Accelerator mass spectrometry (AMS) is by far the predominant technology deployed for radiocarbon tracer studies. Applications are widespread from archaeology to biological, environmental, and pharmaceutical sciences. In spite of its excellent performance, AMS is expensive and complicated to operate. Consequently, alternative detection techniques for 14C are of great interest, with the vision of a compact, user-friendly, and inexpensive analytical method. Here, we report on the use of intracavity optogalvanic spectroscopy (ICOGS) for measurements of the 14C/12C ratio. This new detection technique was developed by Murnick et al. (2008). In the infrared (IR) region, CO2 molecules have strong absorption coefficients. The IR-absorption lines are narrow in line width and shifted for different carbon isotopes. These properties can potentially be exploited to detect 14CO2, 13CO2, or 12CO2 molecules unambiguously. In ICOGS, the sample is in the form of CO2 gas, eliminating the graphitization step that h is required in most AMS labs. The status of the ICOGS setup in Uppsala is presented. The system is operational but not yet fully developed. Data are presented for initial results that illustrate the dependence of the optogalvanic signal on various parameters, such as background and plasma-induced changes in the sample gas composition.

Nine excavation seasons at Ossimo Anvòia in the Val Camonica (Central Alps, Italy) have brought to light a Copper Age ceremonial area with symbolic monoliths (statue menhirs) in their original position. Hundreds of artifacts and ecofacts indicate ideological activity during the 3rd millennium BC. A large pit (F18) was discovered that was unusual for its great size and the abundance of well-preserved charcoal. The pit housed a fallen monolith (M9) showing complicated reshaping. A detailed spatial study based on 6 radiocarbon accelerator mass spectrometry (AMS) measurements combined with charcoal analysis has untangled key information to define the history of feature F18-M9. 14C data show that the burning event occurred most probably in the 4th century AD, not in prehistory. We infer a unique episode of “reconsecration” during the very latest phases of pagan cult activity in the Val Camonica. Further studies are needed to resolve the relationships with other features of the site. In addition, charcoal analysis has produced paleobotanical information for a scarcely known period in the environmental history of the area. A sparse forest with Picea abies, Larix decidua, and Fagus sylvatica existed, associated with areas likely devoted to grazing. There is a remarkable absence of chestnut.

High-quality data from appropriate archives are needed for the continuing improvement of radiocarbon calibration curves. We discuss here the basic assumptions behind 14C dating that necessitate calibration and the relative strengths and weaknesses of archives from which calibration data are obtained. We also highlight the procedures, problems, and uncertainties involved in determining atmospheric and surface ocean 14C/12C in these archives, including a discussion of the various methods used to derive an independent absolute timescale and uncertainty. The types of data required for the current IntCal database and calibration curve model are tabulated with examples.

Pollen extracted from ocean and wetland sediments cored from the eastern Canadian Margin, James Bay region, and Atlantic provinces of Canada have been radiocarbon dated and results are reported here. Pollen dates from ocean sediments were compared with marine carbonate (mollusk shells or foraminifera) dates from the same core levels, dates for which validity was assessed via correlations with other cores, and for which reworking has been excluded. Pollen samples from 3 tidal wetlands were taken from levels dated with 137Cs and 210Pb profiles. Pollen dates from 2 additional wetlands were compared with 14C dates of botanical macrofossils. Most pollen dates disagree with 14C dates based on macrofossils or carbonates, with age differences typically exceeding 250 yr and reaching 4000 yr in one instance. In some cores, pollen dates show age reversals. Significant proportions of reworked pollen grains in ocean and wetland samples are associated with pollen dates that are too old. Prolonged core storage could result in pollen 14C ages that are too young, possibly because of growth of fungi or other microbes, but more work is needed to verify this hypothesis. Despite the problems we encountered, some pollen dates are consistent with other 14C dates from the same core levels, suggesting this dating method can work, but at present, more work is needed to understand the conflicting results obtained.

