Comparison of two sets of marsh-accumulation records from each of three Connecticut (USA) salt marshes, one based on individually calibrated dates and the other on wiggle-match dating of the same series of dates, shows that wiggle-match dating results in more precise and objective reconstructions of longer-term (102–103 yr) changes in accumulation rate. On (sub-)century time scales, wiggle-match dating can reveal steps in the calibrated marsh-accumulation envelope as artefacts of the calibration curve, but may also leave real short-term changes in accumulation rate undetected. Wiggle-matches are non-unique, being dependent on the number, quality and distribution of radiocarbon dates in a sequence, how a series of dates is subdivided into groups (representing intervals of uniform accumulation rate), and what is considered a “best match”. Samples from the studied salt-marsh deposits required no correction for reservoir effects prior to calibration.

Since the early 1950s, the Sellafield nuclear fuel reprocessing plant in Northwest England has released radiocarbon into the Irish Sea in a mainly inorganic form as part of its authorized liquid effluent discharge. In contrast to the trend in which the activities of most radionuclides in the Sellafield liquid effluent have decreased substantially, 14C discharges have increased since 1994–95. This has largely been due to a policy change favoring marine discharges over atmospheric discharges. 14C is radiologically important due to its long half life, mobility in the environment, and propensity for entering the food chain. Current models for radionuclide dispersal in the Irish Sea are based on a reversible equilibrium distribution coefficient (kd), an approach which has been shown to be inadequate for 14C. Development of predictive models for the fate of Sellafield-derived 14C requires a thorough understanding of the biogeochemical fluxes between different carbon reservoirs and the processes controlling the net flux of 14C out of the Irish Sea, through the North Channel. In this study, both an empirical and a halving time approach indicate that close to 100% of the 14C that is discharged from Sellafield is dispersed beyond the Irish Sea on a time-scale of months in the form of DIC, with little transfer to the PIC, POC, and DOC fractions, indicating that the “dilute and disperse” mechanism is operating satisfactorily. This is consistent with previous research that indicated little transfer of 14C to Irish Sea sediments. While significant 14C enhancements have been observed in the biota of the Irish Sea, this observation is not necessarily in conflict with either of the above as the total biomass has to be taken into account in any calculations of 14C retention within the Irish Sea.

The earliest dating of samples taken from logboats found in the area of Poland was done at the Gliwice Radiocarbon Laboratory in the late 1970s and early 1980s. After a 10-year break, the study of their chronology was renewed. The 14C dates (56) include all previously published and new, unpublished results obtained during last several years. Here, we discuss and provide probabilistic interpretation of the calendar age of the dated boats. The calibration of 14C dates was done with the OxCal program for dates less than 300 BP, and with the GdCALIB program for all remaining dates. In distribution of calibrated dates we find a lack of samples between the ages of around 800 BC and 300 AD. This result is surprising and differs from results observed for Central Europe. The remaining age ranges, with high frequency of dates, are in good coincidence with similar periods obtained for Central Europe.

Tree-ring dating of oak logboats was carried out on 60 growth sequences, dated against standard chronologies defined for the area of Poland. The results of 14C dating and tree-ring analyses give consistent chronologies.

Radiocarbon has been an important constituent of radioactive wastes dumped in the open ocean and marginal seas as well as wastes released from nuclear reprocessing plants. Therefore, in some regions these sources could have a greater impact on 14C concentration in seawater than global fallout. The high analytical sensitivity of 14C measurement by accelerator mass spectrometry (AMS) allows even tracer amounts of 14C to be found in seawater at radioactive waste dumping sites and their comparison with the global distribution of this radionuclide. Data on measurements of 14C in samples taken at former dumping sites in the northeast Atlantic and northwest Pacific Oceans and in the open ocean are discussed and compared with other anthropogenic radionuclides, namely 3H. Small increases in 14C concentrations observed in some bottom and surface seawater samples collected at the Northwest Pacific Ocean dumping sites require further 14C analyses before final conclusions can be made on possible leakages from dumped radioactive wastes.

We propose a new method of cross-dating the wood samples based on the classical methods of spectral estimation. This method uses the average cross-spectral density as a function of the relative position of the series. Because it is not sensitive to phase shifts in data it is appropriate for cross-dating samples originating from geographically distinct areas.

