Hostname: page-component-78c5997874-t5tsf Total loading time: 0 Render date: 2024-11-19T11:22:45.819Z Has data issue: false hasContentIssue false
  • English
  • Français

High capacity and rate capability of S/3D ordered bimodal mesoporous carbon cathode for lithium/sulfur batteries

Published online by Cambridge University Press:  21 January 2019

Yan Song ,
Jun Ren ,
Guoyan Wu ,
Wulin Zhang ,
Chengwei Zhang  and
Fuxing Yin
Yan Song
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
Jun Ren
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
Guoyan Wu
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
Wulin Zhang*
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
Chengwei Zhang*
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
Fuxing Yin*
Affiliation:
School of Materials Science & Engineering, Hebei University of Technology, Tianjin 300130, China; and Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin 300130, China
*
a)Address all correspondence to these authors. e-mail: cwzhang@hebut.edu.cn
b)e-mail: yinfuxing@hebut.edu.cn
Get access

Abstract

3D ordered bimodal mesoporous carbon (OBMC) with a high specific surface area of 1368.7 m2/g, ordered large mesopores, and small mesopores on the walls is prepared by a surfactant-free rapid method using SiO2 nanosphere arrays as templates. The resulting OBMC is then composited with sulfur to prepare S/OBMC hybrids via a simple solution infiltration method followed by a heat treatment process. In S/OBMC composite, sulfur is uniformly infiltrated inside the 3D hierarchical pores of OBMC. On the basis of this systematic design, the obtained S/OBMC cathode shows a large discharge capacity value of 1590 mA h/g at first cycle and maintains 989 mA h/g after 100 cycles at 0.2 C. Furthermore, at 1 C charge–discharge rate, a reversible discharge capacity of 733 mA h/g after 100 cycles is reached. The extraordinary electrochemical property of S/OBMC derives from the unique bimodal mesoporous structure with large mesopores and small mesopores that can facilitate the mass transfer and strict dissolution of polysulfide species into the electrolyte.

