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The Mechanical Response of Arrays of Carbon Nanotubes Coated with Metallic Shells

Published online by Cambridge University Press:  19 September 2018

Mohamad B. Zbib*
Affiliation:
School of Materials Engineering, Purdue University, West Lafayette, IN 47907, U.S.A. Department of Mechanical Engineering, Phoenicia University, District of Zahrani, Lebanon.
Matthew Howard
Affiliation:
School of Materials Engineering, Purdue University, West Lafayette, IN 47907, U.S.A. Department of Materials, Imperial College London, London, SW7 2AZ, U.K.
Michael R. Maughan
Affiliation:
School of Materials Engineering, Purdue University, West Lafayette, IN 47907, U.S.A. Department of Mechanical Engineering, University of Idaho, Moscow, ID 83844, U.S.A.
Nicolas J. Briot
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40506, U.S.A.
T. John Balk
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40506, U.S.A.
David F. Bahr
Affiliation:
School of Materials Engineering, Purdue University, West Lafayette, IN 47907, U.S.A.
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Abstract:

A synthesis method to form foams consisting of a shell of metals conformally coated on carbon nanotube (CNT) arrays by electroplating from a single bath electrolyte is demonstrated in this work. A triple cyclic pulse electrodeposition technique was used to deposit Ni and Cu layers on the CNT arrays, and electron microscopy was then used to identify conditions amenable to semi-conformal and island growth morphologies. Nanoindentation of the resulting metallic-CNT composite foam structure, using a flat punch/compression geometry, demonstrates that adding metallic shells to the CNT turf to create a metallic low density foam increases both the hardness and elastic modulus; however, once island growth initiates there is no significant subsequent increase in mechanical properties with increases in deposited metals.

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Articles
Copyright
Copyright © Materials Research Society 2018 

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