Anaerobic bacteria were identified in live drilling muds and cores from nine different North Sea and Irish Basin oilfields, varying in depth from 3500 to 15000 ft, and at temperatures up to 150°C. The anaerobic bacteria may be introduced into the reservoir during drilling operations or injection of water, but in many cases the bacteria are indigenous to the oilfield reservoirs. Confirmation of the indigenous anaerobic bacteria was made using molecular biology techniques (16S rDNA sequence analysis), comparing microbial populations present in the blank drilling mud as supplied to wellsite, in the live drilling mud taken during coring, and in the live core. The role of anaerobic bacteria in oilfield diagenesis is not fully understood, though pyrite precipitation, and exopolymer and H2S gas production were noted in this study, up to temperatures of 95°C.

Fourth-order relative sea level changes may have a significant impact upon burial diagenesis and reservoir quality through their effect upon surface and subsurface temperature. Relative sea level changes can induce sediment surface temperature changes of <20°C when the sediment surface changes from being close to or beneath the thermocline to being sub-aerially exposed. Such sea level changes typically occur on a timescale of half a million years. Approximately one quarter to one third of the magnitude of these temperature fluctuations will be propagated to 2500 m in the subsurface. Shorter timescale fluctuations of similar magnitude, resulting from glaciation, will not be significant below ~1000 m burial as there is not enough time to effect the change before the next surface temperature cycle occurs. Diagenesis is strongly controlled by temperature through its impact on the driving force and rate of geochemical processes. Burial diagenesis and cementation may thus be episodic on timescales associated with sequence stratigraphic events occurring on the surface, thousands of metres above the zone where diagenesis is occurring.

The nature and origin of authigenic clay minerals and silicate cements in the Jurassic and Cretaceous sediments of England and the North Sea are discussed in relation to penecontemporaneous volcanism in and around the North Sea Basin. Evidence, including new REE data, suggests that the authigenic clay minerals represent the argillization of volcanic ash under varying diagenetic conditions, and that volcanic ash is a likely source for at least the early silicate cements in many sandstones. The nature and origin of smectite-rich, glauconite-rich, berthierine-rich and kaolin-rich volcanogenic clay mineral deposits are discussed. Two patterns of volcanogenic clay minerals facies are described. Pattern A is related to ash argillization in the non-marine and marine environments. Pattern B is developed by the argillization of ash concentrated in the sand and silt facies belts in the seas bordering ash-covered islands and massifs. It is associated with regression/ transgression cycles which may be related to thermal doming and associated volcanism, including the submarine release of hydrothermal fluids rich in Fe. The apparent paucity of volcanogenic clay deposits in the Jurasssic and Early Cretaceous sediments of the North Sea is discussed.

A reaction path model was constructed in a bid to simulate diagenesis in the Magnus Sandstone, an Upper Jurassic turbidite reservoir in the Northern North Sea, UKCS. The model, involving a flux of source rock-derived CO2 into an arkosic sandstone, successfully reproduced simultaneous dissolution of detrital K-feldspar and growth of authigenic quartz, ankerite and illite. Generation of CO2 occurred before and during the main phase of oil generation linking source rock maturation with patterns of diagenesis in arkosic sandstones and limiting this type of diagenesis to the earlier stages of oil charging. Independent corroborative evidence for the model is provided by formation water geochemical data, carbon isotope data from ankerite and produced gas phase CO2 and the presence of petroleum inclusions within the mineral cements. The model involves a closed system with respect to relatively insoluble species such as SiO2 and Al2O3 but is an open system with respect to CO2. There are up to seven possible rate-controlling steps including: influx of CO2, dissolution of K-feldspar, precipitation of quartz, ankerite and illite, diffusive transport of SiO2 and Al2O3 from the site of dissolution to the site of precipitation and possibly the rate of influx of Mg2+ and Ca2+. Given the large number of possible controls, and contrary to modern popular belief, the rate of quartz precipitation is thus not always rate limiting.