Lacustrine stromatolites are layered accretionary structures formed in shallow water by cyanobacteria. They are a precise indicator of high lake limits and their morphology and structure provide an insight into paleoenvironments of the time. Previous research on lacustrine stromatolites from Etosha Pan in Namibia based on radiocarbon ages of carbonates were close to the limit of the method and did not account for any possible 14C reservoir effect. The ages were used to suggest that the basin was not extensively flooded during the last 40,000 yr. To assess the reservoir effect, the age characteristics of a stromatolite from Poacher's Point were investigated by 14C dating both carbonate and organic residue from samples at different depths in the deposit. The ∼15-cm-diameter stromatolite was separated into 12 zones from the center to the edge and block samples were cut from each zone; the carbonate and residual organic residue were dated separately. The carbonate ages ranged from 34,700 to 24,700 14C yr BP and the organic ages from 15,700 to 2500 14C yr BP. Ages generally increased with increasing distance from the surface of the deposit. We believe that the organic ages are an accurate estimate of the stromatolite's age, while the much older carbonate ages reflect incorporation of old carbon from limestone bedrock and ancient calcrete introduced by stream and spring flow. Excluding the 2 oldest organic ages (15,700 and 13,600 14C yr BP), which may reflect contamination by older organic material washed into the lake during flooding, a linear regression relationship between carbonate and organic ages indicates that the reservoir effect on carbonate ranges up to ∼24,000 14C yr BP but decreases slightly as the true age of the deposit increases. This regression relationship was used to correct 2 finite carbonate ages for stromatolites from Pelican Island obtained in the early 1980s, which together with our new organic age for a stromatolite from Andoni Bay, document a >8-m-deep lake in Etosha Pan during the Late Pleistocene, at and prior to ∼34,000–26,000 cal yr BP. The organic carbon ages from the Poacher's Point stromatolite suggest prolonged lacustrine conditions during the early to middle Holocene (8000–6600 cal yr BP) but not to the extent seen during the Late Pleistocene.

A new compact accelerator mass spectrometry (AMS) system has been installed in the Kaminoyama Research Institute at Yamagata University (YU). The AMS system is based on a 0.5MV Pelletron accelerator developed by the National Electrostatics Corporation. An automated acid-alkali-acid (AAA) treatment system and an automated graphitization line were also installed in the same facility for sample preparation. Performance tests of the YU-AMS system were carried out by measuring the C-series standard samples (C1–C8) and HOxII provided by IAEA and NIST, respectively. We evaluated the YU-AMS system by comparing the radiocarbon ages of Japanese tree rings with dendrochronologically determined calendar ages with calibration data. We also carried out some performance tests using a control serum and a 14C-labeled drug (oxaliplatin).

We used accelerator mass spectrometry (AMS) to study radiocarbon-specific activity levels in agricultural and botanical samples (moss and pine needles) distributed within a 6.5-km radius of the Qinshan Nuclear Power Plant (NPP). The 14C-specific activity in moss samples (ranging from 265.6 to 223.0 Bq/kg C) decreased with increased distance from the stacks of Plant III (heavy water reactor) and reached the background level (223.8 Bq/kg C) at 6.5 km distance. Compared to the pine needles, the moss was a better indicator for investigating the 14C distribution near Qinshan NPP. The 14C-specific activity distribution in moss samples showed that the diffusion of 14C discharged from the Qinshan NPP was affected by both geographical and meteorological factors. Excess 14C-specific activity in the food samples ranged from 8.5 to 13.0 Bq/kg C (except for rice samples), resulting in a minimal radiation dose of 0.5 μSv per year to the public.

Shallow-water tropical corals can be used to calibrate the radiocarbon timescale. In this paper, we present a new data set based on the comparison between 14C ages and U-Th ages measured in fossil corals collected offshore the island of Tahiti during the Integrated Oceanic Drilling Program (IODP) Expedition 310. After applying strict mineralogical and geochemical screening criteria, the Tahiti record provides new data for 2 distinct time windows: 7 data for the interval between 29 and 37 cal kyr BP and 58 for the last deglaciation period, notably a higher resolution for the 14–16 cal kyr BP time interval. There are 3 main outcomes of this study. First, it extends the previous Tahiti record beyond 13.9 cal kyr BP, the oldest U-Th age obtained on cores drilled onshore in the modern Tahiti barrier reef. Second, it strengthens the data set of the 14–15 cal kyr BP period, allowing for better documentation of the 14C age plateau in this time range. This age plateau corresponds to a drop of the atmospheric 14C synchronous with an abrupt period of sea-level rise (Melt Water Pulse 1 A, MWP-1 A). The Tahiti 14C record documents complex changes in the global carbon cycle due to variations in the exchange rates between its different reservoirs. Third, during the Heinrich event 1, the Tahiti record disagrees with the Cariaco record, but is in broad agreement with other marine and continental data.

