In the early 1900s more and more experimental evidence was accumulated indicating that microscopic particles show wave-like properties in certain situations. These particle-wave features are very evident, e.g., in measurements where electrons are diffracted from a double slit to propagate toward a screen where they are detected. Based on the classical averaging of particles discussed in Section 1.2.2, one expects that the double slit only modulates the overall intensity, not the spatial distribution. Experimentally, however, one observes a nearly perfect interference pattern at the screen implying that the electrons exhibit wave averaging features such as discussed in Section 2.1.2. This behavior, originally unexpected for particle beams, persists even if the experiment is repeated such that only one electron at a time passes the double slit before it propagates to the detection screen. Thus, the wave aspect must be an inherent property of individual electrons and not an ensemble effect.

Another, independent argument for the failure of classical physics is that the electromagnetic analysis of atoms leads to the conclusion that the negatively charged electron(s) should collapse into the positively charged ion because the electron–ion system loses its energy due to the emission of radiation. As we will see, this problem can be solved by including the wave aspects of particles into the analysis. In particular, as discussed in Section 2.3.3, waves can never be localized to a point without increasing their momentum and energy beyond bounds.