Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-17T16:19:11.705Z Has data issue: false hasContentIssue false

Structure and Magnetic Properties of Nd-Co-Fe-Si-C Intermetallics

Published online by Cambridge University Press:  14 March 2011

Monica Sorescu
Affiliation:
Duquesne University, Bayer School of Natural and Environmental Sciences, Physics Department, Pittsburgh, Pennsylvania 15282, U. S. A.
A. Grabias
Affiliation:
Duquesne University, Bayer School of Natural and Environmental Sciences, Physics Department, Pittsburgh, Pennsylvania 15282, U. S. A.
M. Valeanu
Affiliation:
Institute of Atomic Physics, National Institute of Materials Physics, R 76900 Bucharest, Romania
Get access

Abstract

Intermetallics of the type Nd2Co15−xFexSi2Cy (x=7; 9; 12 and y=0; 1) were prepared by arc melting in order to study the competing effects of Fe and Co substitutions on the magnetic hyperfine fields as well as the effects of interstitial carbon additions on the symmetry and local magnetic properties in these systems. The investigations were performed by x-ray diffraction, Mössbauer spectroscopy and hysteresis loop measurements. Both site and average hyperfine magnetic field values were analyzed in order to discriminate between the Fe and Co contributions to the local atomic environments in these systems. While a higher Fe content as well as a higher Co content can both lead to an increase in the site magnetic fields, it was found that the model based on hyperfine field distributions provides a better description of the trends observed in hyperfine magnetic fields in these compounds.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sorescu, M., Brand, R. A., Plugaru, N. and Barb, D., Mater. Lett. 30, 235 (1997).10.1016/S0167-577X(96)00202-9Google Scholar
2. Sorescu, M., Valeanu, M., Tomuta, D. and Barb, D., Solid State Commun. 105, 195 (1998).10.1016/S0038-1098(97)10062-XGoogle Scholar
3. Sorescu, M., Valeanu, M. and Tomuta, D., Mater. Lett. 36, 52 (1998).10.1016/S0167-577X(98)00007-XGoogle Scholar
4. Burzo, E., Kirchmayr, H. R. and Celchowski, A., Landolt-Börnstein handbuch, Vol. 19 d2, Berlin, Springer Verlag, 1990.Google Scholar
5. Givord, D. and Lemaire, R., IEEE Trans.Magn. 10, 109 (1974).10.1109/TMAG.1974.1058311Google Scholar
6. Plugaru, N., Valeanu, M. and Burzo, E., IEEE Trans. Magn. 30, 663 (1994).10.1109/20.312369Google Scholar
7. Herbst, J. F., Croat, J. J., Lee, R. W. and Yelon, W. B., J. Appl. Phys. 53, 250 (1982).10.1063/1.331601Google Scholar
8. Luo, H., Hu, Z., Yelon, W. B., Ezekwenna, P. C., Marasinghe, G. K. and James, W. J., IEEE Trans. Magn. 32, 4389 (1996).10.1109/20.538878Google Scholar
9. Plugaru, N., Morariu, M., Galatanu, A., Lazar, D. P. and Barb, D., J. Appl. Phys. 182, 6193 (1997).10.1063/1.366504Google Scholar
10. Chan, X., Altounian, Z. and Ryan, D. H., J. Magn. Magn. Mater. 125, 169 (1993).10.1016/0304-8853(93)90834-OGoogle Scholar
11. Yelon, W. B., Hu, Z., Chen, M., Luo, H., Ezekwenna, P. C., Marasinghe, G. K., James, W. J., Buschow, K. H. J., Middleton, D. P., Pourarian, F., IEEE Trans. Magn. 32, 4431 (1996).10.1109/20.538891Google Scholar
12. Brand, R. A., Lauer, J. and Herlach, D. M., J. Phys. F 13, 675 (1983).10.1088/0305-4608/13/3/018Google Scholar
13. Sorescu, M. and Valeanu, M., Inter. J. Inorg. Mater. 1, 303 (1999).10.1016/S1466-6049(99)00044-6Google Scholar