We have observed 18 nearby dusty elliptical galaxies in the near- to far-infrared with Spitzer and AKARI. We have found that polycyclic aromatic hydrocarbons are present in 14 out of the 18 elliptical galaxies.

We made near- to mid-infrared imaging and spectroscopic observations of the dwarf galaxy NGC 1569 with the Infrared Camera (IRC) on board AKARI. The unidentified infrared (UIR) band features at 6.2, 7.7, and 11.2 μm, which are generally attributed to polycyclic aromatic hydrocarbons (PAHs), are clearly detected in a structure associated with an Hα filament. The filament is filled with X-ray emission and is thought to be formed by outflow from the galaxy. Since PAHs are destroyed rapidly in hot plasma, it is most likely that PAHs in the filament are produced from fragmentation of large carbonaceous grains in the shock. We also detect excess emission in 2–5 μm in the filament, which may come from very small grains.

Three-millimeter-wavelength spectra of a number of nearby galaxies have been obtained at the Five College Radio Astronomy Observatory (FCRAO) using a new, very broadband receiver. This instrument, which we call the Redshift Search Receiver, has an instantaneous bandwidth of 36 GHz and operates from 74 to 110.5 GHz. The receiver has been built at UMass/FCRAO to be part of the initial instrumentation for the Large Millimeter Telescope (LMT) and is intended primarily for determination of the redshift of distant, dust-obscured galaxies. It is being tested on the FCRAO 14 m by measuring the 3 mm spectra of a number of nearby galaxies. There are interesting differences in the chemistry of these galaxies.

We are studying the Central Molecular Zone (CMZ) in the inner few degrees around the Galactic Centre, by mapping multiple 3-mm molecular lines, with the 22-m Mopra telescope. During 2006, we covered a 5 × 5 arcmin2 area of the Sagittarius B2 molecular cloud complex (Jones et al. 2008). We find substantial differences in chemical and physical conditions within the complex. We show some results here of Principal Component Analysis (PCA) of line features in this Sgr B2 area. During 2007 we covered the larger region of longitude −0.2 to 0.9 deg. and latitude -0.20 to 0.12 deg., including Sgr A and Sgr B2, in the frequency range 85.3 to 91.3 GHz. This includes lines of C3H2, CH3CCH, HOCO+, SO, H13CN, H13CO+, SO, H13NC, C2H, HNCO, HCN, HCO+, HNC, HC3N, 13CS and N2H+.

The interstellar medium (ISM) spectrum is usually explained by the response of dust particles (DPs) to the absorption of ultraviolet (UV) and visible (VIS) photons from nearby stars. With regard to the unidentified infrared (UIR) bands, the DPs are thought heated by UV and VIS photons to about 100 K thereby exciting the polycyclic aromatic hydrocarbons (PAHs). However, the UIR bands may be explained with the DPs at 2.7 K. To wit, the UIR bands form by the direct excitation of PAHs by infrared (IR) radiation induced from the absorption of cosmic microwave background (CMB) radiation in DPs by quantum electrodynamics (QED).

Anhydrous interplanetary dust particles (IDPs), which are the most mineralogically primitive extraterrestrial materials available for laboratory analysis, contain several percent organic matter. The high O:C and N:C ratios suggest the organic matter in the anhydrous IDPs is significantly less altered by thermal processing than the organic matter in meteorites. X-ray Absorption Near-Edge Structure (XANES) spectroscopy and infrared spectroscopy demonstrate the presence of C=C, most likely as C-rings, C=O, and aliphatic C-H2 and C-H3 in all the IDPs examined. A D-rich spot, containing material that is believed to have formed in a cold molecular cloud, has C-XANES and infrared spectra very similar to the organic matter in the anhydrous IDPs, possibly indicating a common formation mechanism. However the primitive organic matter in the IDPs differs from the interstellar/circumstellar organic matter characterized by astronomical infrared spectroscopy in the relative strengths of the asymmetric aliphatic C-H2 and C-H3 absorptions, with the IDP organic having a longer mean chain length. If both types of organic matter originated by the same process, this may indicate the interstellar organic matter has experienced more severe radiation processing than the organic matter in the primitive IDPs.