Keywords

mesoporous materials carbonordered bimodal mesoporeslithium/sulfur battery
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 4 , 28 February 2019 , pp. 600 - 607
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ji, X. and Nazar, L.F.: Advances in Li–S batteries. J. Mater. Chem. 20, 9821 (2010).CrossRefGoogle Scholar
Arumugam, M., Yongzhu, F., and Yu-Sheng, S.: Challenges and prospects of lithium–sulfur batteries. Acc. Chem. Res. 46, 1125 (2013).Google Scholar
Ji, X., Lee, K.T., and Nazar, L.F.: A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries. Nat. Mater. 8, 500 (2009).CrossRefGoogle ScholarPubMed
Hassoun, J. and Scrosati, B.: Moving to a solid-state configuration: A valid approach to making lithium–sulfur batteries viable for practical applications. Adv. Mater. 22, 5198 (2010).CrossRefGoogle ScholarPubMed
Vishnuvardhan, T.K., Kulkarni, V.R., Basavaraja, C., and Raghavendra, S.C.: Synthesis, characterization and a.c. conductivity of polypyrrole/Y2O3 composites. Bull. Mater. Sci. 29, 77 (2006).CrossRefGoogle Scholar
Zhang, Y., Bakenov, Z., Zhao, Y., Konarov, A., Doan, T.N.L., Malik, M., Paron, T., and Chen, P.: One-step synthesis of branched sulfur/polypyrrole nanocomposite cathode for lithium rechargeable batteries. J. Power Sources 208, 1 (2012).CrossRefGoogle Scholar
Xu, G.L., Xu, Y.F., Fang, J.C., Peng, X.X., Fu, F., Huang, L., Li, J.T., and Sun, S.G.: Porous graphitic carbon loading ultra high sulfur as high-performance cathode of rechargeable lithium–sulfur batteries. ACS Appl. Mater. Interfaces 5, 10782 (2013).CrossRefGoogle ScholarPubMed
Zhang, C., Zhang, Z., Wang, D., Yin, F., and Zhang, Y.: Three-dimensionally ordered macro-/mesoporous carbon loading sulfur as high-performance cathodes for lithium/sulfur batteries. J. Alloys Compd. 714, 126 (2017).CrossRefGoogle Scholar
Li, X., Tang, R., Hu, K., Zhang, L., and Ding, Z.: Hierarchical porous carbon aerogels with VN modification as cathode matrix for high performance lithium-sulfur batteries. Electrochim. Acta 210, 734 (2016).CrossRefGoogle Scholar
Guo, J., Xu, Y., and Wang, C.: Sulfur-impregnated disordered carbon nanotubes cathode for lithium–sulfur batteries. Nano Lett. 11, 4288 (2011).CrossRefGoogle ScholarPubMed
Duan, X., Han, Y., Huang, L., Li, Y., and Chen, Y.: Improved rate ability of low cost sulfur cathodes by using ultrathin graphite sheets with self-wrapped function as cheap conductive agent. J. Mater. Chem. A 3, 8015 (2015).CrossRefGoogle Scholar
Zuo, P., Zhang, W., Hua, J., Ma, Y., Du, C., Cheng, X., Gao, Y., and Yin, G.: A novel one-dimensional reduced graphene oxide/sulfur nanoscroll material and its application in lithium sulfur batteries. Electrochim. Acta 222, 1861 (2016).CrossRefGoogle Scholar
Zhang, Y., Zhao, Y., Bakenov, Z., Tuiyebayeva, M., Konarov, A., and Chen, P.: Synthesis of hierarchical porous sulfur/polypyrrole/multiwalled carbon nanotube composite cathode for lithium batteries. Electrochim. Acta 143, 49 (2014).CrossRefGoogle Scholar
Cai, T., Zhou, M., Han, G., and Guan, S.: Phenol–formaldehyde carbon with ordered/disordered bimodal mesoporous structure as high-performance electrode materials for supercapacitors. J. Power Sources 241, 6 (2013).CrossRefGoogle Scholar
Li, N., Zheng, M., Feng, S., Lu, H., Zhao, B., Zheng, J., Zhang, S., Ji, G., and Cao, J.: Fabrication of hierarchical macroporous/mesoporous carbons via the dual-template method and the restriction effect of hard template on shrinkage of mesoporous polymers. J. Phys. Chem. C 117, 8784 (2013).CrossRefGoogle Scholar
Zhang, C., Xu, L., Shan, N., Sun, T., Chen, J., and Yan, Y.: Enhanced electrocatalytic activity and durability of Pt particles supported on ordered mesoporous carbon spheres. ACS Catal. 4, 1926 (2014).CrossRefGoogle Scholar
Wen, X.: Three-dimensional hierarchical porous carbon with a bimodal pore arrangement for capacitive deionization. J. Mater. Chem. 22, 23835 (2012).CrossRefGoogle Scholar
Zhang, C., Zhang, Z., Yin, F., Zhang, Y., Mentbayeva, A., Babaa, M-R., Molkenova, A., and Bakenov, Z.: Three-dimensionally ordered macroporous carbon encapsulated ZnO nanoparticles as high-performance anode for lithium-ion batteries. ChemElectroChem 4, 2125 (2017).CrossRefGoogle Scholar
Tian-Yi, M., Lei, L., and Zhong-Yong, Y.: Direct synthesis of ordered mesoporous carbons. Chem. Soc. Rev. 42, 3977 (2012).Google Scholar
He, G., Ji, X., and Nazar, L.: High “C” rate Li–S cathodes: Sulfur imbibed bimodal porous carbons. Energy Environ. Sci. 4, 2878 (2011).CrossRefGoogle Scholar