Carbonate cements in Tertiary reservoir sandstones from the northern North Sea have distinctive carbon isotopic compositions (δ13C). Oil migration up faults from deeper structures and biodegradation of oil pools are factors of particular importance in influencing the δ13C of carbonate cements in these sandstones. As a result, δ13C can be used as an exploration guide to locating the positions of vertical leakoff points from the Jurassic source rocks. The histogram distribution of δ13C in these carbonate cements is trimodal, with peaks at around −26, −3 and +12‰ (ranges −22 to −30, +2 to −10 and +8 to +18‰, respectively). Bacterial processes played major roles in determining this distribution, with oxidative biodegradation of oil resulting in carbonate cements with very negative compositions and bacterial fermentation resulting in the positive δ13C cements. δ13C distribution patterns may be used to differentiate Tertiary reservoir sandstones from Jurassic in the northern North Sea, and these regional carbonate cement δ13C datasets allow geologically useful inferences to be drawn from δ13C data from new sample locations.

Close relationships are demonstrated between reservoir quality, lithofacies, provenance and burial history in the Jurassic Brent and Viking Groups in the Norwegian North Sea. Porosity and permeability are strongly and systematically related to the initial texture and composition of the sandstones. Porosity variations are related to the amount of compaction, which is more severe in matrix-rich than in clean facies, and quartz cementation, which is most important in clean facies. Permeability variations are related to porosity and facies-controlled variations in grain size, and abundance and texture of intergranular fines. Illitization of early diagenetic kaolins require K, which is derived mainly from dissolution of K-feldspar. Sediments were sourced from K-feldspar- poor provenances during the maximum progradation of the Brent Group, and sandstones deposited at this time are less exposed to illitization and have better permeability at deep burial than reservoir sandstones that initially contained more K-feldspar.

Petrographic study of the Frewens sandstone, Upper Cretaceous Frontier Formation, documents reservoir-scale diagenetic heterogeneity. Iron-bearing calcite cement occurs as large concretions that generally follow bedding and are most common near the top of the sandstone. Median thickness of the concretions is 0.6 m, length 4.5 m, and width 5.7 m; median volume is 5.2 m3. Concretions comprise 12% of the sandstone.

The minus-cement porosity of concretion samples is low, indicating that the calcite precipitated near maximum burial depth. Isotopic and burial history data suggest that the calcite precipitated at ~54°C from evolved meteoric water enriched in 18O or from a mixed meteoric±marine pore-water. Shell-bearing transgressive shales above the Frewens sandstone are interpreted to be the source of calcium carbonate. Concretions of this size and distribution would influence fluid flow in a reservoir and would reduce the amount of hydrocarbons in place.

A three-fold zonation can be imaged within authigenic siderite from sandstones of the Brent Group using back-scatter SEM techniques. We interpret this zonation in terms of the biogeochemical zonation of shallow buried sediment. The innermost siderite crystal zone is very Fe rich (95.0±0.5 mol.% FeCO3), with high Mn levels relative to Ca and Mg. This is interpreted as forming within the Fe reduction zone, with Mn from the closely associated Mn reduction zone. The second siderite crystal zone is frequently represented either by an episode of dissolution, or is impure (80±1 mol.% FeCO3), and this corresponds to the sulphate reduction zone. The outer crystal zone is intermediate in composition, and is equated with the zone of methanogenesis (88±1 mol.% FeCO3). Isotopic values cannot be assigned to individual crystal zones. Bulk δ18O values (−2.7 to −13.0‰ V-PDB) are not consistent with precipitation from seawater at low temperatures, but suggest meteoric pore-waters. δ13C data (−4.3 to −15.7‰ V-PDB) are consistent with microbially-mediated precipitation.

Pyrite and siderite are usually mutually exclusive within a single sample. Sedimentary conditions which favour the development of a strong sulphate reduction zone, and hence the formation of pyrite, do not favour the formation of a strong sub-oxic zone, where siderite is preferentially precipitated, and vice versa. There is a strong facies control upon siderite formation, with ripple cross-laminated sands being most strongly siderite cemented.

Sandstones of the Palaeocene Montrose Group were deposited in a deepwater fan environment, and form a major oil reservoir in the North Sea. Calcite concretions occur commonly within thick-bedded and structureless sandstones. These concretions have been identified by sonic logs and well reports, and were cross-checked with available core data. Regionally, 101 wells have been examined and carbonate concretions form 0.6–7.2% of the core. Concretions are most abundant along the flank of the Fladen Ground Spur, the north Witch Ground Graben (WGG), the east south Viking Graben and East Central Graben (ECG). Concretions of the ECG formed at deep burial, with C from decarboxylation. Geochemical inheritance of Mn and Sr from Cretaceous chalk clasts may occur. Concretion growth may also have been influenced by vertical expulsion of fluids (leak-off) localized above salt tectonics. Isotopic and petrographic evidence indicates that much carbonate C in the WGG was derived from biodegradation of migrating oil in meteoric water at shallow depth. The locations of abundant carbonate with characteristic negative C isotope signatures can be used as shallow exploration guides to leak-off points located above deep overpressured structures.