We have initiated an extensive program of molecular analysis of extraterrestrial organic matter isolated from a broad range of meteorites (spanning multiple classes, groups, and petrologic types), including recent molecular spectroscopic analyses of the organic matter in the Comet 81P/Wild 2 samples. The results of these analyses clearly reveal the signature of multiple reaction pathways that transformed extraterrestrial organic matter away from its primitive roots. The most significant molecular transformation occurred in the post-accretionary phase of the parent body. However, each of the various chemical transformation trajectories point unambiguously back to a common primitive origin. Applying a wide range of spectroscopic techniques we find that the primitive organic precursor is striking in its chemical complexity exhibiting a broad array of oxygen- and nitrogen-bearing functional groups. The π-bonded carbon exists as predominately highly substituted single ring aromatics, there exists no evidence for abundant, large, polycyclic aromatic hydrocarbons (PAHs). We find that the molecular structure of primitive extraterrestrial organics is consistent with synthesis from small reactive molecules, e. g. formaldehyde, whose random condensation and subsequent rearrangement chemistry at low temperatures leads to a highly cross-linked macromolecule.

The reflected spectral energy distribution of low-albedo, red-colored, airless bodies in the outer Solar System (planetary satellites, Centaur objects, Kuiper Belt objects, bare comet nuclei) can be modeled with spectral models that incorporate the optical properties of refractory complex organic materials synthesized in the laboratory and called tholins. These materials are strongly colored and impart their color properties to the models. The colors of the bodies cannot be matched with plausible minerals, ices, or metals. Iapetus, a satellite of Saturn, is one such red-colored body that is well matched with tholin-rich models. Detection of aromatic and aliphatic hydrocarbons on Iapetus by the Cassini spacecraft, and the presence of these hydrocarbons in the tholins, is taken as evidence for the widespread presence of solid organic complexes aromatic and aliphatic units on many bodies in the outer Solar System. These organic complexes may be compositionally similar to the insoluble organic matter in some classes of the carbonaceous meteorites, and thus may ultimately derive from the organic matter in the interstellar medium.

The insoluble organic material (IOM) in primitive meteorites is related to the organic material in interplanetary dust particles and comets, and is probably related to the refractory organic material in the diffuse interstellar medium. If the IOM is representative of refractory ISM organics, models for how and from what it formed will have to be revised.

The Stardust Mission collected samples from Comet 81P/Wild 2 on 2 Jan 2004 and returned these samples to Earth on 15 Jan 2006. After recovery, a six month preliminary examination was done on a portion of the samples. Studies of the organics in the samples were made by the Organics Preliminary Examination Team (PET) - a worldwide group of over 55 scientists. This paper provides a brief overview of the findings of the Organics PET. Organics in the samples were studied using a multitude of analytical techniques including spatial determination of C and heteroatom elemental abundances (STXM), functional group identification (micro-FTIR/Raman, C,N,O-XANES), and specific molecular identification of certain classes of organics (HPLC-LIF, L2MS, TOF-SIMS). Analyses were also made of spacecraft components and environmental samples collected near the recovered returned capsule to assess contamination issues. The distribution of organics (abundance, functionality, and relative elemental abundances of C,N,O) is heterogeneous both within and between particles. They are an unequilibrated reservoir that experienced little parent body processing after incorporation into the comet. Some organics look like those seen in IDPs (and to a lesser extent, meteorites), while new aromatic-poor and highly labile organics, not seen in meteoritic materials, are also present. The organics are O,N-rich compared to meteoritic organics. Some of the organics have an interstellar heritage, as evidenced by D and 15N enrichments.

As messengers from the early Solar System, comets contain key information from the time of planet formation and even earlier – some may contain material formed in our natal interstellar cloud. Along with water, the cometary nucleus contains ices of natural gases (CH4, C2H6), alcohols (CH3OH), acids (HCOOH), embalming fluid (H2CO), and even anti-freeze (ethylene glycol). Comets today contain some ices that vaporize at temperatures near absolute zero (CO, CH4), demonstrating that their compositions remain largely unchanged after 4.5 billion years. By comparing their chemical diversity, several distinct cometary classes have been identified but their specific relation to chemical gradients in the proto-planetary disk remains murky. How does the compositional diversity of comets relate to nebular processes such as chemical processing, radial migration, and dynamical scattering? No current reservoir holds a unique class, but their fractional abundance can test emerging dynamical models for origins of the scattered Kuiper disk, the Oort cloud, and the (proposed) main-belt comets. I will provide a simplified overview emphasizing what we are learning, current issues, and their relevance to the subject of this Symposium.

