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ART. 87 - On the Tension of Mercury Vapour at Common Temperatures

Published online by Cambridge University Press:  05 December 2011

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Summary

The author called attention to the difficulty of reconciling the values of Regnault and Hagen with the phenomena observed by Crookes relating to the viscosity of gases at high exhaustions. The total gaseous pressure in the working chamber cannot be less than that of the mercury at the pump. If the penetration of mercury vapour be prevented by chemical means, some other gas must be present in equivalent quantity. If the value of Regnault and Hagen is substantially correct, it does not appear how the phenomena [of viscosity] could vary so much as they are observed to do at the highest degrees of exhaustion as measured by the McLeod gauge. The question then arises whether the value of mercury tension hitherto received may not be much in excess of the truth. In Hagen's researches it is assumed without reason that the pressure in a chamber of variable temperature is governed by the temperature of the coldest part, but this consideration tells in the wrong direction. It was suggested that possibly a change in the capillary constant, or currents in the fluid mercury at the chilled surface of the meniscus, might have had something to do with the minute changes of level which have been attributed to differences of pressure in the mercury vapour.

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Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1900

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