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11 - Atmosphere control for the protection of metals during production processes

Published online by Cambridge University Press:  05 June 2012

Gerald H. Meier
Affiliation:
University of Pittsburgh
Frederick S. Pettit
Affiliation:
University of Pittsburgh
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Summary

Introduction

The exposure of metals to gases at high temperatures during production processes may be divided broadly under two headings.

  1. (1) Reheating for subsequent working or shaping.

  2. (2) Reheating for final heat treatment, sometimes of finished components.

When reheating for subsequent working or shaping, the main concern is to heat the components as quickly and economically as possible to the working temperature, within the metallurgical constraint of avoiding element redistribution and thermal cracking. In addition, it is usual to expose the metal directly to a burned-fuel atmosphere containing about 1% excess oxygen necessary to ensure complete combustion and, therefore, the most economic use of the fuel. Under these conditions, as there is little likelihood of operating a controlled-atmosphere policy, surface damage due to oxidation or scaling and, in the case of steels, decarburization, must be removed at a later stage in the process. Indeed, if the surface of the material to be reheated already has some undesirable features, it may be possible to remove, or reduce, them by allowing some scaling to occur.

Alloys which are susceptible to surface deterioration during reheating may be protected either by controlling the atmosphere composition to minimize, or avoid, surface deterioration or by applying a coating to protect the alloy from the atmosphere.

Coatings are not an economic proposition in the treatment of large tonnage production in this way, but are applied to cause selective carburization, etc., during surface-hardening procedures.

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Chapter
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Publisher: Cambridge University Press
Print publication year: 2006

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References

Kubaschewski, O., Evans, E. H., and Alcock, C. B., Metallurgical Thermochemistry, Oxford, Pergamon Press, 1967Google Scholar
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L. H. Fairbank and L. G. W. Palethorpe, ‘Heat treatment of Metals,’ ISI Special Report. No. 95, London, ISD 1966, p. 57
R. V. Cutts and H. Dan, Proceedings of the Institute of Iron and Steel Wire Manufacturers Conference, Harrogate, March 1972, paper 7

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