Skip to main content Accessibility help
×
Hostname: page-component-76fb5796d-9pm4c Total loading time: 0 Render date: 2024-04-28T04:23:12.038Z Has data issue: false hasContentIssue false

11 - CaseStudy: The Carbon Cycle

Published online by Cambridge University Press:  05 May 2016

Graham W. Griffiths
Affiliation:
City University London
Get access

Summary

INTRODUCTION

One of the great scientific endeavors of the twenty-first century is the concerted effort by international research groups to understand how the global climate is changing. There is general agreement that sustained emissions of carbon dioxide into the atmosphere as a result of anthropological activities is the main cause of rising carbon dioxide (CO2) in the atmosphere. Increased levels of CO2 results in more heat, in the form of infra-red radiation, being trapped in the atmosphere—the so-called greenhouse effect. This additional heat tends, over time, to increase the global temperature. Thus, the rising concentrations of CO2 in the atmosphere is a prime candidate for the cause of climate change, which is predicted to increase weather extremes, melting of glaciers and the rise in global sea levels [IPCC-07].

This case study is an attempt to illustrate some of the methods used to study climate change using a relatively simple model consisting of a system of algebraic and differential equations. We restrict our discussion to the major physical processes in the carbon cycle, with the associated equations and solution methods being explained in some detail.

THE MODEL

The mathematical model used here is based on that developed by James Walker [Walk-91], which has also been featured elsewhere to demonstrate numerical procedures [Mol-05]. However, the scope has been extended to include detailed representation of airgas exchange between atmosphere and ocean, improved seawater chemistry calculations, including pH levels, and the inclusion of basic radiation calculations for the atmosphere. We will use the model to illustrate the main processes involved when large quantities of CO2 are emitted into the atmosphere. The model consists of three main reservoirs: the atmosphere, surface water of the oceans and ocean deep water. The calculations attempt to predict how fossil fuel emissions result in higher concentrations of CO2 in the atmosphere and how a large fraction of these emissions is absorbed into the oceans. The effect of increased levels of CO2 is shown to increase absorption of terrestrial infra-red radiation by the atmosphere and, hence, a corresponding rise in the effective global temperature of the Earth. The main model parameters are detailed in Table 11.1.

Although this model is extremely simplified, it does bring out the salient features of the effect of increasing levels of carbon dioxide emissions.

Type
Chapter
Information
Numerical Analysis Using R
Solutions to ODEs and PDEs
, pp. 539 - 584
Publisher: Cambridge University Press
Print publication year: 2016