Polarimetric observations demonstrated that all comets with significant values of circular polarization show predominantly left–handed circularly polarized light. We discuss the presence of homochiral organics in cometary materials as a source of the observed circular polarization. We have studied the effect of chirality on light–scattering properties of cometary dust considering particles that possess optical activity. Our investigations show that the cometary dust may include optically active materials which can be prebiological homochiral organics.

It is known since long ago that in comets a large quantity of organic matter exists in form of grains or is embedded in silicate grains. This was detected in situ by cometary space missions as well as inferred as a distributed source of some molecules observed in comets. Since organic matter is rather volatile, finding slow sublimating grains in comets can be good evidence of organics as a constituent of such grains. Here we describe a method to detect sublimating grains in comets. It consists of specific observations, specific data analysis, and some light-scattering modeling. We detect sublimating grains by measuring the quantity of grains as a function of the nucleocentric distance. Once detected, it is possible to get their photometric characteristics and compare them with the results of light-scattering modeling. The method has been applied to several comets. Sublimating grains were reliably identified for two of them.

While gaseous carbon-rich species in cometary comae (coming from the nuclei icy component) are extensively studied by spectroscopic remote observations, so-called CHONs dust particles, i. e. organic compounds coming from the nuclei refractory component, have mostly been studied by dust mass spectrometers flying through the comae of comets 1P/Halley and 81P/Wild 2. However, remote observations of the light scattered by dust in cometary comae and in the interplanetary medium, coupled with both numerical and experimental simulations, have recently allowed us to confirm that such particles harbor a significant fraction of absorbing material, presumably consisting of organic compounds (Levasseur-Regourd et al. PSS 2007, Lasue et al. A&A 2007).

We estimate the fraction of absorbing material present in cometary dust for extensively observed comets (e.g., 1P/Halley, C/1995 O1 Hale-Bopp) and in the interplanetary dust (from zodiacal light observations). We also establish that, besides compact particles, fluffy aggregates are definitely present in these media. The properties (e.g., size distribution, morphology, composition) of the cometary and interplanetary dust particles, as inferred from light scattering data analysis, are compared with those of the IDPS collected in the upper Earth atmosphere and of the unique samples returned by the Stardust mission at Wild 2. The results are discussed in terms of the formation of comets in the protosolar nebula, and of the possible survival, at the epoch of late early bombardment, of cometary organics embedded in fluffy aggregates.

The population of Saturn's outermost tenuous E-ring is dominated by tiny water ice particles, some of which contain organic or mineral impurities. Active cryo-volcanism on the moon Enceladus, embedded in the E-ring, has been known to be a major source of particles replenishing the ring since late 2005. Therefore, particles in the vicinity of Enceladus provide crucial information about the dynamic and chemical processes occurring far below the moon's icy surface.

We present a compositional analysis of thousands of impact ionisation mass spectra of Saturn's E-ring particles, with sizes predominantly below 1 μm, detected by the Cosmic Dust Analyser onboard the Cassini spacecraft. Our findings imply that organic compounds are a significant component of icy particles ejected by Enceladus plumes. Our in situ measurements are supported by detections of other Cassini instruments. They hint at a dynamic interaction of a hot rocky core with liquid water below the icy surface, where the organic molecules are generated. Further insights are expected from two close Enceladus flybys to be performed by Cassini in 2008. Then, for the first time, we will obtain spectra of freshly ejected particles at the traversals through the cryo-volcanic plumes.

