Sorption of aniline and its derivatives by montmorillonite substituted by cations of widely different acidity depends upon the polarizing power of the interlayer cations. Infra-red spectra indicate that the anilines are mostly bound to the interlayer cations through water molecules, except in Cs montmorillonite, where bonding to the oxygen surfaces of the alumino-silicate sheets seems to predominate. Anilines are weak bases, which compete with the oxygen surfaces for protons of acidic interlayer water. Consequently, the tendency of anilines to act as proton donors in the clay interlayers increases with the polarizing power of the exchangeable cation. The concept of ‘basic’ water is introduced to account for some of the features of the spectra of Cs montmorillonite treated with the organic ligands.

The composition and physical properties of three clay soils were altered by introducing aluminum under an electro-chemical gradient in order to evaluate the role of pH in controlling changes in soil composition and the feasibility of pH buffering during electrochemical treatment.

Both X-ray diffraction and selective chemical extraction methods were used to determine the distribution and mode of occurrence of aluminum in the treated samples. Aluminum was detected in the treated samples in both exchangeable form and as a hydroxy-aluminum interlayer. Aluminum oxide minerals such as gibbsite were not detected in any of the treated samples. Mineralization by aluminum ions was speeded and intensified in bentonite soils by buffering the catholyte with carbon dioxide.

Plasticity of bentonite soil samples from South Dakota was reduced markedly by electrochemical treatment, whereas the plasticity of an illite soil from Illinois and an illite-montmorillonite soil from Mississippi were relatively unaffected. Nearly all treated samples exhibited some degree of electrochemical induration or mineralization. Induration was most pronounced in bentonite soil samples with high water contents and alkaline pH largely because of hydroxy-aluminum interlayering in the ciay. On the other hand interlayering was negligible in illite soil samples with low pH; the main effect of electrochemical treatment in this case was the addition of aluminum in exchange sites.

A purple-colored clay of 1M mica polymorph in association with lead-zinc ore was collected from an abandoned mine dump near Silverton. Colorado. Electron micrographs show that the crystallites of the clay are less than 2μ in size and have poorly developed hexagonal outlines. Differential thermal and i.r. absorption analyses indicate similarity with those of muscovite. The structural formula of the 1M mica polymorph is (K1.45 Na0.02) (Al3.75 Mg0.19) (Si6.90 Al1·10) O20 (OH)4. The purple color may be related to trace amounts of manganese in the clay.

The complex viscosity of a material is a two-component quantity, comprising real and imaginary parts. The real part of the complex viscosity is often very useful because in many materials it approaches the ordinary steady-flow viscosity at low frequencies. Because many materials with high viscosities are very slow in reaching a steady-flow condition, the determination of the steady-flow viscosity may be very difficult; however, an approximation can often be obtained from low-frequency values of the real part of the complex viscosity. In this study, the complex viscosity of a Georgia kaolin has been determined by measurements made on specimens subjected to oscillatory simple shear, over three decades of frequency. Other independent variables in the study are the water content of the clay and the shear strain amplitude. Data were obtained from experimental measurements in the form of values of the magnitude, or absolute value, of the complex viscosity, and the phase angle between the imposed oscillatory strain and the stress response. Empirical functional relationships are developed to relate these quantities to the independent variables, and these are in turn used to obtain the real and imaginary parts of the complex viscosity as functions of the independent variables. The results of this study indicate that the complex viscosity is not linear, but decreases approximately as a power function of the strain amplitude; the relation between the complex viscosity and the water content is approximately an inverse logarithmic one, and changes very rapidly at water contents near the liquid limit; and the phase angle increases with increasing strain amplitude approximately as a power function.

An X-ray diffraction method for determining quartz in sediments is described which is both rapid and precise, with a coefficient of variation of 1·9 per cent. Samples are ignited at 950°C prior to X-ray analysis. This removes the interference of clay peaks, increases the relative intensity of the quartz peaks and reduces the initial matrix variation of samples. The peak area ratio of quartz (4·26Å) to an added standard boehmite (6·18 Å) is measured. Quartz content is obtained from a working curve constructed using similar rocks of known free silica content, which were analysed by the method of Trostel and Wynne (1940).