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[And-10] Andrews, D. (2010), An Introduction to Atmospheric Physics, Cambridge University Press.
[ASTM-05] ASTM (2005), ASTM G173-03e1 Standard Tables for Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on 37◦ Tilted Surface, January. Year 2000 ASTMStandard Extraterrestrial SpectrumReference E-490-00 data are available for download at Solar Spectra:Air Mass Zero: http://rredc.nrel.gov/solar/spectra/am0/.
[Bac-73] Bacastow, R. and C. D., Keeling (1973), Atmospheric Carbon Dioxide and Radiocarbon in the Natural Carbon Cycle: II. Changes from A.D. 1700 to 2070 as Deduced from a Geochemical Model, in Carbon and the Biosphere, G. M., Woodwell and E. V., Pecan, editors, Atomic Energy Commission, Technical Information Service, pp. 86–135.
[Bee-11] Wikipedia (2011), The Beer–Lambert Law, available online at http://http://en.wikipedia.org/wiki/Beer-Lambert_law.
[Bod-13] Boden, T. A., G., Marland and R. J., Andres (2013), Global, Regional, and National Fossil-Fuel CO2 Emissions, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, doi: 10.3334/ CDIAC/00001_V2013, available online at http://cdiac.ornl.gov/ftp/ndp030/global.1751_2010.ems
[Bol-84] Boltzmann, L. (1884), Ableitung des Stefan'schen Gesetzes, betreffend die Abhangigkeit derWarmestrahlung von der Temperatur aus der electromagnetischen Lichttheorie, Annalen der Physik und Chemie 22, 291–294.Google Scholar
[Bro-82] Broecker, W. S. and T.-H., Peng (1982), Tracers in the Sea, Lamont-Doherty Earth Observatory.
[Cal-05] Caldeira, K. and M. E., Wickett (2005), Ocean Model Predictions of Chemistry Changes from Carbon Dioxide Emissions to the Atmosphere and Ocean, Journal of Geophysical Research 110, 1–12.Google Scholar
[Dic-90] Dickson, A. G. (1990), Thermodynamics of the Dissociation of Boric Acid in Synthetic Seawater from 273.15 to 298.15 K, Deep-Sea Research 37, 755–766.Google Scholar
[DoE-94] Dickson, A. G. and C., Goyet, eds. (1994), Handbook of Methods for the Analysis of the Various Parameters of the Carbon Dioxide System in Seawater, version 2, ORNL/CDIAC-74.
[Egl-10] Egleston, E. S., C. L., Sabine and F. M. M., Morel (2010), Revelle Revisited: Buffer Factors that Quantify the Response of Ocean Chemistry to Changes in DIC and Alkalinity, Global Biogeochemical Cycles 24-1, 1–9.Google Scholar
[Eme-08] Emerson, S. and J., Hedges (2008), Chemical Oceanography and the Marine Carbon Cycle, Cambridge University Press.
[Fal-00] Falkowski, P., et al. (2000), The Global Carbon Cycle: A Test of Our Knowledge of Earth as a System, Science, October 13.
[Han-01] Hansen, J. E., R., Ruedy, M., Sato, M., Imhoff, W., Lawrence, D., Easterling, T., Peterson, and T., Karl (2001), A Closer Look at United States and Global Surface Temperature Change, Journal of Geophysical Research 106, 23947–23963.Google Scholar
[Han-11] Hansen, J., M., Sato, P., Kharecha, and K. von, Schuckmann (2011), Earth's Energy Imbalance and Implications, Atmospheric Chemistry and Physics 11, 13421– 13449.Google Scholar
[Hay-15] Hay, C. C., E., Morrow, R. E., Kopp and J.X., Mitrovica (2015), Probabilistic Reanalysis of Twentieth-Century Sea-Level Rise, Nature, 517-7535, 481–484.Google Scholar
[Hot-67] Hottel, H. C. and A. F., Sarofim, (1967), Radiative Transfer, McGraw-Hill.
[IPCC-01] IPCC (2001), Radiative Forcing of Climate Change, in Climate Change 2001: The Scientific Basis: Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change, [J.T., Houghton, Y., Ding, D. J., Griggs, M., Noguer, P. J. van der, Linden, X., Dai, K., Maskell and C.A., Johnson, editors, Cambridge University Press, pp. 349–416.
[IPCC-07] IPCC (2007), Climate Change 2007:The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, S., Solomon, D., Qin, M., Manning, M., Marquis, K., Averyt, M. M. B., Tignor, H. L., Miller Jr. and Z., Chen, editors, Cambridge University Press.
[IPCC-13] IPCC (2013), Climate Change 2013:The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, T. F., Stocker, D., Qin, G.-K., Plattner, M., Tignor, S. K., Allen, J., Boschung, A., Nauels, Y., Xia, V., Bex and P. M., Midgley, editors, Cambridge University Press.
[Jac-05] Jacobson, M. Z. (2005), Fundamentals of AtmosphericModeling, 2nd ed., Cambridge University Press.
[Kas-89] Kasten, F. and A. T., Young (1989), Revised Optical Air Mass Tables and Approximation Formula, Applied Optics 28-22, 4735–4738.Google Scholar
[Kee-09] Keeling, R. F., S. C., Piper, A. F., Bollenbacher and S. J., Walker (2009), Mauna Loa Observatory Data, Scripps Institution of Oceanography, University of California, available online at http://cdiac.ornl.gov/ftp/trends/co2/maunaloa.co2.
