Book contents
- Frontmatter
- Contents
- Preface
- General list of symbols
- Useful physical constants and values
- 1 Introduction to colloid science and rheology
- 2 Hydrodynamic effects
- 3 Brownian hard spheres
- 4 Stable systems
- 5 Non-spherical particles
- 6 Colloidal attractions and flocculated dispersions
- 7 Thixotropy
- 8 Shear thickening
- 9 Rheometry of suspensions
- 10 Suspensions in viscoelastic media
- 11 Advanced topics
- Index
- References
11 - Advanced topics
Published online by Cambridge University Press: 05 December 2011
Book contents
- Frontmatter
- Contents
- Preface
- General list of symbols
- Useful physical constants and values
- 1 Introduction to colloid science and rheology
- 2 Hydrodynamic effects
- 3 Brownian hard spheres
- 4 Stable systems
- 5 Non-spherical particles
- 6 Colloidal attractions and flocculated dispersions
- 7 Thixotropy
- 8 Shear thickening
- 9 Rheometry of suspensions
- 10 Suspensions in viscoelastic media
- 11 Advanced topics
- Index
- References
Summary
This chapter introduces some advanced methods of colloid rheology that focus primarily on determining fundamental properties of colloidal systems and, in some cases, on creating new colloidally based materials and devices. The advanced rheological techniques included here are stress jumps and superposition rheometry. Furthermore, microrheological techniques are introduced by Eric Furst (University of Delaware), whereby probes can be used to interrogate materials at the colloidal level. Such methods open up a rich field of investigation for testing colloidal micromechanics, as well as creating new colloid-based devices.
The second part of this chapter provides a first look into the expansive field of electrorheological and magnetorheological fluids, whereby a second applied field (electrical or magnetic) is used simultaneously with a flow field to create useful devices from suspensions. Finally, a brief introduction to colloids at interfaces is provided by Jan Vermant (Katholieke Universiteit Leuven), in which colloidal forces specific to surfaces lead to new and useful colloidal structures, which are being probed by novel surface rheological methods. These vignettes provide an introduction to a rich and rapidly evolving literature within the context of colloid rheology as presented in this monograph.
- Type
- Chapter
- Information
- Colloidal Suspension Rheology , pp. 354 - 387Publisher: Cambridge University PressPrint publication year: 2011
References
Stress jumps on weakly flocculated dispersions: Steady state and transient resultsJ Colloid Interface Sci 287 2005 542CrossRefGoogle ScholarPubMed
A servo-controlled rheometer for measurement of dynamic modulus of viscoelastic liquidsJ Sci Instr 43 12 1966CrossRefGoogle Scholar
Shear thickening in steady and superposition flows: Effect of particle interaction forcesJ Rheol 45 2001 799CrossRefGoogle Scholar
Anisotropy of nonaqueous layered silicate suspensions subjected to shear flowJ Rheol 53 2009 517CrossRefGoogle Scholar
Eine neue Methode zur Bestimmung der Viskositaet lebender ProtoplastenJahrb Wiss Bot 61 1922 284Google Scholar
Optical measurements of frequency-dependent linear viscoelastic moduli of complex fluidsPhys Rev Lett 74 1995 1250CrossRefGoogle ScholarPubMed
Viscoelasticity and generalized Stokes-Einstein relations of colloidal dispersionsJ Chem Phys 111 1999 8721CrossRefGoogle Scholar
Hydrodynamic and colloidal interactions in concentrated charge-stabilized disperisonsJ Colloid Interface Sci 225 2000 166CrossRefGoogle Scholar
Small amplitude active oscillatory microrheology of a colloidal suspensionJ Rheol 53 2009 357CrossRefGoogle Scholar
Nonlinear microrheology: Bulk stresses versus direct interactionsLangmuir 24 2008 1147CrossRefGoogle ScholarPubMed
Active microrheology of a colloidal suspension in the direct colision limitPhys Fluids 22 2010CrossRefGoogle Scholar
Advances in electrorheological fluids based on inorganic dielectric materialsJ Ind Eng Chem 12 2006 184Google Scholar
Electrorheological fluids as colloidal suspensionsAdv Colloid Interface Sci 30 1989 153CrossRefGoogle Scholar
The giant electrorheological effect in suspensions of nanoparticlesNat Mater 2 2003 727CrossRefGoogle ScholarPubMed
Studies on the steady-shear behavior of electrorheological suspensionsLangmuir 6 1990 15CrossRefGoogle Scholar
Solid phases in electro- and magnetorheological systemsJ Chem Phys 130 2009 204513.CrossRefGoogle ScholarPubMed
Characterization of heterogeneous systems by dielectric spectroscopyProg Polym Sci 27 2002 1617CrossRefGoogle Scholar
Polarization and interactions of colloidal particles in ac electric fieldsJ Chem Phys 129 2008CrossRefGoogle ScholarPubMed
Dielectric electrorheological fluids: Theory and experimentAdv Phys 52 2003 343CrossRefGoogle Scholar
Many-body electrostatic interactions in electrorheological fluidsPhys Rev E 48 1993 2721CrossRefGoogle ScholarPubMed
Macroscopic model of interaction between particles in an electrorheological fluidJ Electrostat 33 1994 103CrossRefGoogle Scholar
Time-dependent and nonlinear effects in electrorheological fluidsJ Chem Phys 81 1997 1985Google Scholar