The accuracy of cross dating depends on the integrity of the samples used, and in the case of well-preserved wood samples, the precision of relative age comparison may reach a single year. The method was tested on two dendrochronological series from Scythian barrows of known age in Southern Siberia: the Pazyryk barrows (the Altai Mountains) and the Dogee-Baary-2 burials (Western Sayan Mountains) separated by 450 km. The analysis has shown that the Pazyryk barrow is younger by 80 ± 4 yr than the Dogee-Baary −2 burials. This result is in agreement with the new chronology of Scythian-related sites suggested for Southern Siberia and Central Asia.

Beach rock is a good indicator of the past sea levels, as it is considered to have been formed within the range of intertidal zone. Radiocarbon dates of beach rocks collected from Iriomote Island, Ishigaki Island, and Miyako Island, in the southern part of the Nansei Islands, indicate that the beach rocks were formed between around 4000 BP and 400 BP. Late Holocene sea-level changes were revealed based on the elevations and 14C dates of the beach rocks. The results indicate that the sea level was similar to the present one for at least the past 4000 BP. Isotopic fractionations (δ13C) of the beach rocks were between +9.40% and −0.08%, suggesting a different origin for calcium carbonate.

In comparison with windward coral reefs, the facies and evolution of leeward coral reefs has been discussed to a lesser extent. By accelerator mass spectrometry (AMS) carbon-14 dating of coral specimens collected from the trench excavated across a modern coral reef during a fishery port repair, we revealed the internal facies and Holocene evolution of a leeward reef in Ishigaki Island, Ryukyu Islands, southwest Japan. The reef facies can be split into three facies: the tabular Acropora framework facies, the tabular Acropora reworked facies, and the unconsolidated bioclast facies. The tabular Acropora reworked facies first formed a ridge by 3500 BR Then, the tabular Acropora framework facies grew both upward and seaward. The accumulation rates of the tabular Acropora framework facies ranged from 2.2 to 8.3 m/ka. Thus, the reef framework facies and accumulation rates of this leeward reef is similar to those of windward reefs, although the age of the reef top is younger than that of windward reefs.

The Bayesian approach to calibration of radiocarbon dates was used to wiggle-match the “floating” tree-ring chronology from a Pazyryk culture (Scythian-type complex from Sayan-Altai Mountain system, southern Siberia) burial ground in order to estimate the calendar age of its construction. Seventeen bidecadal tree-ring samples were 14C dated with high precision (±20–30 yr). The results of wiggle-matching show that the Pazyryk-type burial mounds in the southern Altai Mountains were created in the first part of 3rd century BC.

Seasonal variations of δ13C were analyzed for two Japanese cypress trees (Chamaecyparis obtusa), one buried and one living. Both trees were different in age but sampled in areas geographically close to each other in central Japan. A buried cypress with 394 annual rings was excavated from Old Fuji mudflow, the last glacial strata of the dormant Mt. Fuji volcano. The accelerator mass spectrometry (AMS) radiocarbon date of this glacial sample was 18,600 ± 120 BP (NUTA–4884). A living tree stem, which has 192 rings, was cut from the Izu Peninsula in 1986. In order to measure the seasonal δ13C fluctuation, the tree rings were divided equally into three earlywood and one or two latewood consecutive sections. The δ13C value within an annual ring generally increased from the first to the third or fourth sections then decreased in the last section. This pattern of the variation was similar in the glacial and modern samples. The δ13C value within an annual ring seems to be controlled by environmental factors (not plant physiological ones), since there was no isotopic shift in the seasonal δ13C variation at the earlywood-latewood boundary, which was controlled by plant physiology. The result suggests the potential to reconstruct the paleoenvironment within a year using the seasonal δ13C variation, though site-specific conditions such as soil characteristics would also affect to its fluctuation.

Appropriate dating tools are essential for paleoenvironmental studies. Cosmogenic 32Si with a half-life of about 140 years is ideally suited to cover the dating range 30–1000 years. Here we have applied scintillation spectrometry for detection of natural 32Si to date marine shelf sediments. High detection efficiency, combined with stable background, allows for the detection of extremely low 32Si specific activities found in such sediments with counting rates below one count per hour. For a sediment core from the Ganges-Brahmaputra delta 32Si dating yields mean sedimentation rates of 0.7 ± 0.2 cm/yr for 50 to several hundred years BP and 3.1 ± 0.8 cm/yr for the past 50 years. The four-fold increase of the sedimentation rate over the past 50 years may reflect increased sediment loads in the rivers due to increasing human colonization within the rivers' drainage basins.

