Texas Bio-Nuclear is a proprietary establishment engaged in offering C14 dating by the liquid-scintillation method as a service to those institutions and individuals who have a need for such a service. The Laboratory began actual dating operations in December 1961. The first few months were devoted to processing check samples in order to establish the reliability of the system. The dates listed below are not inclusive of all our dating, since the dates we furnish our clients are their property and the publishing of this information is their decision.

Rural landscapes are increasingly diverse and heterogeneous, involving a mix of small and large parcels, amenity and agricultural properties, and resident and absentee owners. Managing invasive plants in landscapes with changing ownership requires understanding the views and practices of different landowners. We surveyed landowners in two rural valleys with 26% absentee ownership and a large number of small parcels in Missoula County, Montana. Landowners indicated a high level of awareness and concern about weeds; more than 80% agreed that weeds are a problem in their valley. Seventy-eight percent of landowners managed weeds, but only 63% were effective at weed management. Absentee owners were far less likely to manage weeds on their properties and less likely to utilize herbicides, as compared with resident landowners. Landowners reported that seeds coming from adjacent properties were the most significant barrier to effective weed control. Many landowners manage weeds to be a good neighbor and believe that cooperation between neighbors is critical to weed management.

The Golden-cheeked Warbler Dendroica chrysoparia is a federally endangered Neotropical migrant that inhabits montane pine-oak forests in Mexico and northern Central America during the non-breeding season. Although it is known that Golden-cheeked Warblers are closely associated with ‘encino’ oaks (evergreen or holm oak) such as Quercus sapotifolia, Q. eliptica and Q. elongata, which have shiny, narrow, elliptical, or oblong leaves, quantitative habitat targets are useful for effectively incorporating this information into conservation planning and forest management practices. We analysed data on wintering Golden-cheeked Warblers collected during the non-breeding season in Honduras from 1996 to 1998 to identify quantitative targets for habitat conditions for this species. Data on warbler abundance were collected using line transect surveys located in montane pine-oak forests in a stratified-random fashion. Habitat data were collected at five 0.04 ha plots on these same transects and the averaged values used as predictors of Golden-cheeked Warbler abundance. We found that Golden-cheeked Warblers were strongly associated with the basal area of encino oaks and density of ‘roble’ oaks, such as Q. segoviensis, Q. purulhana and Q. rugosa, which have large, lobed leaves. Density of Golden-cheeked Warblers peaked at ≈ 5.6 m2 ha–1 basal area of encino and ≈7 roble oaks ha–1. These values can be used to identify quantitative habitat targets that can be directly incorporated into forest management practices to ensure that these activities maintain habitat conditions necessary for their use by Golden-cheeked Warblers.

Pseudomonas aeruginosa is a nosocomial pathogen capable of exhibiting a variety of resistance mechanisms against multiple classes of antibiotics. Fluoroquinolones, commonly used to treat a variety of infections in both ambulatory and hospitalized patients, have been increasingly linked to the development of resistance, both to fluoroquinolones and to other classes of antibiotics including β-lactams, cephalosporins, and carbapenems. In turn, as many as 95% of multidrug-resistant pseudomonal isolates may be resistant to fluoroquinolones. Although research has examined the effect of fluoroquinolone use on P. aeruginosa resistance, to our knowledge, no work has been published describing possible differences among individual fluoroquinolones related to resistance to other antibiotic classes. The purpose of this analysis was to assess the possible effects of varying usage of levofloxacin, gatifloxacin, and moxifloxacin on P. aeruginosa susceptibility to piperacillin-tazobactam, cefepime, and tobramycin. Data from January 2000 through December 2008 were obtained from clinical microbiology and pharmacy databases of the Medical University of South Carolina Medical Center, which is a 689-bed academic medical center and level 1 trauma center with adult and pediatric beds. This study was approved by the institution's institutional review board.

We describe here the use of calixarenes, methylene (-CH2-) linked phenolic macrocyclic molecules, to stabilize the formation of quantum-confined (Q-) CdS clusters. Specifically, we focus on the use of an amino-derivatized calixarene, para-[(dimethylamino)- methyl]calix[6]arene, to stabilize Q-CdS clusters which have been characterized by High Resolution TEM (HREM), as well as absorption and emission spectroscopies. Under typical preparative conditions, an average particle diameter of 36 Å is obtained. HREM, in combination with Selected Area Diffraction (SAD), confirms the structure of the clusters as zinc blende CdS. Spectroscopic studies using absorption and emission methods indicate that both particle size and cluster photophysics are sensitive to the ratio of CdS to calixarene.

