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ART. 170 - On the Superficial Viscosity of Water

Published online by Cambridge University Press:  05 July 2011

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Summary

The idea that liquids are endowed with a viscosity peculiar to the surface is to be found in the writings of Descartes and Rumford; but it is to Plateau that its general acceptance is due. His observations related to the behaviour of a compass needle, turning freely upon a point, and mounted in the centre of a cylindrical glass vessel of diameter not much more than sufficient to allow freedom of movement. By means of an external magnet the needle was deflected 90° from the magnetic meridian. When all had come to rest the magnet was suddenly removed, and the time occupied by the needle in recovering its position of equilibrium, or rather in traversing an arc of 85°, was noted. The circumstances were varied in two ways: first, by a change of liquid, e.g., from water to alcohol; and, secondly, by an alteration in the level of the liquid relatively to the needle. With each liquid observations were made, both when the needle rested on the surface, so as to be wetted only on the under side, and also when wholly immersed to a moderate depth. A comparison of the times required in the two cases revealed a remarkable dependence upon the nature of the liquid. With water, and most aqueous solutions, the time required upon the surface was about double of that in the interior; whereas, with liquids of Plateau's second category, alcohol, ether, oil of turpentine, &c., the time on the surface was about half of the time in the interior.

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Scientific Papers , pp. 363 - 375
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1902

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