This paper describes a generalization of the inverse of a non-singular matrix, as the unique solution of a certain set of equations. This generalized inverse exists for any (possibly rectangular) matrix whatsoever with complex elements. It is used here for solving linear matrix equations, and among other applications for finding an expression for the principal idempotent elements of a matrix. Also a new type of spectral decomposition is given.

For dealing with atoms involving many electrons the accurate quantum theory, involving a solution of the wave equation in many-dimensional space, is far too complicated to be practicable. One must therefore resort to approximate methods. The best of these is Hartree's method of the self-consistent field. Even this, however, is hardly practicable when one has to deal with very many electrons, so that one then requires a still simpler and rougher method. Such a method is provided by Thomas' atomic model, in which the electrons are regarded as forming a perfect gas satisfying the Fermi statistics and occupying the region of phase space of lowest energy. This region of phase space is assumed to be saturated, with two electrons with opposite spins in each volume (2πh)3, and the remainder is assumed to be empty. Although this model hitherto has not been justified theoretically, it seems to be a plausible approximation for the interior of a heavy atom and one may expect it to give with some accuracy the distribution of electric charge there.

We show that any set of distinct homotopy classes of simple closed curves on the torus that pairwise intersect at most k times has size $k+O(\sqrt k \log k)$ . Prior to this work, a lemma of Agol, together with the state of the art bounds for the size of prime gaps, implied the error term $O(k^{21/40})$ , and in fact the assumption of the Riemann hypothesis improved this error term to the one we obtain $O(\sqrt k\log k)$ . By contrast, our methods are elementary, combinatorial, and geometric.

The theoretical calculation of observable atomic constants is often only possible if the effective electric field inside the atom is known. Some fields have been calculated to fit observed data but for many elements no such fields are available. In the following paper a method is given by which approximate fields can easily be determined for heavy atoms from theoretical considerations alone.

The probability relations which can occur between two separated physical systems are discussed, on the assumption that their state is known by a representative in common. The two families of observables, relating to the first and to the second system respectively, are linked by at least one match between two definite members, one of either family. The word match is short for stating that the values of the two observables in question determine each other uniquely and therefore (since the actual labelling is irrelevant) can be taken to be equal. In general there is but one match, but there can be more. If, in addition to the first match, there is a second one between canonical conjugates of the first mates, then there are infinitely many matches, every function of the first canonical pair matching with the same function of the second canonical pair. Thus there is a complete one-to-one correspondence between those two branches (of the two families of observables) which relate to the two degrees of freedom in question. If there are no others, the one-to-one correspondence persists as time advances, but the observables of the first system (say) change their mates in the way that the latter, i.e. the observables of the second system, undergo a certain continuous contact-transformation.

The conductivity of thin films of the alkali metals has recently been measured in the H. W. Wills Physical Laboratory, Bristol*. It was found that as the thickness of the film is decreased to that of a few atomic layers the conductivity drops below that of the bulk metal. In the papers quoted the hypothesis was put forward that this effect is due to the shortening of the mean free paths of the conduction electrons of the metal by collisions with the boundaries of the film. The experimental results were compared with a formula derived on the basis of this hypothesis. This formula was, however, obtained subject to a number of simplifying assumptions, and it is the first purpose of this paper to obtain a more accurate formula. I also compare this formula with experiment, and make certain deductions about the surfaces of thin films.

The paper is concerned with the practical determination of the characteristic values and functions of the wave equation of Schrodinger for a non-Coulomb central field, for which the potential is given as a function of the distance r from the nucleus.

The method used is to integrate a modification of the equation outwards from initial conditions corresponding to a solution finite at r = 0, and inwards from initial conditions corresponding to a solution zero at r = ∞, with a trial value of the parameter (the energy) whose characteristic values are to be determined; the values of this parameter for which the two solutions fit at some convenient intermediate radius are the characteristic values required, and the solutions which so fit are the characteristic functions (§§ 2, 10).

Modifications of the wave equation suitable for numerical work in different parts of the range of r are given (§§ 2, 3, 5), also exact equations for the variation of a solution with a variation in the potential or of the trial value of the energy (§ 4); the use of these variation equations in preference to a complete new integration of the equation for every trial change of field or of the energy parameter avoids a great deal of numerical work.

For the range of r where the deviation from a Coulomb field is inappreciable, recurrence relations between different solutions of the wave equations which are zero at r = ∞, and correspond to terms with different values of the effective and subsidiary quantum numbers, are given and can be used to avoid carrying out the integration in each particular case (§§ 6, 7).

Formulae for the calculation of first order perturbations due to the relativity variation of mass and to the spinning electron are given (§ 8).

The method used for integrating the equations numerically is outlined (§ 9).

It has been pointed out to me that some of the statistical ideas employed in the following investigation have never received a strictly logical definition and analysis. The idea of a frequency curve, for example, evidently implies an infinite hypothetical population distributed in a definite manner; but equally evidently the idea of an infinite hypothetical population requires a more precise logical specification than is contained in that phrase. The same may be said of the intimately connected idea of random sampling. These ideas have grown up in the minds of practical statisticians and lie at the basis especially of recent work; there can be no question of their pragmatic value. It was no part of my original intention to deal with the logical bases of these ideas, but some comments which Dr Burnside has kindly made have convinced me that it may be desirable to set out for criticism the manner in which I believe the logical foundations of these ideas may be established.

Let $\mathfrak{A}$ be a finite abelian group. In this paper, we classify harmonic $\mathfrak{A}$-covers of a tropical curve $\Gamma$ (which allow dilation along edges and at vertices) in terms of the cohomology group of a suitably defined sheaf on $\Gamma$. We give a realisability criterion for harmonic $\mathfrak{A}$-covers by patching local monodromy data in an extended homology group on $\Gamma$. As an explicit example, we work out the case $\mathfrak{A}=\mathbb{Z}/p\mathbb{Z}$ and explain how realisability for such covers is related to the nowhere-zero flow problem from graph theory.

An attempt is made to interpret quantum mechanics as a statistical theory, or more exactly as a form of non-deterministic statistical dynamics. The paper falls into three parts. In the first, the distribution functions of the complete set of dynamical variables specifying a mechanical system (phase-space distributions), which are fundamental in any form of statistical dynamics, are expressed in terms of the wave vectors of quantum theory. This is shown to be equivalent to specifying a theory of functions of non-commuting operators, and may hence be considered as an interpretation of quantum kinematics. In the second part, the laws governing the transformation with time of these phase-space distributions are derived from the equations of motion of quantum dynamics and found to be of the required form for a dynamical stochastic process. It is shown that these phase-space transformation equations can be used as an alternative to the Schrödinger equation in the solution of quantum mechanical problems, such as the evolution with time of wave packets, collision problems and the calculation of transition probabilities in perturbed systems; an approximation method is derived for this purpose. The third part, quantum statistics, deals with the phase-space distribution of members of large assemblies, with a view to applications of quantum mechanics to kinetic theories of matter. Finally, the limitations of the theory, its uniqueness and the possibilities of experimental verification are discussed.