We performed a statistical analysis of the data on summer temperature anomalies in northern Fennoscandia (8–1995 AD) and found that a 70–130-yr cycle is present in this series during most of the time period. A comparison of the reconstructed northern Fennoscandia temperature with different indicators of solar activity (Wolf numbers, the length of solar Schwabe cycle, extended bi-decadal radiocarbon series, and data on sunspots observed by naked eye) shows that the more probable cause of the periodicity is the modulation of regional northern Fennoscandia climate by the long-term solar cycle of Gleissberg. The effect of this century-scale solar modulation of the global Northern Hemisphere temperature is weaker.

A geochronological survey of the Bengal shelf area involved results from more than 20 sediment cores dated using gamma spectrometry and the nuclides 137Cs, 228Ra, 226Ra, and 210Pb. In some cores, which contained older sediments, 32Si and 14C were determined to examine the possibility to extrapolate the obtained chronologies to century and millennial scale. Geochronological work in this region is faced with problems of cyclone-induced sediment reworking, grain-size effects on fallout nuclides, scarcity of carbonates, unknown 14C reservoir effect and sedimentation rates that are too high to obtain sediment cores long enough to establish a chronology. Despite these problems, comparison between the results of the different dating methods provided the most reliable sediment balance to date for the submarine delta of the Ganges-Brahmaputra river system and indicated that on a time scale of several centuries at least 35% of the annual sediment load is deposited.

We have measured the radiocarbon content of tree rings from a section of Huon pine retrieved from Tasmania. The sample was divided into 39 five-ring sub-samples covering a period of 194 years. Radiocarbon ages of each of these sub-samples was determined by making four measurements of each sub-sample at the Arizona AMS laboratory (Table 1). The resulting 1σ precisions are about 0.5%. A comparison of our data with the appropriate curve in INTCAL98 indicates that the calendar age of our sample is close to 14,000 cal BP. Using this age calibration, we have constructed a plot of Δ14C versus assumed calendar age. This plot shows an essentially constant value over the youngest 125 rings of our sample. Over the oldest 75 yr of the sample, the Δ14C curve exhibits three fluctuations, the largest of which is about 65‰. The time of the peaks in the Huon-pine 14C curve corresponds approximately with the European Bølling/Allerød climatic event. Work is in progress to extend the data 100 yr more toward older ages.

In recent years, the most common technique for radiocarbon dating of deep-ocean sediments has been accelerator mass spectrometry (AMS) analysis of hand-picked planktonic foraminifera (forams). Some studies have exposed age offsets between different sediment size fractions from the same depth within a core and this has important implications when establishing a chronological framework for palaeoceanographic records associated with a particular sediment component. The mechanisms generating the age offsets are not fully understood, a problem compounded by the fact that the fraction defined as “large” varies between different studies. To explore this problem, we dated samples of hand-picked forams from two Biogeochemical Ocean Flux Study (BOFS) cores, for which the presence of an offset between the bulk carbonate and >150 μm foraminiferal calcite had already been demonstrated. The presence of a constant age offset between bulk carbonate and coarse fraction material at the two BOFS sites has been confirmed, but the magnitude of the offset is dependent on whether a simple size-separation technique or hand-picking of well-preserved forams is applied. This may be explained if the selection of well preserved forams biases the sample towards those specimens that have spent least time in the surface mixed layer (SML) or have undergone less size selective mixing. Modeling of the 14C profiles demonstrates that SML depth and sediment accumulation rates are the same for both the bulk and coarse sediment fractions, which is consistent with the hypothesis that size-selective mixing is responsible for the age offset.

Human bones from single inhumation burials and artifacts made from terrestrial mammal (ungulate) bone found in direct association with the skeletons were obtained from the Stone Age site of Schela Cladovei situated just below the Iron Gates Gorge of the River Danube. The results of stable isotope analyses of the human bone collagen are consistent with a heavy dependence on aquatic protein while radiocarbon dating of the samples reveals an offset of 300–500 years between the two sample types, indicating a freshwater reservoir effect in the human bone samples. Since protein consumption is by far the major source of nitrogen in the human diet we have assumed a linear relationship between δ15N and the level of aquatic protein in each individual's diet and derived a calibration for 14C age offset versus δ15N which has been applied to a series of results from the site at Lepenski Vir within the gorge. The corrected 14C ages (7310-6720 BP) are now consistent with the previous 14C age measurements made on charcoal from related contexts (7360–6560 BP). In addition, the data indicate a change from a primarily aquatic to a mixed terrestrial/aquatic diet around 7100 BP and this may be argued as supporting a shift from Mesolithic to Neolithic. This study also has wider implications for the accurate dating of human bone samples when the possibility exists of an aquatic component in the dietary protein and strongly implies that δ15N analysis should be undertaken routinely when dating human bones.

