Archaeological investigations in the Iron Gates reach of the Lower Danube Valley between 1964 and 1984 revealed an important concentration of Stone Age sites, which together provide the most detailed record of Mesolithic and Early Neolithic settlement from any area of southeastern Europe. Over 425 human burials were excavated from 15 sites. Of these, less than one-fifth have been directly dated. This article presents 37 new AMS dates on human bone from five sites in the Iron Gates, together with the corresponding δ13C and δ15N values. They include the first dates on human bone from two sites, Icoana and Velesnica. The results are important for the chronology of Stone Age mortuary practices in the Iron Gates and the timing of the Mesolithic–Neolithic transition in the region.

The aim of this article is to discuss radiocarbon dating offsets due to freshwater and marine reservoir effects (FRE and MRE, respectively) in the southeastern Baltic. Thirty-six 14C dates from Lithuanian coastal and inland Subneolithic, Neolithic, and Bronze Age sites as well as two Mesolithic-Neolithic cemeteries are presented here. Accelerator mass spectrometry (AMS) dates, sometimes paired or tripled, have been obtained on samples of various origin, foodcrusts, or visible charred deposits adhering to the surfaces of ceramic vessel walls were also dated and investigated for stable isotope signals. The results argue for a significant freshwater component in the food processed in ceramic vessels during the Subneolithic and Neolithic. Paired dating of ungulate and human bones at the Spiginas and Donkalnis cemeteries (6300–1900 cal BC) does not suggest an FRE, although stable isotope data on human bone collagen strongly suggest a large input of freshwater food in the diet. An FRE in the order of 320–510 yr was estimated for the Šventoji paleolagoon around 3000 cal BC. At the same time, the FRE of the Curonian Lagoon could be larger as implied by large apparent 14C ages of modern pike-perch (981 ± 30 BP) and bream (738 ± 30 BP) bones as well as “foodcrust” offsets (650–530 yr) at Nida (3500–2500 cal BC). An MRE of 190 ± 43 yr was estimated for the southeastern coast of the Littorina Sea according to offsets between dates of seal bones and terrestrial samples at Nida and Šventoji. Any FRE at Lake Kretuonas remains uncertain due to the limited work to date.

Radiocarbon variations in the atmosphere have been observed at the Žlkovce monitoring station of the Bohunice nuclear power plant (NPP), situated only 5 km ESE from the NPP. The observed 14C levels provide unique evidence of a decreasing long-term impact of the Bohunice NPP on the region. Simultaneously, decreasing emissions of fossil fuel carbon dioxide in the atmosphere of the monitoring site have been found. The observed Δ14C variations with time have attenuating amplitudes and decreasing mean values, showing maxima in summer and minima in winter, the latter primarily caused by increased emission of fossil CO2 in winter months. Sporadic short-term releases of 14C from the Bohunice NPP were observed at the Žlkovce station. The annual atmospheric Δ14C variations compared with tree-ring data collected at the Žlkovce village show reasonable agreement. The observed Δ14C levels after 2005 are close to the European clean-air levels as measured at the Jungfraujoch (3450 m asl) monitoring station.

Microarchaeological methods, especially those focused on geoarchaeology and radiocarbon dating, have revolutionized the manner in which the Iron Age settlement peak in the Negev Highlands is interpreted. We review here results from field and laboratory studies conducted at two Iron Age sites (Atar Haroa and Nahal Boqer) compared to one Byzantine/Early Islamic site (Wadi el-Mustayer)—all located near Sede Boqer. We present our methodology, which is based on small-scale but detailed excavations, study of sediments, and identification of livestock dung remains and their utility as indicators of past subsistence practices. To this we add meticulous 14C dating, ceramic petrography, and identification of botanic and zoological remains. We conclude that subsistence during the Iron Age included tending livestock but did not include agriculture. We further propose that the long-distance trade of copper from the Arabah Valley under Egyptian auspices and possibly the trading of cinnamon, dates, and other Arabian/Indian commodities were the driving force in the initiation (and later decline) of the Iron Age settlement system. We hypothesize that the agricultural settlement peak during the Byzantine/Early Islamic period was also influenced by an imperial power from outside of the Negev and that large-scale agriculture was enabled due to the adoption of new agricultural techniques, including terracing of ephemeral streams along with water diversion systems and possibly water storage facilities such as advanced cisterns. Future studies are expected to shed additional light on the complexity of settlement oscillations in the Negev Highlands region in key periods such as the Early and Intermediate Bronze Ages.

