Namurian alkali-dolerites in W and central Fife comprise up to nine component sills. These have three-dimensional shapes which are directly related to penecontemporaneous structures in the sedimentary host rocks. Two forms of control are identified. Basinal control is apparent where restored sill geometry shows thickening towards the bottoms of saucer-shapes which mimic sediment disposition at the time of emplacement. Fault control is evidenced by sills which change horizon along extensive E–W fractures once assumed to be entirely post-Carboniferous but now confirmed as growth-faults.

There are no associated dykes representing likely feeders comparable with those of the later tholeiitic Midland Valley Sill, but evidence is presented to suggest that at least some of the alkali-dolerite magma reached sill intrusion levels through volcanic pipes.

Proximal braided stream deposits of the Old Red Sandstone of central Scotland are characterised by a variety of upward coarsening units formed during downstream migration gravel bars. Transitional variations in thickness, grain size and structure of these units, and their associated sediments are used to establish facies and paths of facies change (lineages). Three facies lineages are recognised which are interpreted as recording the downstream changes the structure of sediments of three different types of braided river systems. Lineages differ from each other in proportion of sandstone, channel depth and the structure of upward coarsening units: lineage 1 represents alluvium formed in a river system which produced texturally mature gravels and which increased in depth downstream; lineage 2 comprises sediments deposited in shallow channels which become shallower downstream; lineage 3 represents a downstream change from conglomerate to sandstone and from an unchannelled to achannelled regime.

Stream depth and ratio of sand to gravel exert fundamental controls on the structure of alluvium. Thick (thickness >50 m) sections showing vertical changes in clast size often comprise single facies lineage. Thick upward coarsening sequences are found with lineages 2 or 3 and upward fining with lineage 1 or 3.

A 49 m complete section through the 288 Ma Lugar Sill obtained from drill cores can be subdivided into nine units. The uppermost four units are teschenitic and are mirror images of the bottom four. A 35 m thick central unit consists of theralite passing down into kaersutite theralite and then picrite. Marginal chilling 'of the units indicates multiple intrusion from the outside inwards. Olivine in the central unit (Fo88–90) encloses Cr-rich spinels and increases in amount inwards to over 50%. Clinopyroxene, kaersutite and biotite show symmetrically increasing Fe/Mg from the centre of the sill outwards. Most major and trace elements vary symmetrically throughout the sill with those in the central unit reflecting mainly olivine distribution but incompatible elements exhibit upward enrichment. Remarkably, the most-evolved rocks in the sill are at its margins. The sill was formed by multiple injections of successively less-evolved teschenitic magmas followed by a larger pulse of theralitic liquid carrying abundant olivine phenocrysts. The amount of olivine in this final pulse increased during emplacement. Subsequent in-situ differentiation in the central unit, with upward enrichment in residual liquid and volatiles, gave rise to lugarites. The various magmas were produced in a lower-level magma chamber by differentiation of a mantle-derived, alkali-rich picritic magma.

Post-Variscan magmatism in SW England involved the synchronous emplacement of basaltic and potassic lavas, minette dykes and the Cornubian granite batholith at c. 290 Ma. The basaltic and potassic rocks have high contents of Ni and Cr, which suggest that both are not excessively fractionated. The basaltic lavas are moderately enriched in LREE and LIL elements relative to HREE, whereas the chemically-varied potassic lavas are more strongly enriched in LREE and LIL elements, with notable depletions in Nb, Ta and Ti relative to LREE. These features are consistent with the view that these rocks are subduction-related. Possibly the potassic rocks were derived from an ultimate source in lithosphere subducted or downthrust during the Variscan orogeny. The source of the basaltic rocks was probably in the asthenosphere. The minette dykes are chemically similar to the potassic lavas, suggesting that they are genetically related. Most dykes occur in a zone up to 25 km wide around the margin of the granite batholith, in a “shadow-zone” relationship. The granite batholith (c. 48,000 km3) is moderately enriched in Th and HFS elements, but is strongly enriched in Rb. Rb-Th relationships indicate an origin for the granite by fractionation from potassic magma in addition to melting of crust.

Potassium (K)-rich volcanic rocks occur within Permian sedimentary rocks in SW England and are approximately contemporaneous with the emplacement of the Cornubian granite batholith. The volcanic rocks have chemical characteristics of subduction-related magmas and may have been derived by small amounts of partial melting of heterogeneous large-ion lithophile (LIL) enriched mantle with the assemblage olivine–pyroxene–garnet–phlogopite–titanate. The LIL enrichment may have occurred during shallow or oblique subduction of oceanic lithosphere below SW England during the Devonian and Carboniferous. Such LIL-enriched mantle may have contributed some components to the Cornubian granite batholith.