The Palaeocene Everest Complex, located in the Central Graben of the North Sea, comprises interbedded sandstones and mudrocks deposited in a submarine fan environment and overlies Cretaceous limestones. Depositional facies are the main influence on reservoir quality, although the latter is reduced significantly locally by ferroan calcite cementation, particularly in the lower part of the complex. Carbon and O stable isotope analyses have been made from cements in sandstones and mudrocks and from shear fractures and injection features within mudrock intervals. These indicate a marine source of detrital carbonate becoming mixed with HCO3− from decarboxylation higher in the succession. Petrographic observation and microprobe analyses indicate that dissolution of coccoliths and foraminifera in limestones are the principal sources of cementation. The similar composition of cements in sandstones, fractures and injection features suggests a common formation. Burial history modelling shows cement precipitation is synchronous with periods of excess pressure and therefore excess pressure release associated with rock failure is proposed as a prominent mechanism for initiating cementation.

The Devonian-Carboniferous reservoir of the Clair Field contains a complex and variably abundant clay mineral assemblage. An abrupt vertical change in clay mineralogy has been observed in both wells studied (UKCS 206/8-7 and 206/8-8) from being rich in Mg-chlorite, chlorite- smectite (including dioctahedral corrensite), illite, illite-smectite and Fe-chlorite, to being smectite- rich. This change broadly coincides with the unconformable boundary between the Lower Clair Group and Upper Clair Group of the reservoir which possibly defines the Devonian-Carboniferous boundary. The clay minerals present reflect interaction between: (1) tectonic stability and climate that controlled the detrital composition of the sediment; (2) the pore-waters that developed; and (3) the result of diagenetic modification.

Matrix porosity and permeability is severely restricted where the pore-lining clays are abundant (>15%) and where the clays bridge or fill pores. The type of clay mineral species appears to have a minor influence on reservoir quality, although they may be extremely important during production. The best reservoir quality occurs in mature aeolian sediments with a thin illite and illite-smectite clay coating.

The different rates of smectite illitization have been investigated in interbedded sandstone and mudstone samples from the Neogene to Lower Pleistocene stratigraphy of the Niigata sedimentary basin. For samples of approximately the same age and under the same temperature and pressure conditions, the analytical results of XRD and EDS show that differences in the transformation from R = 1 I-S to R≥3 I-S at a temperature of ~30–40°C and 1000 m in depth are determined by the initial smectite composition and the relative ion concentration of pore-fluid in the sedimentary rock system. The ordered I-S and illite in the mudstone have inherited compositional characteristics from the initial detrital smectite and illite. In the sandstone, the I-S composition was changed by interaction with pore-fluids and by precipitation and crystal growth during diagenesis.

In the Maastrichtian-Danian chalk in the North Sea, discrete intervals, appearing as normal white chalk, contain up to 60% α-quartz <2 μm in size. Atomic force microscopy (AFM) reveals that the particles are of nm size, appearing as spherical particles and aggregates. Similar particles consisting of opal-CT were found in surface exposures of chalk in Denmark. Two new abiogenic pathways of silica formation in chalk are proposed. The first model proposes that SiO2 nano-size particles and aggregates precipitated and flocculated in the free-water phase as opal and were diagenetically transformed from opal-CT at low temperature to α-quartz at elevated temperature. In the second model, the dominance of radiolarians in the deep-water environment of the North Sea resulted in low dissolution supply with subsequent precipitation and flocculation of nano-size α-quartz particles. In the shallower water of the shelf environment of the present onshore chalk, the abundance of sponges and their dissolution supplied enough Si to precipitate opal-CT in the free-water phase.