We consider a general methodology for the transferral of chronologies from a master reference record containing direct dating information to an undated record of interest that does not. Transferral is achieved through the identification, by an expert, of a series of tie-points within both records that are believed to correspond to approximately contemporaneous events. Through tying of the 2 records together at these points, the reference chronology is elastically deformed onto the undated record. The method consists of 3 steps: creation of an age-depth model for the reference record using its direct dating information; selection of the tie-points and translation of their age estimates from the reference to the undated record; and finally, creation of an age-depth model for the undated record using these uncertain tie-point age estimates. Our method takes full account of the uncertainties involved in all stages of the process to create a final chronology within the undated record that allows joint age estimates to be found together with their credible intervals. To achieve computational practicality, we employ a Gaussian process to create our age-depth models. Calculations can then be performed exactly without resort to extremely slow Monte Carlo methods involving multiple independent model fits that would be required by other age-depth models.

Tritium time series for precipitation in Beijing have been reconstructed for the period 1953–2002 using various methods: Guanbingjun method; trend surface analysis method; double reference curve method; triangulation method; and correlation method. By comparing the reconstructed results with the measured data of Beijing as well as data of other regions available in the IAEA GNIP database, the corresponding tritium time series have been developed for Beijing for the period 1953–2002, and the optimal time series was selected. The reconstructed result can be used for groundwater dating and related studies in Beijing as well as the surrounding areas.

The Indonesian Arc represents the subduction of the Indian-Australian plate beneath Asia. It has been the scene of catastrophic tectonic activity, including the recent 2004 M=9.1 Aceh earthquake and resulting Indian Ocean tsunami. We have dated planktonic forams associated with historic tephras (Tambora, 1815 and Krakatau, 1883) in marine sediment cores to determine radiocarbon reservoir ages for 2 locations along the arc. Our best estimates for 19th century regional reservoir corrections (ΔR) are +90 ± 40 yr for surface-dwelling species and +220 ± 40 yr for mixed planktic assemblages containing some upper thermocline species, but scatter in the data suggests that past surface reservoir ages may have varied by about ±100 yr. We used the results of this study to investigate a proposed very large AD 535 eruption at or near Krakatau. We find no evidence for ash from such an eruption, and although this is negative evidence, we consider it sufficiently strong to rule out any possibility that one took place.

A new system for CO2 absorption and liquid scintillation counting (LSC) was designed and developed along with its inherent measurement protocol for radiocarbon analysis in gaseous emissions, fuels, and biobased products. CO2 is chemically trapped as a carbamate in a suitable absorbing solution (3-methoxy-propyl-amine), gravimetrically measured, and analyzed by LSC (using a QuantulusTM 1220) to determine the 14C content. The use of cryogenic traps and a pressure transducer in the system prevents the need for closed-loop recirculation or additional steps to maximize CO2 capture in a short amount of time. The choice of PTFE vials used both for CO2 pretreatment and subsequent LSC analysis provides the opportunity to significantly reduce the background counting down to 40% with respect to the low-40K glass vials. This upgrade resulted in improving the maximum detectable age back to 36,000 yr BP in routine measurements. This method therefore turns out to be flexible enough to be applied for 14C dating as well as to differentiate between modern and fossil carbon.

