Hostname: page-component-5c6d5d7d68-tdptf Total loading time: 0 Render date: 2024-08-17T23:12:50.787Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of Oriented Meso-Structure Silica Film by Ferrocenyl Surfactant

Published online by Cambridge University Press:  10 February 2011

H.S. Zhou  and
I. Honma
H.S. Zhou
Affiliation:
Energy Division, Electrotechnical Laboratory (ETL) 1-1-4, Umezono, Tsukuba, Ibaraki 305, Japan
I. Honma
Affiliation:
Energy Division, Electrotechnical Laboratory (ETL) 1-1-4, Umezono, Tsukuba, Ibaraki 305, Japan
Get access

Abstract

Self-assembly of organic-inorganic molecules into highly order nanostructured architectures have attracted increasing attention because these materials provide a rich source for scientific research and technological applications. We report the synthesis of an oriented silica mesostructured film by ferrocenyl surfactant templating using a spin coating method. The oriented silica meso-structure film was prepared as follows: tetraethoxysilane (TEOS) was partially hydrolyzed by a substoichiometric amount of pure water mixed with ethanol (EtOH) under acidic condition. The solution became homogeneous as the hydrolysis proceeded, then, ferrocenyl TMA was added, the mixture was stirred at room temperature for about 1 hour, and finally, the film was obtained by spin coating the hybrid sol. X-ray diffraction pattern of the film showed that the film oriented in a lamellar structure with (100) d-space of 36.3 A. The optical and electronic conductivity properties of the film have also been explored.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 77
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Beck, J.S. US Pat., 1991, 5, 507, 296.Google Scholar
2 Kresge, C.T.; Leonowicz, M.E.; Roth, W.J. and Vartuli, J.C. US Pat., 1992, 5, 098, 684.Google Scholar
3 Kresge, C.T.; Leonowicz, M.E.; Vartuli, J.C. and Beck, J.S. Nature, 1992, 359, 710.Google Scholar
4 Beck, J.S.; Vartuli, J.C.; Roth, W.J.; Leonowicz, M.E.; Kresge, C.T.; Schmitt, K.D.; Chu, C.T-W.; Olson, D.H.; Sheppard, E.W.; McCullen, S.B.; Higgins, J.B. and Schlenker, J.L. J. Am. Chem. Soc., 1992, 114, 10834.10.1021/ja00053a020Google Scholar
5 Wu, Chun-Guey and Bein, Thomas Science, 1994, 264, 1757,10.1126/science.264.5166.1757Google Scholar
6 Ogawa, M., J. Amer. Chem. Soc. 1994, 116, 7941.Google Scholar
7 Yang, H., Kuperman, A., Coombs, N., Mamiche-Afra, S., Ozin, A, Nature, 1996, 379, 703.10.1038/379703a0Google Scholar
8 Lu, Y.. Ganguli, R., Drewien, C.A., Anderson, M.T., Brinker, C.J., Gong, W., Guo, Y., Soyez, H., Dunn, B., Huang, M.H. and Zink, J.I., Nature, 1997, 389, 364.10.1038/38699Google Scholar
9 Aksay, I.A., Trau, M., Manne, S., Honma, I., Yao, N., Zhou, L., Fenter, P., Eisenberger, P.M. and Gruner, S.M., Science, 1996, 273, 892.10.1126/science.273.5277.892Google Scholar
10 Trau, M., Yao, N., Kim, E., Xia, Y., Whitesides, G.M. and Aksay, I.A., Nature, 1997, 390, 674.10.1038/37764Google Scholar
11 Honma, I., Zhou, H.S., Kundu, D. to be submitted J. Am. Chem. Soc.Google Scholar
12 Honma, I., Zhou, H.S.; Chem. Mater. 1998, 10, 103.Google Scholar
13 Zhou, H.S., Sasabe, H., Honma, I., J. Mater. Chem. 1998, 8(3), 515.Google Scholar
14 Wu, Chun-Guey and Bein, Thomas Chem. Mater. 1994, 6, 1109.Google Scholar
15 Ogawa, M., Langmuir, 1995, 11, 4639.Google Scholar
16 Braun, P.V., Osenar, P. and Stupp, S.I., Nature, 1996, 380, 325.10.1038/380325a0Google Scholar
17 Kundu, D., Zhou, H.S., Honma, I.; submitted to Chem. Mater.Google Scholar