A yield stress scaling function for electrorheological fluidsAppl Phys Lett 78 2001 3806CrossRefGoogle Scholar
Effects of electric fields on the rheology of non-aqueous concentrated suspensionsJ Chem Soc, Faraday Trans 1. 85 1989 2785CrossRefGoogle Scholar
The role of suspension structure in the dynamic response of electrorheological suspensionsInt J Mod Phys B 8 1994 2789CrossRefGoogle Scholar
Electrorheology of a model colloidal fluidJ Colloid Interface Sci 187 1994 437CrossRefGoogle Scholar
Electrorheological behavior of whisker suspensions under oscillatory shearColloids Surf A 299 2007 262CrossRefGoogle Scholar
Measurement modes of the response time of a magnetorheological fluid (MRF) for changing magnetic flux densityRheol Acta 46 2007 665CrossRefGoogle Scholar
Proceedings of the 5th International Conference on ER Fluids, MR Suspensions and Associated TechnologySingaporeWorld Scientific 1995Google Scholar
On the theory of rheological properties of magnetic suspensionsPhysica A 382 2007 378CrossRefGoogle Scholar
Particles as surfactants: Similarities and differencesCurr Opin Colloid Interface Sci 7 2002 21CrossRefGoogle Scholar
Control over colloidal aggregation in monolayers of latex particles at the oil-water interfaceLangmuir 22 2006 4936CrossRefGoogle ScholarPubMed
Flow-induced anisotropy and reversible aggregation in two-dimensional suspensionsLangmuir 19 2003 9134CrossRefGoogle Scholar
Structure and dynamics of particle monolayers at a liquid-liquid interface subjected to shear flowFaraday Discuss 123 2003 145CrossRefGoogle Scholar
Shearing or compressing a soft glass in 2D: Time-concentration superpositionPhys Rev Lett 90 2003CrossRefGoogle ScholarPubMed
Interfacial rheology of stable and weakly aggregated two-dimensional suspensionsPhys Chem Chem Phys 9 2007 6463CrossRefGoogle ScholarPubMed
Emulsions stabilised solely by colloidal particlesAdv Colloid Interface Sci 100 2003 503CrossRefGoogle Scholar
Phase inversion of particle-stabilized materials from foams to dry waterNat Mater 5 2006 865CrossRefGoogle ScholarPubMed
Colloidal Particles At Liquid InterfacesCambridgeCambridge University Press, 2006CrossRefGoogle Scholar
On the possible role of surface elasticity in emulsion stabilityLangmuir 25 2009 5565CrossRefGoogle ScholarPubMed
Exploiting particle shape in solid stabilized emulsions stabilitySoft Matter 5 2009 1717CrossRefGoogle Scholar
Self-assembly and rheology of ellipsoidal particles at interfacesLangmuir 25 2009 2718CrossRefGoogle ScholarPubMed
The electrostatic interaction between interfacial colloidal particlesJ Phys A: Math Gen 18 1985 1055CrossRefGoogle Scholar
105 2010
Direct measurements of the effects of salt and surfactant on interaction forces between colloidal particles at oil water interfacesLangmuir 24 2008 1686CrossRefGoogle Scholar
Capillary interactions between particles bound to interfaces, liquid films and biomembranesAdv Colloid Interface Sci 85 2 2000CrossRefGoogle ScholarPubMed
Long-range attraction between colloidal spheres at the air-water interface: The consequences of an irregular meniscusPhys Rev E 62 2000 5263CrossRefGoogle Scholar
Dynamics of a fluid interface: Equation of motion for Newtonian surfaceChem Eng Sci 12 1960 98CrossRefGoogle Scholar
An interfacial stress rheometer to study rheological transitions in monolayers at the air-water interfaceLangmuir 16 1999 2450CrossRefGoogle Scholar
Methods of measuring rheological properties of interfacial layers: Experimental methods of 2D rheologyColloid J 71 2009 1CrossRefGoogle Scholar
A double wall-ring geometery for interfacial shear rheometryRheol Acta 49 2010 131CrossRefGoogle Scholar
Two-particle microrheology of quasi-2D viscous systemsPhys Rev Lett 97 2006CrossRefGoogle ScholarPubMed
Interfacial dilatational rheology by oscillating bubble/drop methodsCurr Opin Colloid Interface Sci 15 2010 217CrossRefGoogle Scholar
The Einstein viscosity correction in dimensionsInt J Multiphase Flow 10 1984 113CrossRefGoogle Scholar
Elastic properties of 2D colloidal crystals from video microscopyPhys Rev Lett 90 2003CrossRefGoogle ScholarPubMed
Scaling of the viscoelasticity of weakly attractive particlesPhys Rev Lett 85 2000 449CrossRefGoogle ScholarPubMed
Shearing particle monolayers: Strain-rate frequency superpositionPhys Rev E 81 2010CrossRefGoogle ScholarPubMed
Two-dimensional sol-gel transition in silica alkoxides at the air-water interfaceLangmuir 25 2009 11205CrossRefGoogle ScholarPubMed
1985 141
Dynamic transitions and oscillatory melting of a two-dimensional crystal subjected to shear flowJ Rheol 48 2004 159CrossRefGoogle Scholar
Structure and dynamics of particle monolayers at a liquid-liquid interface subjected to extensional flowLangmuir 18 2002 4372CrossRefGoogle Scholar
Orthokinetic aggregation in two dimensions of monodisperse and bidisperse colloidal systemsJ Colloid Interface Sci 220 1999 269CrossRefGoogle ScholarPubMed
Restructuring and break-up of two-dimensional aggregates in shear flowLangmuir 22 2006 4959CrossRefGoogle ScholarPubMed
Direct visualization of yielding in model two-dimensional collolidal gelsJ Rheol 53 2009 1437CrossRefGoogle Scholar