Petrographic, mineralogical and geochemical core analysis of Palaeocene turbiditic sandstones in the Sleipner East gas-condensate reservoirs show the importance of diagenetic clay distribution on porosity, permeability, and water saturation. An observed ‘high resistivity zone’ (HRZ) corresponds to intervals with low water saturation, a more restricted distribution of diagenetic clay (mainly chlorite), and up to 5% quartz cement. The underlying ‘low resistivity zone’ (LRZ) corresponds to intervals with more widely distributed diagenetic clay, which have lower degrees of quartz cementation, higher porosity, and variably reduced permeability. Crosscutting relationships of the HRZ/LRZ with mapped sedimentary depositional units, as well as fluid inclusion analysis data, suggest that the distribution of diagenetic clay was affected by an earlier (late Miocene?) oil charge, and more extensive chlorite formation in a palaeo-water zone. Recent gas condensate charge and structuring of these sandstones resulted in LRZ reservoirs with substantially higher water saturations than those in the HRZ.

In the Miller Field, diagenetic quartz abundance, isotopic compositions and salinities of quartz-cementing fluids display a distinct pattern which is related to the structural depth of the reservoir sandstones. Quartz cement volumes increase from the crest of the field (average 6.0±1.5%) towards the flanks of the field (average 13.2±2.1%) and directly reduce reservoir porosity. By integrating petrographic observations with results of fluid inclusion measurements and O isotope analyses of diagenetic quartz, the pattern of quartz cementation is seen to be related to the reservoir filling history. Oil filled the crest of the reservoir first and prevented extensive quartz cementation. At greater depth in the reservoir oil zone, quartz overgrowths continued to precipitate until inhibited by the developing oil column. Oxygen isotope compositions of diagenetic quartz imply that quartz cement continued to precipitate in the water zone of the reservoir up to the present day.

Silicification and illitization due to diagenesis result in the modification of porosity and permeability in many North Sea reservoirs, including Greater Alwyn. A good estimation of the mineral composition is required as input/output data for geochemical modelling modes intended to reproduce these effects. Using sedimentological studies to determine laterally equivalent facies, three facies were chosen. ‘Initial states’ for modelling were thus defined as the present-day composition of less-evolved laterally-equivalent facies, ‘final states’ as the present-day composition in the most evolved part of the basin. Precise actual mineral compositions were calculated using a reconciliation program, DATREC. Average compositions calculated for each facies in each field provided data useful in constraining input/output values used in modelling, and gave insights into depositional variation. Arithmetic tests assuming isochemical transformations, constraining the chemical compositions of ‘initial states’ to fit actual mineralogical compositions of ‘final states’, were run using this software. They show that, from an arithmetical point of view, if the assumption of equivalent facies holds, isochemical reactions can occur in some, but not in all facies, thereby demonstrating the importance of checking equivalence of facies and diagenesis hypotheses by quantitative calculations.

The Tarbert Formation on a north±south oriented structure along the eastern flank of the Viking Graben has been studied. The reservoir in the two wells studied is buried ~100 m deeper in the northern than in the southern well. The present reservoir temperature is ~130°C. The reservoir quality is good, but due to extensive illitization of kaolin, the northern well shows lower permeability values than the southern well, for similar porosity values. The initial composition of the analysed samples in the two wells is very similar. There are no significant differences in total clay content and both wells contain K-feldspars and kaolin. However, the diagenetic alteration is more advanced in the deeper well. Total porosity is about the same in both wells but, due to illitization, the ratio of micro- vs. macro-porosity is higher in the deeper well. Petroleum emplacement in the structure occurred in two phases: oil emplacement predates, whereas gas emplacement postdates, most of the quartz cementation. In the deeper well, illitization occurred after gas emplacement.

Rocks above and below the Precambrian-Palaeozoic unconformity at the base of many Palaeozoic sedimentary basins of mid-continental North America are distinguished by secondary K-feldspar, chlorite and illite. Thrusting of the Appalachian foreland is generally considered responsible for the fluid migrations which caused this alteration. We have examined secondary chlorite and illite from Cambro-Ordovician rocks which overlie the unconformity in southern Ontario, Canada. This area is situated along the interface between the Michigan and Appalachian basins. Water involved in chloritic alteration at ~150°C has an O isotope composition compatible with a basinal brine evolved from seawater. Brine migration was probably triggered by the Taconic Orogeny to the east. In comparison, the secondary illite (365–321 Ma) largely postdates the Acadian Orogeny, and the illite-forming fluids have stable isotopic compositions typical of tepid (~40–55°C) meteoric water. We suggest that basement arches beneath southern Ontario were reactivated by this orogeny, which facilitated introduction of meteoric water. Similar alteration in underlying Precambrian rocks shows that fluid flow was focused along the unconformity during the regional Ordovician brine migration, as well as during the localized Mississippian introduction of fresh water.