scanning electron microscopy, transmission electron microscope (TEM), high-resolution transmission electron microscope, infrared, Raman, and x-ray photoelectron spectrometer supported this result. This kind of disorder probably also existed in the reported HKUST-1 film that shows strong (400) diffraction in x-ray diffraction (XRD) pattern. This result probably explains why (400) diffraction in XRD pattern of reported synthesized HKUST-1 film is anomalously strong. This strategy is simple. No seed, no pretreated solvothermal mother liquors, and no specific functionalization are required.

Keywords

filmcrystal growthepitaxial
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 22 , 22 November 2012 , pp. 2911 - 2915
Copyright
Copyright © Materials Research Society 2012

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