This article presents radiocarbon dates from human bone samples (n = 13) from seven pre-Columbian cemeteries in the Samaca and Ullujaya Basins of the lower Ica Valley, south coast of Peru, spanning from the end of the Early Horizon to the Inca Late Horizon. These contexts have been severely looted. Yet, in all cases, their putative dating by material culture remains is confirmed by these 14C dates. This shows that such disturbed contexts, sadly typical of the Peruvian coast, can nonetheless still yield valuable bioarchaeological and burial practice data. These dates elaborate upon an emerging picture of the absolute dating of the cultural phases of the wider south coast region, in particular casting new light on the poorly understood Middle Horizon to Late Intermediate period transition. A paucity of archaeological data for this 3-century period has been taken as evidence of some sort of environmentally or socially induced lacuna. Instead, the 14C dates presented here suggest that the basins of the lower Ica Valley were continuously occupied over this period.

A review of current research reveals multiple lines of evidence suggesting that no single freshwater reservoir offset (FRO) correction can be applied to accelerator mass spectrometer (AMS) ages obtained on carbonized food residue from cooking vessels. Systematically evaluating the regional presence, magnitude, and effects of a freshwater reservoir effect (FRE) is a demonstrably difficult analytic problem given the variation of ancient carbon reservoirs in both space and time within water bodies, and which should be performed in advance of AMS assays. In coastal and estuarine contexts, a priori partitioning FRE from known marine reservoir effects (MRE) is also necessary to eliminate potential mixed effects. Likewise, any FRE varies based on the proportional mix of resources producing the residues and the ancient carbon uptake of those products. Processing techniques are a significant component of assessing potential FRE, and each pot/cooking vessel is therefore an independent context requiring analytic evaluation. In northeastern North America, there is little ethnohistoric/ethnographic evidence for fish boiling/stewing in ceramic cooking vessels; rather, fish were more often dried, smoked, or cooked for immediate consumption on open fires. Assays of fatty acids extracted from prehistoric vessel fabrics even on known fishing sites reveals no evidence for fish in the food mix. These observations suggest that the likelihoods of FRE in carbonized food residue in northeastern North America is therefore low, and that assays potentially suffering from FRO are minimal. In turn, this suggests that AMS ages from carbonized food residues are reliable unless analytically demonstrated otherwise for specific cases, and should take primacy over ages on other associated materials that have historically been employed for critical threshold chronological events.

The Mexico City Metropolitan Area (MCMA) produces a complex mixture of gases and aerosols from diverse sources, including burning of fossil fuels, biomass, and wastes, with a significant biogenic contribution. We present the first results of ongoing projects to study temporal and spatial variations of 14CO2 in the area. Temporal variations reconstructed from tree rings of Taxodium mucronatum indicate a considerable radiocarbon depletion, in accordance to the vast amount of fossil fuels burnt inside Mexico Valley, with values between 62 and 246‰ lower than background values for the 1962–1968 period, and lower by 51–88‰ for the 1983–2010 period. The lower dilution found for the last decades might indicate an increase in enriched 14CO2 sources. Results from the spatial distribution, as revealed from integrated CO2 samples and grasses from six points within the MCMA collected during the 2013 dry season, show variations between sites and sample types. For integrated CO2 samples, values range from 35.6‰ to 54.0‰, and for grasses between −86.8‰ and 40.7‰. For three of the sampling points, the grasses are significantly depleted, by up to ∼133‰, as compared to the corresponding integrated CO2 sample. This may result from differences in the carbon assimilation period and exposure to different CO2 sources. Higher-than-background Δ14C values were found for all integrated CO2 samples, presumably resulting from 14C-enriched CO2 derived from forest fires in the mountains during the sampling period. Results obtained so far confirm the complexity of the 14C cycle in the MCMA.