Certain diseases have been associated with the administration of heavy elements as contrast agents to patients undergoing medical imaging procedures. Recently, the presence of gadolinium (Gd) administered as a paramagnetic contrast agent for MRI contrast studies was associated with the incidence of Nephrogenic Fibrosing Dermopathy (NFD), also called Nephrogenic Systemic Fibrosis (NSF). To determine specific causation, Gd and other metallic nanoparticles in various tissues must be detected directly and characterized in-situ. This is done to develop specific mechanisms for the chemical modification of the metal elements as the result of a biologic response. Fixed biopsies embedded in paraffin were sectioned at 3-5 μm thick, deparaffinized by hand (xylene and 100% ethyl alcohol), placed on carbon planchettes, and allowed to air dry. Deparaffinized tissues were examined using a field emission SEM (FE-SEM) to directly detect and image the presence of Gd as well as other metals. Backscatter electron (BSE) imaging (20kV) was used to discern metal particles within tissues. Energy dispersive spectroscopy (EDS) (15kV) was used to verify the specific elements present. This allowed for the spatial characterization of the nanoparticles within the tissues but due to the physical limitations of SEM/EDS, quantification of the amount of metal was not possible. Mass concentration of the metal elements was determined using inductively coupled plasma mass spectrometry (ICP-MS) on digested tissues. Thick tissue sections, >30 μm, were used for ICP-MS to provide enough mass for detection. These sections were taken from the histology blocks adjacent to the thin sections used in the FE-SEM. Gadolinium was detected in skin, heart, lung and liver tissues. The highest concentrations were found in heart and skin; both had average tissue concentrations greater than 200μg/g (100-450μg/g range). In skin, gadolinium nano-particulates were readily seen near cell body locations in autopsy samples and within the cells in biopsy samples. The cells where gadolinium was most easily found were along blood vessels. In the cells the agglomerates appear granular with a size of less than 100 nm. They are diffused throughout the cell but as of this time not associated with any particular cell structure. Subsequent work using TEM will examine that aspect as well as the specific ultrastructure and chemistry of the nanoparticles. In this investigation, gadolinium was detected in the tissues of a number of patients with NSF. Although neither dispositive of a pathophysiologic mechanism, nor proof of causation, the detection and quantification of gadolinium within tissues of NSF patients is supportive of the epidemiologic association between exposure to gadolinium containing contrast material and development of the disease.

There is a real need for a material which absorbs in the visible light of the solar spectrum, is stable in water and at the same time economical. One-dimensional vertically aligned nanotubes have contributed to a great extent towards the visible light driven photoelectrolysis of water. In this work, we give an overview of the different nanotubes obtained through anodization of various metals and their application in the photooxidation of water

Public perception of engineering recognizes its importance to national and international competitiveness, economy, quality of life, security, and other fundamental areas of impact; but uncertainty about engineering among the general public remains. Federal funding trends for education underscore many of the concerns regarding teaching and learning in science, technology, engineering, and mathematics subjects in primary through grade 12 (P-12) education. Conflicting perspectives on the essential attributes that comprise the engineering design process results in a lack of coherent criteria against which teachers and administrators can measure the validity of a resource, or assess its strengths and weaknesses, or grasp incongruities among competing process models. The literature suggests two basic approaches for representing engineering design: a phase-based, life cycle-oriented approach; and an activity-based, cognitive approach. Although these approaches serve various teaching and functional goals in undergraduate and graduate engineering education, as well as in practice, they tend to exacerbate the gaps in P-12 engineering efforts, where appropriate learning objectives that connect meaningfully to engineering are poorly articulated or understood. In this article, we examine some fundamental problems that must be resolved if preengineering is to enter the P-12 curriculum with meaningful standards and is to be connected through learning outcomes, shared understanding of engineering design, and other vestiges to vertically link P-12 engineering with higher education and the practice of engineering. We also examine historical aspects, various pedagogies, and current issues pertaining to undergraduate and graduate engineering programs. As a case study, we hope to shed light on various kinds of interventions and outreach efforts to inform these efforts or at least provide some insight into major factors that shape and define the environment and cultures of the two institutions (including epistemic perspectives, institutional objectives, and political constraints) that are very different and can compromise collaborative efforts between the institutions of P-12 and higher education.