Variability in surface and deep ocean circulation in the North Atlantic is inferred from grain-size characteristics and the composition of terrigenous sediments from a deep-sea core taken on Reykjanes Ridge, south of Iceland. End-member modeling of grain size data shows that deep-ocean circulation in this area decreased significantly during periods of maximum iceberg discharge. The episodes of reduced circulation correlate with the cold and abrupt warming phases of the Dansgaard-Oeschger cycles as recognized in the Greenland ice cores.

Calibration is essential for interpretation of radiocarbon dates, especially when the 14C dates are compared to historical or climatic records with a different chronological basis. 14C ages of samples from the marine environment, such as shells or fish bones, or samples with a marine component, such as human bone in coastal regions, require an additional consideration because of the reservoir age of the ocean. While the pre-industrial global mean reservoir correction, R(t), is about 400 years, local variations (ΔR) can be several hundred years or more. ΔR compilations on a global scale have been undertaken previously (Stuiver et al. 1986; Stuiver and Braziunas 1993), but have not been updated recently. Here we describe an on-line reservoir correction database accessed via mapping software. Rather than publishing a static ΔR compilation, new data will be incorporated when it becomes available. The on-line marine reservoir correction database can be accessed at the website http://www.calib.org/.

Compound-specific radiocarbon analysis of five fatty-acid biomarkers was conducted for marine sediments collected from the western North Pacific. The fatty acids (C12 to C34) showed a typical bimodal distribution pattern with two maxima at C16 and C26. Their carbon isotopic compositions ranged from −25.1‰ (C16) to −31.8‰ (C28), suggesting that they derived from terrestrial higher plants and marine organisms. A large variations of 14C ages were found among the fatty acids detected in the same sedimentary horizon of the core, ranging from 530 BP (C18) to 3250 BP (C28). The results of 14C analysis of fatty acids could be divided into two groups, i.e., lower molecular weight (LMW) fatty acids (C16, C18) derived from marine organisms and higher molecular weight (HMW) fatty acids (C24, C26, C28) derived from terrestrial higher plants. The HMW fatty acids showed older ages, ranging from 2550 BP (C24) to 3250 BP (C28), than LMW fatty acids (530 BP [C18] to 1,820 years BP [C16]). On the other hand, bulk-phase total organic matter (TOM) showed the age of 2260 BP that is between those two groups, suggesting that it was likely a mixture of organic matter derived from marine and terrestrial sources. The compound specific 14C ages and δ13C data of sedimentary fatty acids presented here could provide useful information to decipher the fate and transport process of terrestrial organic matter to marine sediments.

Faunal remains originating from terrestrial and marine mammals, and belonging to the same archaeological deposits were compared to evaluate the marine radiocarbon reservoir ages around the Hokkaido island, Japan. From five shell middens of different ages from the Jomon period (4900 BP) to the Ainu cultural period (800 BP), 107 animal bone samples were selected for radiocarbon measurements. The apparent age differences between Japanese deer and northern fur seal showed the clear effect of deep-water upwelling in this region. Our data showed relatively stable age differences from 4500 BP to 800 BP, with an estimated ΔR values around 380 14C yr. Results are consistent with previous estimation based on simulation models and oceanographic properties.

Radiocarbon dating was carried out in the sediment profiles of four marine sediment cores taken from Iskenderun Bay, Turkey. The bay is quite shallow in the present day, and a previous tectonic study had considered that the bay floor might have been subsiding. However, this cannot be so, for the 14C ages would thereby lead to the apparent paradox of normal marine sedimentation having taken place during times when glacio-eustatic sea level lowering would have exposed the bay floor. Rather, we conclude that the floor of Iskenderun Bay on the whole has been experiencing rapid uplift since the end of the Last Glacial, due to a combination of tectonic factors linked to the compression between the Anatolian and African plates.