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4 - Langmuir monolayers

Published online by Cambridge University Press:  05 July 2014

Michael Dennin
Affiliation:
University of California
Jeffrey Olafsen
Affiliation:
Baylor University, Texas
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Summary

Introduction

Langmuir monolayers have proven themselves to be a powerful experimental system for the study of a range of issues in soft condensed matter [1–4]. Essentially, Langmuir monolayers are a single layer of insoluble molecules at the air–water interface. As such, they form an almost ideal two-dimensional system. This offers the opportunity to study fundamental questions in the phase behavior and material properties of two-dimensional systems. Secondly, they are readily transferred from the surface to a solid substrate. This has been the motivation for studying these systems for a range of technological applications. Finally, they are a natural system for the study of biological questions given that much of biology relies on processes at interfaces, such as cellular membranes and membranes of cellular components.

The experimental techniques associated with Langmuir monolayers can loosely be divided into two classes: formation of the monolayer and characterization of the monolayer. In this chapter, we will briefly review important issues in the formation of Langmuir monolayers. The focus will be mostly on the general concepts and issues, with some specific recipes given for illustrative purposes. However, it should be recognized that many groups specializing in Langmuir monolayers have refined and developed specific methods that are optimized for their system. So, some care needs to be taken in applying any given specific recipe. In the area of characterization, we will briefly review standard surface pressure characterization and provide a survey of commercial tools, including x-ray and neutron scattering techniques.

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Publisher: Cambridge University Press
Print publication year: 2010

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  • Langmuir monolayers
  • Edited by Jeffrey Olafsen, Baylor University, Texas
  • Book: Experimental and Computational Techniques in Soft Condensed Matter Physics
  • Online publication: 05 July 2014
  • Chapter DOI: https://doi.org/10.1017/CBO9780511760549.004
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  • Langmuir monolayers
  • Edited by Jeffrey Olafsen, Baylor University, Texas
  • Book: Experimental and Computational Techniques in Soft Condensed Matter Physics
  • Online publication: 05 July 2014
  • Chapter DOI: https://doi.org/10.1017/CBO9780511760549.004
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  • Langmuir monolayers
  • Edited by Jeffrey Olafsen, Baylor University, Texas
  • Book: Experimental and Computational Techniques in Soft Condensed Matter Physics
  • Online publication: 05 July 2014
  • Chapter DOI: https://doi.org/10.1017/CBO9780511760549.004
Available formats
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