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ART. 176 - On the Theory of Surface Forces

Published online by Cambridge University Press:  05 July 2011

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Summary

Since the time of Young the tendency of a liquid surface to contract has always been attributed to the mutual attraction of the parts of the liquid, acting through a very small range,—to the same forces in fact as those by which the cohesion of liquids and solids is to be explained. It is sometimes asserted that Laplace was the first to look at the matter from this point of view, and that Young contented himself with calculations of the consequences of superficial tension. Such an opinion is entirely mistaken, although the authority of Laplace himself may be quoted in its favour. In the introduction to his first paper, which preceded the work of Laplace, Young writes:—“It will perhaps be more agreeable to the experimental philosopher, although less consistent with the strict course of logical argument, to proceed in the first place to the comparison of this theory [of superficial tension] with the phenomena, and to inquire afterwards for its foundation in the ultimate properties of matter.” This he attempts to do in Section VI., which is headed Physical Foundation of the Law of Superficial Cohesion. The argument is certainly somewhat obscure; but as to the character of the “physical foundation” there can be no doubt.

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Scientific Papers , pp. 397 - 425
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1902

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