Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-21T15:08:55.003Z Has data issue: false hasContentIssue false

Fundamentals of Particle Flocculation and Removal From Water

Published online by Cambridge University Press:  15 February 2011

Patrick T. Spicer
Affiliation:
Department of Chemical Engineering, University of Cincinnati, Cincinnati, OH 45221-0171
Sotiris E. Pratsinis
Affiliation:
Department of Chemical Engineering, University of Cincinnati, Cincinnati, OH 45221-0171
Get access

Abstract

The flocculation of polystyrene particles with aluminum sulfate or alum (Al2 (SO4)3) by turbulent shear was studied as a function of the applied shear rates (63–129 s−1) and flocculant concentrations (11 and 32 mg/L) in a stirred tank. Increasing the shear rate increased the floc growth rate but decreased the maximum attainable floc size. Increasing the concentration of alum increased the floc growth rate and the maximum floc size. A steady state between floc growth and breakage was attained after which the floc size distribution no longer changed. The normalized steady state size distributions allowed evaluation of the relative contributions of shear rate and flocculant concentration to the performance of the process.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Reich, I. and Void, R. D., “Flocculation-Deflocculation in Agitated Suspensions. I.Carbon and Ferric Oxide in Water,” J. Phys. Chem., 63, 1497 (1959).Google Scholar
2. Tambo, N. and Watanabe, Y., “Physical Aspect of Flocculation Process: I. Fundamental Treatise,” Water Res., 13, 429 (1979).Google Scholar
3. Cohen, R. D., “Evolution of the Cluster Size Distribution in Stirred Suspensions,” J. Chem. Soc. Faraday Trans., 87, 1163 (1991).Google Scholar
4. Cohen, R. D., “Self-Similar Cluster Size Distribution in Random Coagulation and Breakup,” J. Coll. Int. Sci., 149, 261 (1992).Google Scholar
5. Swift, D. L., and Friedlander, S. K., “The Coagulation of Hydrosols by Brownian Motion and Laminar Shear Flow,” J. Coll. Int. Sci., 19, 621 (1964).Google Scholar
6. Oles, V., “Shear-Induced Aggregation and Breakup of Polystyrene Latex Particles,” J. Coll. Int. Sci., 154, 351 (1992).Google Scholar
7. Francois, R. J., “Growth Kinetics of Hydroxide Flocs,” J. A WWA, 80 92 (1988).Google Scholar
8. Dentel, S. K. and Gossett, J. M., ” J. AWWA, 59 101 (1987).Google Scholar