To interpret the concentrations of the products measured in Titan's atmosphere and to better understand the associated chemistry, many theoretical models have been developed so far. Unfortunately, large discrepancies are still found between theoretical and observational data. A critical examination of the chemical scheme included in these models points out some problems regarding the reliability of the description of critical reaction pathways as well as the accuracy of kinetic parameters. Laboratory experiments can be used to reduce these two sources of uncertainty. It can be:

i) experimental simulations: in our laboratory (LISA), representative Titan's simulation experiments are planned to be carried out in a reactor where the initial gas mixture will be exposed, for the first time, to both electrons and photons. Thus, the chemistry between N atoms and CH3, CH2, CH fragments, issued from electron dissociation of N2 and photo-dissociation of CH4 respectively, will be initiated. Thank to a time resolved technique, we will be able to analyse “in situ”, qualitatively and quantitatively, the stable species as well as the short life intermediates. Then, the implied chemistry will be determined precisely, and consequently, its description will be refined in theoretical models. The current status of this program will be given.

ii) specific experiments: they are devoted, for example, to determine kinetic rate constants and low temperature VUV spectra that will be used to feed models and to interpret observational data. Such experiments performed in LISA and in Rennes' laboratory concern polyynes and cyanopolyynes as these compounds could link the gaseous and the solid phase in planetary atmosphere. Results concerning C4H+ hydrocarbons kinetic rate constants and VUV cross section of HC3N and HC5N will be detailed.

Ion-neutral chemistry in Titan's upper atmosphere (~ 1000 km altitude) is an unexpectedly prodigious source of hydrocarbon-nitrile compounds. We report observations from the Cassini Ion Neutral Mass Spectrometer (INMS; Waite et al. 2004) and Cassini Plasma Spectrometer (CAPS; Young et al. 2004) that allow us to follow the formation of the organic material from the initial ionization and dissociation of nitrogen and methane driven by several free energy sources (extreme ultraviolet radiation and energetic ions and electrons) to the formation of negative ions with masses exceeding 10,000 amu.

The presence of an undersurface ocean renders Europa as one of the few planetary bodies in our Solar System that has been conjectured to have possibly harbored life. Some of the organic and inorganic species present in the ocean underneath are expected to transport upwards through the relatively thin ice crust and manifest themselves as impurities of the water ice surface. For this reason, together with its unique dynamic atmosphere and geological features, Europa has attracted strong scientific interests in past decades.

Europa is imbedded inside the Jovian magnetosphere, and, therefore, is constantly subjected to the immerse surrounding radiations, similar to the other three Galilean satellites. The magnetosphere-atmosphere-surface interactions form a complex system that provides a multitude of interesting geophysical phenomenon that is unique in the Solar System. The atmosphere of Europa is thought to have created by, mostly, charged particles sputtering of surface materials. Consequently, the study of Europa's atmosphere can be used as a tool to infer the surface composition. In this paper, we will discuss our recent model studies of Europa's near-surface atmosphere. In particular, the abundances and distributions of the dominant O2 and H2O species, and of other organic and inorganic minor species will be addressed.

Cassini RADAR observations now permit an initial assessment of the inventory of two classes, presumed to be organic, of Titan surface materials: polar lake liquids and equatorial dune sands. Several hundred lakes or seas have been observed, of which dozens are each estimated to contain more hydrocarbon liquid than the entire known oil and gas reserves on Earth. Dark dunes cover some 20% of Titan's surface, and comprise a volume of material several hundred times larger than Earth's coal reserves. Overall, however, the identified surface inventories (> 3 × 104 km3 of liquid, and >2 × 105 km3 of dune sands) are small compared with estimated photochemical production on Titan over the age of the Solar System. The sand volume is too large to be accounted for simply by erosion in observed river channels or ejecta from observed impact craters. The lakes are adequate in extent to buffer atmospheric methane against photolysis in the short term, but do not contain enough methane to sustain the atmosphere over geologic time. Thus, unless frequent resupply from the interior buffers this greenhouse gas at exactly the right rate, dramatic climate change on Titan is likely in its past, present and future.

Lightning is considered as one of energy sources for synthesis of biochemical compounds. Numerous theoretical and experimental researches of gas-grain chemistry show that chemical reactions on the gas - ice boundary play a considerable role in such synthesis. In this connection the greatest interest represents studying lightning in gas-dusty atmospheres of water-containing bodies (comets, ice satellites of Jupiter and Saturn).