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Effect of trace Na additions on the hydrogen absorption kinetics of Mg2Ni

Published online by Cambridge University Press:  07 April 2016

Xuan Quy Tran ,
Stuart D. McDonald ,
Qinfen Gu ,
Syo Matsumura  and
Kazuhiro Nogita
Xuan Quy Tran*
Affiliation:
Nihon Superior Centre for the Manufacture of Electronic Materials (NS CMEM), School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia
Stuart D. McDonald
Affiliation:
Nihon Superior Centre for the Manufacture of Electronic Materials (NS CMEM), School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia
Qinfen Gu
Affiliation:
Powder Diffraction Beamline, Australian Synchrotron, Victoria 3168, Australia
Syo Matsumura
Affiliation:
Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoka 819–0395, Japan
Kazuhiro Nogita
Affiliation:
Nihon Superior Centre for the Manufacture of Electronic Materials (NS CMEM), School of Mechanical and Mining Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia
*
a)Address all correspondence to this author. e-mail: xuan.tran@uqconnect.edu.au
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Abstract

It is demonstrated that Na doping can significantly improve the hydriding performance of Mg2Ni under an isobaric-isothermal condition of 2 MPa H2 and 350 °C. This is achieved via an increase of the interphase grain boundary area and density of dislocations as compared to the Na-free material. Significant enrichment of Na+ cations on the alloys' surface coupled with the catalytic effect of metallic Ni are suggested to increase the hydrogen–metal bonding strength facilitating hydrogen adsorption/dissociation. The mechanisms of hydrogen absorption are discussed based on a nucleation and growth theory. Additionally, by means of in situ synchrotron powder x-ray diffraction, the transition of Mg2Ni into the stable Mg2NiH0.3 is observed in real-time.

Keywords

Mghydrogenationenergy storage
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 9 , 14 May 2016 , pp. 1316 - 1327
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Copyright
Copyright © Materials Research Society 2016 

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References

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