The Atacama region of Chile has the highest concentration of hallucinogenic paraphernalia from prehistoric cemeteries on the planet. These artifacts have been studied since the late 19th century, primarily from the perspective of stylistic classification, which has been used to infer their temporal assignation. However, direct chronological dating of the snuff trays has not been addressed until now, through an interdisciplinary study conducted in San Pedro de Atacama on the psychotropic paraphernalia collection of the Instituto de Investigaciones Arqueológicas y Museo R.P. Gustavo Le Paige S.J. (IIAM), part of the Universidad Católica del Norte. In this study, samples were taken from eight snuff trays for radiocarbon dating and to develop a suitable procedure and protocol for sample extraction and handling of wooden archaeological pieces. This article provides the results of these activities by establishing the existence of a sequence of styles in the hallucinogenic paraphernalia that goes from the Middle to Late Intermediate period (about AD 300 to 1400), which shows that in this time-span there were two styles (Tiwanaku and local), and then both were replaced by a macroregional style.

When did the trade in lucrative spices from South Asia to the West commence? Recent organic residue analyses performed on small early Iron Age (11th–late 10th century BCE) Phoenician clay flasks provide the first concrete archaeological evidence that such sustainable trade took place much earlier than hitherto suspected. The analysis shows that several of the flasks contained cinnamon, which in this period could only have originated in South/Southeast Asia. Here, we first summarize the rationale and results of that study. Subsequently, we provide an updated review of all sources of data relevant to the question at hand—archaeological, analytical, and textual. Finally, we offer suggestions for future research on the Asian spice trade with the West.

The thousands of Bronze Age burial mounds of northwestern Europe often have complex histories, with multiple construction phases and secondary burials added to these mounds. It can be difficult to understand the dynamic nature of these events and the ebb and flow of activities in these monumental funerary landscapes. This article presents chronological models of five Bronze Age barrows from two sites. A total of 41 radiocarbon-dated cremation burials were fitted into several chronological sequences. The results from the chronological models at both sites suggest that the creation of a burial mound was just one event within a much longer funerary history. For both sites, there are indications that the deceased were buried in flat graves decades and sometimes more than a century prior to any monument construction. Once in place, the barrows were then used as a repository for the dead for decades afterwards. At the same time, a comparison of the models suggests that funerary events at both sites were punctuated. At one site, several barrows were in use simultaneously, at the other, barrows seem to be each other's successor. The models provide evidence for both protracted histories as well as punctuated events.

Previous studies of live-collected pre-weapons testing mollusk shells in the northern Gulf of California have demonstrated that the local radiocarbon reservoir effect (ΔR) is large and highly variable. To test the validity of this observation for paired charcoal and shell samples from archaeological contexts, we dated samples from four shell midden locations and six midden layers from the eastern shoreline of the Gulf of California near Puerto Peñasco, Sonora, Mexico. Dated charcoal samples were small twigs or brushy plants used to cook shellfish and the shells dated within each midden showed signs of burning. Ages range from approximately 5700 to 1900 cal BP. The offset between the modeled marine 14C age for calibrated ages of the middens and measured shell 14C age (ΔR) averaged 425 yr with a standard deviation of 115 yr.

This article describes a new capability for high-precision 14C measurement of CO2 from air at the Rafter Radiocarbon Laboratory, GNS Science, New Zealand. We evaluate the short-term within-wheel repeatability and long-term between-wheel repeatability from measurements of multiple aliquots of control materials sourced from whole air. Samples are typically measured to 650,000 14C counts, providing a nominal accelerator mass spectrometry (AMS) statistical uncertainty of 1.3‰. No additional uncertainty is required to explain the within-wheel variability. An additional uncertainty factor is needed to explain the long-term repeatability spanning multiple measurement wheels, bringing the overall repeatability to 1.8‰, comparable to other laboratories measuring air materials to high precision. This additional uncertainty factor appears to be due to variability in the measured 14C content of OxI primary standard targets, likely from the combustion process. We observe an offset of 1.4‰ in our samples relative to those measured by the University of Colorado INSTAAR, comparable to interlaboratory offsets observed in recent intercomparison exercises.

One century after its discovery, the Columns Tomb of Kumbi Saleh (Mauritania) remains an archaeological riddle. Since 1914, six field programs have been successively carried out at the medieval urban site of Kumbi Saleh, which now is commonly identified as Ghana. The latter was the famous capital city of the medieval West African state, which controlled the gold mines of West Africa and was involved in the gold trade with North Africa and the Mediterranean Basin. However, interpretation of the tomb, the largest structure from the necropolis, is still an issue as its dating itself has never been firmly established. As a consequence, scholars have usually referred to an unsatisfactory timeframe spanning 1000 years. The study of this monument was recently resumed, motivated by the rediscovery of bones collected in the tomb in 1914 and stored at the Musée de 1'Homme (Paris, France). AMS radiocarbon dating of the bone and tooth apatite fraction of three skulls demonstrates that the three individuals occupying the main vault of the tomb died between the end of the 11th century and the 12th century, precisely at the time of expansion of the Muslim Almoravid movement south of Sahara.

