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ART. 192 - Experiments upon Surface-Films

Published online by Cambridge University Press:  05 July 2011

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Summary

The experiments here described are rather miscellaneous in character, but seem of sufficient interest to be worthy of record. The greater number of them have been exhibited in the course of lectures at the Royal Institution.

The Behaviour of Clean Mercury

According to Marangoni's rule, water, which has the lower surfacetension, should spread upon the surface of mercury; whereas the universal experience of the laboratory is that drops of water standing upon mercury retain their compact form without the least tendency to spread. To Quincke belongs the credit of dissipating the apparent exception. He found that mercury specially prepared behaves quite differently from ordinary mercury, and that a drop of water deposited thereon spreads over the whole surface. The ordinary behaviour is evidently the result of a film of grease, which adheres with great obstinacy.

The process described by Quincke is somewhat elaborate; but my experience with water suggested that success might not be so difficult, if only the mistake were avoided of pouring the liquid to be tried from an ordinary bottle. In the early experiments upon the camphor movements difficulty seems to have been experienced in securing sufficiently clean water surfaces. The explanation is probably to be found in the desire to use distilled water, and to the fact that the liquid would usually be simply poured from a stock bottle into the experimental vessel. No worse procedure could be devised; for the free surface in the bottle is almost sure to be dirty, and is transferred in great part to the vessel.

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Scientific Papers , pp. 562 - 571
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1902

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