Dutta, S., Wu, K.C.W., and Kimura, T.: Predictable shrinkage during the precise design of porous materials and nanomaterials. Chem. Mater. 27, 6918 (2015).CrossRefGoogle Scholar
Qiao, W.M., Song, Y., Hong, S.H., Lim, S.Y., Yoon, S.H., Korai, Y., and Mochida, I.: Development of mesophase pitch derived mesoporous carbons through a commercially nanosized template. Langmuir 22, 3791 (2006).CrossRefGoogle ScholarPubMed
Tang, Z., Song, Y., Tian, Y., Liu, L., and Guo, Q.: Pore development of thermosetting phenol resin derived mesoporous carbon through a commercially nanosized template. Mater. Sci. Eng., A 473, 153 (2008).CrossRefGoogle Scholar
Wei, F., Snyder, M.A., Sandeep, K., Pyung-Soo, L., Won Cheol, Y., Mccormick, A.V., Penn, R.L., Andreas, S., and Michael, T.: Hierarchical nanofabrication of microporous crystals with ordered mesoporosity. Nat.Mater. 7, 984 (2008).Google Scholar
Li, Y., Wang, L., Gao, B., Li, X., Cai, Q., Li, Q., Peng, X., Huo, K., and Chu, P.K.: Hierarchical porous carbon materials derived from self-template bamboo leaves for lithium–sulfur batteries. Electrochim. Acta 229, 352 (2017).CrossRefGoogle Scholar
Zhang, Y., Hu, G., O’Hare, D., Wu, D., and Sun, Y.: Partially graphitized carbon filaments from as-synthesized silica/surfactant composite. Carbon 44, 1969 (2006).CrossRefGoogle Scholar
Yang, D., Ni, W., Cheng, J., Wang, Z., Wang, T., Guan, Q., Zhang, Y., Wu, H., Li, X., and Wang, B.: Flexible three-dimensional electrodes of hollow carbon bead strings as graded sulfur reservoirs and the synergistic mechanism for lithium–sulfur batteries. Appl. Surf. Sci. 413, 209 (2017).CrossRefGoogle Scholar
See, K.A., Jun, Y.S., Gerbec, J.A., Sprafke, J.K., Wudl, F., Stucky, G.D., and Seshadri, R.: Sulfur-functionalized mesoporous carbons as sulfur hosts in Li–S batteries: Increasing the affinity of polysulfide intermediates to enhance performance. ACS Appl. Mater. Interfaces 6, 10908 (2014).CrossRefGoogle ScholarPubMed
Scrosati, B., Hassoun, J., and Sun, Y.K.: Lithium-ion batteries. A look into the future. Energy Environ. Sci. 4, 3287 (2011).CrossRefGoogle Scholar
Yang, Y., Yu, G., Cha, J.J., Wu, H., Vosgueritchian, M., Yao, Y., Bao, Z., and Cui, Y.: Improving the performance of lithium-sulfur batteries by conductive polymer coating. ACS Nano 5, 9187 (2011).CrossRefGoogle ScholarPubMed
Pongilat, R., Franger, S., and Nallathamby, K.: Functionalized carbon as polysulfide traps for advanced lithium–sulfur batteries. J. Phys. Chem. C 122, 5948 (2018).CrossRefGoogle Scholar
Zhu, F.L., Yang, Z., Zhao, J.P., and Zhao, X.: Microwave assisted preparation of expanded graphite/sulfur composites as cathodes for Li–S batteries. New Carbon Mater. 31, 199 (2016).CrossRefGoogle Scholar
Benítez, A., González-Tejero, M., Caballero, Á., and Morales, J.: Almond shell as a microporous carbon source for sustainable cathodes in lithium–sulfur batteries. Materials 11, 1428 (2018).CrossRefGoogle Scholar
Guo, Y., Wu, H., Zhang, Y., Xiang, M., Zhao, G., Liu, H., and Zhang, Y.: Vesicle-like sulfur/reduced graphene oxide composites for high performance lithium-sulfur batteries. J. Alloys Compd. 724, 1007 (2017).CrossRefGoogle Scholar
Wang, X., Zhang, Z., Qu, Y., Lai, Y., and Li, J.: Nitrogen-doped graphene/sulfur composite as cathode material for high capacity lithium–sulfur batteries. J. Power Sources 256, 361 (2014).CrossRefGoogle Scholar
Lee, J.S. and Manthiram, A.: Hydroxylated N-doped carbon nanotube–sulfur composites as cathodes for high-performance lithium–sulfur batteries. J. Power Sources 343, 54 (2017).CrossRefGoogle Scholar
Tang, J., Yang, J., and Zhou, X.: Acetylene black derived hollow carbon nanostructure and its application in lithium–sulfur batteries. RSC Adv. 3, 16936 (2013).CrossRefGoogle Scholar
Xie, Y., Fang, L., Cheng, H., Hu, C., Zhao, H., Xu, J., Fang, J., Lu, X., and Zhang, J.: Biological cell derived N-doped hollow porous carbon microspheres for lithium–sulfur batteries. J. Mater. Chem. A 4, 15612 (2016).CrossRefGoogle Scholar
Snyder, M.A., Alex, L.J., Davis, T.M., Scriven, L.E., and Michael, T.: Silica nanoparticle crystals and ordered coatings using lys-sil and a novel coating device. Langmuir 23, 9924 (2007).CrossRefGoogle Scholar
Yan, M., Dong, G., Fuqiang, Z., Yifeng, S., Haifeng, Y., Zheng, L., Chengzhong, Y., Bo, T., and Dongyuan, Z.: Ordered mesoporous polymers and homologous carbon frameworks: Amphiphilic surfactant templating and direct transformation. Angew. Chem., Int. Ed. 44, 7053 (2005).Google Scholar