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4 - Use of Multi-collector ICP-MS for Studying Biogeochemical Metal Cycling

from Part II - Advanced Analytical Instrumentation

Published online by Cambridge University Press:  06 July 2019

Janice P. L. Kenney
Affiliation:
MacEwan University, Edmonton
Harish Veeramani
Affiliation:
Carleton University, Ottawa
Daniel S. Alessi
Affiliation:
University of Alberta
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Summary

Multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) is a powerful technique for the study of biogeochemical cycling of a variety of metals. The advantages of this technique include high ionization efficiency, low detection limits, and rapid analysis. It can produce highly precise and accurate elemental isotope compositions of natural and experimental samples, which can provide insights into the mechanisms of both biological and abiological processes in in natural environments. In this chapter, the operating principles of the instrument, purification of samples, interferences encountered, correction methods to eliminate the instrumental mass discrimination, and data analysis with respect to reliability and reproducibility are discussed. A case study is included that highlights the capability of MC-ICP-MS to infer mechanisms of Fe redox processes in an acidic oligotrophic lake using natural abundance of stable Fe isotopes.

Type
Chapter
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Analytical Geomicrobiology
A Handbook of Instrumental Techniques
, pp. 93 - 118
Publisher: Cambridge University Press
Print publication year: 2019

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