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1853. On the Metallic Reflexion exhibited by certain Non-Metallic Substances

Published online by Cambridge University Press:  07 September 2010

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In the October Number of the Philosophical Magazine is a translation of a paper by M. Haidinger of Vienna, containing an account of his observations relating to the optical properties of Herapathite. In this paper he refers to a communication which I made to the British Association at the meeting at Belfast; and indeed one great object of his examination of this salt was to see whether a law which he had discovered, and already extensively verified, relating to the connexion between the reflected and transmitted tints of bodies which have the property of reflecting a different tint from that which they transmit, would be verified in this case. The report of my communication published in the Abbé Moigno's Cosmos had led him to suppose that my observations were at variance with his law.

My attention was first directed to this subject while engaged in some observations on safflower-red (carthamine), which I was led to examine with reference to its fluorescence. In following out the connexion which I had observed to exist between the absorbing power of a medium and its fluorescence, I was induced to notice particularly the composition of the light transmitted by the powder; and I found that the medium, while it acted powerfully on all the more refrangible rays of the visible spectrum, absorbed green light with remarkable energy. I need not now describe the mode of absorption more particularly. During these experiments I was struck with the metallic yellowish-green reflexion which this substance exhibits.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1904

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