We used the radiocarbon wiggle-match dating technique to date the varved sediments of Lake Gyltigesjön in southern Sweden with the main aim to construct an accurate chronology covering the period between about 3000 and 2000 cal BP. Wiggle-match dating was applied to bulk sediments to evaluate the possibility of constructing accurate chronologies in the absence of terrestrial plant macrofossils and when the amount of old carbon in the sediments is unknown. Facilitated by a floating varve chronology and relatively stable 14C reservoir ages, the results show the possibility to assess the contribution of old carbon solely based on the 14C wiggle-matching of bulk sediments. We confirm the wiggle-matched chronology and the 14C reservoir age of approximately 260 yr by cross-checking the results with 14C dating of macrofossils. The obtained calibrated ages based on bulk sediments have an uncertainty range of about 60–65 yr (95.4% confidence interval). This study confirms that 14C wiggle-match dating of bulk sediments is a viable tool when constructing high-resolution chronologies. The method is especially useful in Sun-climate studies since the timing between solar activity variations (expressed as 14C variations) and climate changes can be accurately determined.

Guided by simulations using SIMION 8.1, a series of modifications were made to an experimental version of an Isobar Separator for Anions (ISA). The resulting improved version of the ISA provides a means of re-energizing the ions after they are cooled by gas collisions as they pass through the gas-filled radiofrequency quadrupoles (RFQ), and also provides higher transmission efficiencies. Reinvestigation of the separation of CaF3− and KF3− with this refined apparatus resulted in a better balance between isobar suppression and analyte transmission. KF3− was attenuated at eV energies by 4 orders of magnitude while 40% transmission of CaF3− was retained, for a 20keV CaF3− beam of Φ2mm and ±12mr. These results advance the possibility of an efficient small ISA-AMS system for both cosmogenic and medical applications of 41Ca.

Due to its possible role in solid/water carbon isotope exchange, the effect of salinity on radiocarbon dating of groundwater was examined by batch interaction of alluvial sediment and calcite powder with freshwater (Cl– = 100 mg L–1) and Dead Sea (DS) brine (Cl– = 225 g L–1). These 2 water types were spiked with H13CO3– tracer and kept under constant agitation for about 1 yr. Several bottles were respiked twice with the tracer. The uptake of the 13C by calcite was monitored through repeated isotopic measurements of the aqueous solutions, and the effect on 14C groundwater dating was evaluated using a simple transport reaction model. The results indicate that the kinetics of water/calcite isotope exchange start with a very fast initial step followed by a slower one, which was used here to simulate the long-term water/solid exchange in “real” aquifers. The exchange model that best fits the data was homogeneous recrystallization that formed just a very thin layer of newly formed calcite. The estimated recrystallization rates for calcite powder/solution interaction were much smaller for the DS brine than for freshwater: 3 × 10–5 to 7 × 10–6 and 9 × 10–4 to 7 × 10–5 mol m2 yr–1, respectively. The 13C experimental data imply a very small effect of the brine/calcite isotope exchange on the 14C age estimate for the brines within the DS coastal aquifer. However, when calcite recrystallization reaches ∼1% of the solid, the 14C groundwater dating estimates will show aging by ∼10%.

We present a new record of radiocarbon ages measured by accelerator mass spectrometry (AMS) on a deep-sea core collected off the Pakistan Margin. The 14C ages measured on the planktonic foraminifera Globigerinoides ruber from core MD04-2876 define a high and stable sedimentation rate on the order of 50 cm/kyr over the last 50 kyr. The site is distant from the main upwelling zone of the western Arabian Sea where 14C reservoir age is large and may be variable. Many independent proxies based on elemental analyses, mineralogy, biomarkers, isotopic proxies, and foraminiferal abundances show abrupt changes correlative with Dansgaard-Oeschger and Heinrich events. It is now common knowledge that these climatic events also affected the Arabian Sea during the last glacial period through changes in the Indian monsoon and in ventilation at intermediate depths. The stratigraphic agreement between all proxies, from fine- to coarse-size fractions, indicates that the foraminiferal 14C ages are representative of the different sediment fractions.