In the framework of the European Research Council-funded project, “Reconstructing Ancient (Biblical) Israel: The Exact and Life Sciences Perspective,” we carried out multiple analyses on iron and bronze objects from provenanced contexts in Israel, as well as on previously unidentified metallurgical remains from the production of both metals. In addition, we counted anew iron and bronze objects from well-stratified contexts and studied metalworking sequences at major sites, which included those that had undergone the bronze/iron transition. This enabled us to clarify some of the issues related to the bronze/iron transition in the southern Levant. Using this evidence, we showed that iron was not used for utilitarian purposes before the Iron I (late 12th century BCE) and that iron only became dominant concurrently with the beginning of its systematic production during the Iron IIA (10th–9th centuries BCE). A strong correlation between iron and bronze production suggests that during the Iron I local independent bronzesmiths adopted the new iron technology. Under local administrations that developed during the Iron IIA, workshops that previously produced bronze turned to iron production, although they continued to manufacture bronze items as a secondary venture. Significantly, at some of the major urban centers iron production was an independent industry that included the entire operational sequence, including the on-site smelting of the ore. This development appears to have been a major contributor to the transition to systematic production of iron.

An overview of current knowledge on the human paleodiet of the southern Russian Far East is presented. The earliest data are available for the Neolithic complexes of Primorye Province, dated to ~7000–5800 BP. For 10 humans from the coastal site of Boisman 2, a heavy reliance on marine fish and mammals (~70–80% of the total diet) has been established; this is similar to the Jomon and Chulmun complexes of Hokkaido Island and Korea. For two individuals from the inland site of Chertovy Vorota, a mixture of terrestrial and riverine (including anadromous species such as salmon, ~25% of the total diet) food resources is evident. In the Amur River basin, the diet of the Paleometal (i.e. Bronze/Early Iron Ages) population (dated to ~2500–1800 BP) was probably based on a mixture of C4 plants (millet, ~50–60% of the total diet), C3 plants, and terrestrial animals, while in the Middle Ages (~1500–300 BP) the contribution of C4 food was lower at ~20–25%. On Sakhalin Island, the maritime-oriented economy existed for a long time, at least since the Late Neolithic/Paleometal Age (dated to ~2500–1800 BP) and until the ethnographic time period (from the 17th–18th centuries AD onwards). Up to ~80–90% of the diet consisted of marine mammals and fish, and this is in accord with dietary patterns of the Epi-Jomon and Okhotsk cultural complexes on Hokkaido Island. Information on the paleodiet of the coastal populations of the Japan and Okhotsk Seas should be taken into account when calibration of 14C dates run on human bones from these regions is undertaken, because the predominant consumption of marine food caused a distortion of the true 14C age.

The determination of radiocarbon content in biogenic samples such as tree leaves and short-lived plants is crucial when studying the anthropogenic impact on the ecosystem and for detecting any alteration in stable and radioactive CO2. A total of 76 samples of evergreen and deciduous tree leaves as well seasonal plants were collected in winter, spring, and summer. Sampling was carried out from rural villages located in Mount Lebanon Province, Lebanon. Based on the data obtained from a previous study carried out in autumn, which showed that the selected sites are characterized by depletion of 14C caused by the releases of pollutants and CO2 from a cement factory in the region, further investigation was carried out in the present work to determine possible significant seasonal variations in Δ14C values. Reference samples of identical species were collected in the same period from a clean zone. The conventional 14C method was used to determine the carbon isotopic ratio. Δ14C data are compared to those obtained in autumn. 14C concentration in the studied sites was significantly lower than in the clean area in all seasons. ANOVA tests showed that there is a significant seasonal variation for deciduous leaves and seasonal plants, while this difference was not significant in evergreen leaves. In addition, no significant variation was recognized for different species in the same season.