Studies were conducted in 2003 and 2004 over seven environments evaluating rice root growth inhibition (RGI) and foliar injury from penoxsulam at 30 and 60 g ai/ha and bispyribac-sodium at 30 g ai/ha applied to four- to five-leaf rice at three flood timings, 1, 7, and 14 d after herbicide treatment (DAT), for five rice cultivars, ‘Bengal’, ‘Cypress’, ‘Wells’, ‘Cocodrie’, and ‘XP712’. Flooding at 1 and 7 DAT resulted in greater RGI compared with flood at 14 DAT when evaluated 1 wk after flood (WAF). By 2 WAF, RGI was greater with flooding at 1 DAT compared with flooding at 7 DAT for cultivars Bengal, Cypress, and Wells. Analyzing flood timing 1 DAT, bispyribac-sodium reduced root growth of Bengal and Cypress compared with penoxsulam at 30 g/ha at 1 week after treatment (WAT). At 2 WAT, RGI for Cocodrie was higher following penoxsulam at 60 g/ha when compared with bispyribac-sodium. By 3 WAT, RGI was higher following penoxsulam at 60 g/ha when compared with penoxsulam at 30 g/ha for Cocodrie and greater than bispyribac-sodium and penoxsulam at 30 g/ha for Cypress. Foliar injury following penoxsulam at both rates was less than injury following bispyribac-sodium for all cultivars except XP712 at 1 WAT. XP712 resulted in < 5% RGI and < 6% foliar injury at each evaluation. Rice grain yield was not affected by herbicide treatment for any cultivar compared with the standard treatment of propanil plus quinclorac.

Clomazone is an effective herbicide widely used for PRE grass control in rice. However, use of clomazone on sandy textured soils of the western Texas rice belt can cause serious rice injury. Two field experiments at three locations were conducted in 2002 and 2003 to determine the optimum rate range that maximizes barnyardgrass and broadleaf signalgrass control and minimizes rice injury across a wide variety of soil textures and planting dates. At Beaumont (silty clay loam), Eagle Lake (fine sandy loam), and Ganado (fine sandy loam), TX, PRE application of 0.34 kg ai/ha clomazone applied to rice planted in March, April, or May optimized barnyardgrass and broadleaf signalgrass control and rice yield while minimizing rice injury. Data suggest that, although injury might occur, clomazone is safe to use in rice on sandy textured soils.

Field experiments were conducted in 2002 and 2003 in Beaumont, TX, to evaluate the effect of flood timing on red rice control with imazethapyr applied at different cultivated rice growth stages. Treatments included flood establishment at 1, 7, 14, and 21 d after postemergence (POST) herbicide treatment (DAT). Imazethapyr was applied preemergence at 70 g ai/ha followed by 70 g/ ha POST when imidazolinone-tolerant rice cultivar ‘CL-161’ had three- to four-leaf stage (EPOST) or five-leaf stage (LPOST). Flood needed to be established within 14 DAT to achieve at least 95% red rice control when imazethapyr was applied EPOST. However, flood needed to be established within 7 DAT to provide at least 95% red rice control when imazethapyr was applied LPOST. Delaying the flood up to 21 DAT reduced rice grain yield for both application timings.

A study was conducted in 2001 and 2002 in Texas to evaluate red rice control and crop response of imidazolinone-tolerant rice with imazethapyr on coarse-textured soils. Because imazethapyr was not registered for use on imidazolinone-tolerant rice on coarse-textured soils in Texas, crop response was evaluated to determine whether imidazolinone-tolerant rice yields would be reduced with sequential applications of imazethapyr on soils having greater than 50% sand content. The treatment factors consisted of preemergence (PRE) applications of imazethapyr at 50, 70, or 87 g ai/ ha followed by (fb) preflood (PREFLD) applications of 35 or 50 g/ha. Imazethapyr at 70 g/ha PRE fb 70 g/ha PREFLD was added as a seventh treatment. PRE applications were activated by rainfall or surface irrigation after application, and PREFLD applications were sprayed 1 to 2 d before application of the permanent flood. In both years, 100% red rice control was achieved with all rate combinations. Early-season visual rice injury ranged from 5 to 21% and did not result in yield losses, indicating that imazethapyr is safe on coarse-textured soils.