To build a calendar age scale for core MD04-2876, we matched its climate record to the oxygen isotopic (δ18O) profile of Hulu Cave stalagmites that have been accurately dated by U-Th (Wang et al. 2001; Southon et al. 2012; Edwards et al., submitted). Both archives exhibit very similar signatures, even for century-long events linked to monsoonal variations. For comparison, we have also updated our previous work on core MD95-2042 from the Iberian Margin (Bard et al. 2004a,b,c), whose climate record has likewise been tuned to the high-resolution δ18O Hulu Cave profile. Sophisticated and novel statistical techniques were used to interpolate ages and calculate uncertainties between chronological tie-points (Heaton et al. 2013, this issue). The data from the Pakistan and Iberian margins compare well even if they come from distant sites characterized by different oceanic conditions. Collectively, the data also compare well with the IntCal09 curve, except for specific intervals around 16 cal kyr BP and from 28 to 31 cal kyr BP. During these intervals, the data indicate that 14C is somewhat older than indicated by the IntCal09 curve. Agreement between the data from both oceanic sites suggests that the discrepancy is not due to local changes of sea-surface 14C reservoir ages, but rather that the IntCal09 curve needed to be updated in these intervals as has been done in the framework of IntCal13 (Reimer et al. 2013a, this issue).

Luzia woman is considered one of the oldest Paleoindian skeletons found in the Americas. Luzia was found at the Lapa Vermelha IV site (Lagoa Santa, Minas Gerais, Brazil) in 1975 by the archaeologist Annette Laming-Emperaire (1917–1977) who sent to the Gif laboratory charcoals collected in the vicinity of the skeleton for radiocarbon dating. Twenty-nine charcoal samples were dated from different levels of the stratigraphy of the cave (Délibrias et al. 1986). Recently, new charcoal samples were discovered within Laming-Emperaire's correspondence and were subsequently dated by the Saclay AMS laboratory. The new results confirm the age of Luzia; however, the ages correspond to the younger part of the interval: charcoals found near Luzia's skull give an age of 10,030 ± 60 14C yr BP (11,243–11,710 cal BP).

High-precision analysis using accelerator mass spectrometry (AMS) was performed upon known-age Holocene and modern, pre-bomb coral samples to generate a marine reservoir age correction value (ΔR) for the Houtman-Abrolhos Archipelago (28.7°S, 113.8°E) off the Western Australian coast. The mean ΔR value calculated for the Abrolhos Islands, 54 ± 30 yr (1 σ) agrees well with regional ΔR values for Leeuwin Current source waters (N-NW Australia-Java) of 60 ± 38 yr. The Abrolhos Islands show little variation with ΔR values of the northwestern and north Australian coast, underlining the dominance of the more equilibrated western Pacific-derived waters of the Leeuwin Current over local upwelling. The Abrolhos Islands ΔR values have remained stable over the last 2896 cal yr BP, being also attributed to the Leeuwin Current and the El Niño Southern Oscillation (ENSO) signal during this period. Expected future trends will be a strengthening of the teleconnection of the Abrolhos Islands to the climatic patterns of the equatorial Pacific via enhanced ENSO and global warming activity strengthening the Leeuwin Current. The possible effect upon the trend of future ΔR values may be to maintain similar values and an increase in stability. However, warming trends of global climate change may cause increasing dissimilarity of ΔR values due to the effects of increasing heat stress upon lower-latitude coral communities.

For the older part of the radiocarbon dating range, the IntCal13 curve provides the “state of the art” for terrestrial calibration based on all available data. It is constructed from different records, each of which by themselves could be used as a “comparison tool,” depending on the research objectives. This paper discusses the pros and cons of different approaches that can be taken when using 14C dates from this time range where the agreement amongst the underlying data sets is poorer than in other time periods. The discussion is illustrated with example calibrations against IntCa09, IntCal13, and comparisons to the Suigetsu record. The examples and discussion arc aimed at users of terrestrial 14C dates, in particular Upper Paleolithic archaeologists and those working with environmental terrestrial materials in the same time range.

The Jena Analysis Code (JAC) was developed at the Jena radiocarbon laboratory for the analysis of all 14C accelerator mass spectrometry (AMS) data measured there. The fundamental principles and algorithms of JAC are presented here, along with the equally important checking procedures. JAC places emphasis on the uncertainty due to background subtraction and other contributions to the statistical uncertainty of 14C events.