Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-17T18:06:47.275Z Has data issue: false hasContentIssue false
  • English
  • Français

Sorption Properties of Carbon Composite Materials Formed from Layered Clay Minerals

Published online by Cambridge University Press:  28 February 2024

Karol Putyera ,
Teresa J. Bandosz ,
Jacek Jagiełło  and
James A. Schwarz
Karol Putyera*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Teresa J. Bandosz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
Jacek Jagiełło*
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
James A. Schwarz
Affiliation:
Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13244-1190
*
1Permanent address: Institute of Inorganic Chemistry, Slovak Academy of Sciences, 842 36 Bratislava, Slovakia.
2Permanent address: Institute of Energochemistry of Coal and Physicochemistry of Sorbents, University of Mining and Metallurgy, 30-059, Krakøw, Poland.
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The sorption properties of carbon-composite materials based on montmorillonite and hydrotalcite matrices have been studied using nitrogen adsorption isotherms and inverse gas chromatography. Carbon composite materials derived from both types of inorganic precursors contain pore structure accessible for adsorbate molecules. Adsorption capacity per unit mass of these composite adsorbents is larger in the case of hydrotalcite than in montmorillonite-based materials. Exposing these materials to ambient conditions results in their hydration. Subsequent water removal by heating under vacuum increases nitrogen adsorption capacity, which is explained by the opening of the adsorption space. The water content of hydrated samples and its effect on adsorption capacity is greater for the case of hydrotalcite-based materials. No direct relationship between carbon content and adsorption properties of the materials studied is observed.

Keywords

CarbonHydrotalciteInverse gas chromatographyMontmorilloniteNitrogen sorptionSurface energy
Type
Research Article
Information
Clays and Clay Minerals , Volume 42 , Issue 1 , February 1994 , pp. 1 - 6
Copyright
Copyright © 1994, Clay Minerals Society

References

Barrer, R. M., (1978) Zeolites and Clay Minerals as Sorbents and Molecular Sieves: Academic Press, London.Google Scholar
Bandosz, T. J., JagiełłO, J., Andersen, B., and Schwarz, J. A., (1992) Inverse gas chromatography study of modified smectite surface: Clays & Clay Minerals 40, 306–310.CrossRefGoogle Scholar
Bandosz, T. J., JagiełłO, J., Amankwah, K. A. G., and Schwarz, J. A., (1992) Chemical and structural properties of clay minerals modified by inorganic and organic material: Clay Miner. 27, 435–444.CrossRefGoogle Scholar
Bandosz, T. J., Putyera, K., JagiełłO, J., and Schwarz, J. A., (1993) Application of inverse gas chromatography to the study of the surface properties of modified layered materials: Microporous Mat. 1, 73–79.CrossRefGoogle Scholar
Carrott, P. J. M., and Sing, K. S. W., (1987) Gas chromatographic study of microporous carbons: J. of Chromatography 406, 139–144.CrossRefGoogle Scholar
Dimotakis, E. D., and Pinnavaia, T. J., (1990) New route to layered double hydroxides intercalated by organic anions: Precursors to polyoxometalate-pillared derivatives: Inorg. Chem. 29, 2393–2394.CrossRefGoogle Scholar
Everett, D. H., and Powl, L. C., (1976) Adsorption in slitlike and cylindrical micropores in the Henry's Law region: J. Chem. Soc., Faraday Trans. I 72, 619–639.CrossRefGoogle Scholar
Gaffney, T. R., Farris, T. S., Cabrera, A. L., and Armor, J. N., (1992) Modified carbon molecular sieves for gas adsorption: U.S.Pat. 5,098,880.Google Scholar
Geismar, G., Lewandowski, J., and de Boer, E., (1991) Anion-exchange and reactions in Mg-Al oxide hydrates with hydrotalcite structure. II. Intercalated anion-exchange in organic solvents and chemical reactions: Chemiker-Zeitung 115, 335–339.Google Scholar
Gergova, K., Galushko, A., Petrov, N., and Minkova, V., (1992) Investigation of the porous structure of activated carbons prepared by pyrolisis of agricultural by-products in a stream of water vapor: Carbon 30, 721–727.CrossRefGoogle Scholar
JagiełłO, J., Bandosz, T. J., and Schwarz, J. A., (1992) Inverse gas chromatography study of activated carbons: The effect of controlled oxidation on microstructure and surface chemical functionality: J. of Coll. Inter. Sci. 151, 433–445.Google Scholar
Kiselev, A. V., and Yashin, Y. I., (1969) Gas Adsorption Chromatography: Plenum Press, New York, p. 23.CrossRefGoogle Scholar
Occelli, M. L., and Tindwa, P. M., (1983) Physicochemical properties of montmorillonite interlayered with cationic oxyaluminium pillars: Clays & Clay Minerals 31, 22–28.CrossRefGoogle Scholar
Pinnavaia, T. J., (1983) Intercalated clay catalysts: Science 220, 365–371.CrossRefGoogle ScholarPubMed
Putyera, K., (1991) Molecular oxygen activation with Co(II) complexes intercalated into intracrystalline spaces of inorganic matrices: Ph.D. thesis, Slovak Academy of Sciences, Bratislava, CSFR.Google Scholar
Sonobe, N., Kyotani, T., and Tomita, A., (1990) Carbonization of polyfurfuryl alcohol and polyvinyl acetate between the lamellae of montmorillonite: Carbon 28, 483–488.CrossRefGoogle Scholar
Verma, S. K., and Walker, P. L. Jr. 1992() Preparation of carbon molecular sieves by propylene pyrolysis over microporous carbons: Carbon 30, 829–836.CrossRefGoogle Scholar