This article reviews recent studies of pigs in the Iron Age in the southern Levant. The studies were carried out as part of the European Research Council-funded Ancient Israel project, with the aim of examining questions of identity and ethnic boundaries, with special emphasis on Philistia and ancient Israel. On the Philistine side, the results show a dichotomy in pork consumption between urban centers and the rural sector, and suggest that European domestic pigs were brought to the Levant by the Sea Peoples, most probably to secure the supply of meat. Reviewed with previous evidence, we suggest that economic motivation was the driving force for pork consumption and abandonment. Regarding ancient Israel, new studies show that avoiding pork was a widespread phenomenon of much of the Iron Age in both the highland and the lowlands outside of Philistia. They also point to a rise in pork consumption in lowlands sites of the Northern Kingdom in the Iron IIB and suggest a link between this phenomenon and the early consolidation of the taboo on pigs in Judah in late-monarchic times.

A program of paired dating of human and faunal remains on a sample of 11 prehistoric (Mesolithic/Neolithic to Early Bronze Age) graves in the Upper Lena basin, southeast Siberia, was initiated to investigate the freshwater reservoir effect (FRE). The results show the presence of a substantial but highly variable offset, ranging from 255 to 1010 14C yr. In contrast to previous studies centered on Lake Baikal and the Angara River, human stable nitrogen isotope values show little or no correlation with the radiocarbon offset, despite the clear trophic differences seen in δ15N between terrestrial and aquatic sources of protein in the region's isotope ecology. However, stable carbon isotope measurements show a moderate negative correlation of some predictive value (r = −0.70, p = 0.016, df = 10). Two different regression equations have been calculated, the first using human δ13C values for the entire data set (r2 = 0.49) and the second, using both δ13C and δ15N values, limited to the Early Bronze Age of the southern Upper Lena (r2 = 0.84, p = 0.030, df = 5). The source of the old carbon in the Upper Lena River system is not clear. While the river flows over carbonate bedrock and is moderately alkaline, we suggest that old terrestrial carbon entering the riverine foodweb through bank erosion and other processes is a more likely candidate for the majority of the 14C offset.

The Late Bronze Age to the Iron Age transition involves profound cultural and political changes in the southern Levant. The transition is dated to the 12th century BC, based on archaeological artifacts and historical documents. A more precise absolute date for this transition for the southern Levant based on radiocarbon is difficult since the 14C calibration curve reduces precision significantly due to wiggles that form an approximately 200-yr-long plateau. This article analyzes 14C samples from the Late Bronze Age to the Iron Age transition at Qubur el-Walaydah. To increase the resolution of 14C dates within the plateau, 14C samples were collected only from well-defined multilayered contexts. 14C dates from 11 contexts were obtained and these were analyzed using a Bayesian model that incorporated the stratigraphic information. Using this integrative approach we date the Late Bronze Age III levels at Qubur el-Walydah, containing the initial phase of locally produced Philistine pottery between 1185–1140 BC, and the Late Bronze to Iron Age transition between 1140–1095 BC.

In 1954, B K Thapar excavated the multicomponent site of Maski (Raichur District, Karnataka) to establish an archaeological sequence for the southern Deccan region of India. Thapar identified four major periods of occupation, now known as the Neolithic (3000–1200 BC), Iron Age (1200–300 BC), Early Historic (300 BC to AD 500), and the Medieval periods (AD 500–1600). Renewed research at the site by the Maski Archaeological Research Project (F.1/8/2009-EE) has investigated the development of social differences and inequalities in south Indian prehistory. This article reports the first ever radiocarbon assays from habitation and megalithic burial contexts in the vicinity of Maski. Accelerator mass spectrometry (AMS) dates of charcoal sampled from exposed occupational strata on Maski's Durgada Gudda hill and subsequent Bayesian analyses indicate that the site was extensively occupied during the 14th century AD, corroborating interpretations of numismatic and inscriptional materials. Associated artifacts with these 14C samples have significant implications for recognizing late Medieval period ceramics and occupation in the region. AMS assays of four charcoal samples from exposed megalithic burials just south of the Durgada Gudda hill, similar to those recognized by Thapar, indicate that burial practices commonly attributed to the Iron Age predate the period, and thus are not precise chronological markers. However, the results also suggest that megalithic burial practices became more labor intensive during the Iron Age, creating a cultural context for the generation of new forms of social affiliations and distinctions through differential participation in the production of commemorative places.