[Kie-97] Kiehl, J. T. and K. E., Trenberth (1997), Earth's Annual Global Mean Energy Budget, Bulletin of the American Meteorological Association 78, 197–206.Google Scholar
[Kle-09] Kleypas, J. A. and K. K., Yates (2009), Coral Reefs and Ocean Acidification, Oceanography 22-4, 108–117.Google Scholar
[Kop-04] Kopp, G., G., Lawrence and G., Rottman (2004), Total IrradianceMonitor Design and On-Orbit Functionality, SPIE Proceedings 5171, 14–25.Google Scholar
[Lio-02] Liou, K. N. (2002), An Introduction to Atmospheric Radiation, 2nd ed., Academic Press.
[Lue-00] Luecker, T. J., A. G., Dickson and C. D., Keeling (2000), Ocean CO2 Calculated from Dissolved Inorganic Carbon, Alkalinity, and the Equation for K1 and K2: Validation Based on Laboratory Measurements of CO2 in Gas and Seawater at Equilibrium, Marine Chemistry 70, 105–119.Google Scholar
[McH-15] McHugh, A. J., G. W., Griffiths and W. E., Schiesser (2015), An IntroductoryCO2 Model, World Scientific Press.
[Mar-13] Marland, G., T. A., Boden and R. J., Andres (2013), Global, Regional, and National CO2 Emissions, in Trends:A Compendium of Data on Global Change, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy.
[Mil-09] Miller, S., C., Marandino, W. de Bruyn, W. and E. S., Saltzman (2009), Air Sea Gas Exchange of CO2 and DMS in the North Atlantic by Eddy Covariance, Geophysical Research Letters 36, L15816.Google Scholar
[Mil-06] Millero, F. (2006), Chemical Oceanography, 3rd ed., CRC Press.
[Mol-05] Moler, C. (2005), Numerical Computing with MATLAB, Mathworks, available online at http://www.mathworks.com/moler/odes.pdf.
[Mor-15] Morrison, A. K., T. L., Frolicher and J. L., Sarmiento (2015), Upwelling in the Southern Ocean, Physics Today 68-1, 27–32.Google Scholar
[Nef-94] Neftel, H., H., Friedli, E., Moor, H., Lotscher, H., Oeschger, U., Siegenthaler and B., Stauffer (1994), Historical CO2 Record from the Siple Station Ice Core, Physics Institute, University of Bern, available online at http://cdiac.ornl.gov/ftp/trends/co2/siple2.013.
[NOAA-14] NOAA(2014), Annual Greenhouse Gas Index (AGGI), NationalOceanic andAtmosphericAdministration, Earth SystemResearch Laboratory, GlobalMonitoring Division, available online at esrl.noaa.gov/gmd/aggi/aggi.html.
[Pei-92] Peixoto, J. P. and A. H., Oort (1992), Physics of Climate, Springer.
[Pie-10] Pierrehumbert, R. T. (2010), Principles of Planetary Climate, Cambridge University Press.
[Pil-88] Pilson, M. E. Q. (1998), An Introduction to the Chemistry of the Sea, Prentice Hall.
[Pla-00] Planck, M. (1900), Ueber das Gesetz der Energieverteilung im Normalspectrum, Verh. D. Physik 2, 237–239. [Subsequently in English: Planck, M. (1901), On the Law of Distribution of Energy in the Normal Spectrum, Annals of Physics 4, 553.]Google Scholar
[Rev-57] Revelle, R. and H. E., Suess (1957), Carbon Dioxide Exchange between Atmosphere and Ocean and the Question of an Increase of Atmospheric CO2 during Past Decades, Tellus 9, 18–27.Google Scholar
[Sab-04] Sabine, C. L. et al. (2004), The Oceanic Sink for Anthropogenic CO2, Science, 305-5682, 367–371.Google Scholar
[Sar-02] Sarmiento, J. L. and N., Grubar (2002), Sinks for Anthropogenic Carbon, Physics Today, August, 30–36.
[Ste-79] Stefan, J. (1879), Uber die Beziehung zwischen der Warmestrahlung und der Temperatur [On the relation between heat radiation and temperature], Sitzungsberichte der mathematisch-naturwissenschaftlichen Classe der kaiserlichen Akademie derWissenschaften 79, 391–428.Google Scholar
[Stew-07] Stewart, R. H. (2007), Introduction to Physical Oceanography, Texas A&M University, available online at http://oceanworld.tamu.edu/resources/ocng_textbook/PDF_files/book_pdf_files.html.
[TIM-07] TIM (2007), Total Solar Irradiance (TSI) Data. TIM data are regularly updated and available for download at the Solar Radiation and Climate Experiment (SORCE), available online at http://lasp.colorado.edu/sorce/data/tsi_data.htm
[Wall-06] Wallace, J. M. and P. V., Hobbs (2006), Atmospheric Science: An Introductory Survey, 2nd ed., Academic Press.
[Walk-91] Walker, J. C. G. (1991), Numerical Adventures with Geochemical Cycles, Oxford University Press.
[Wan-92] Wanninkhof, R. (1992), Relationship between Wind Speed and Gas Exchange over the Ocean, Journal of Geophysical Research 97-C5, 7373–7382.Google Scholar
[Wie-93] Wien, W. (1893), Eine neue Beziehung der Strahlung schwarzer Korper zum zweiten Hauptsatz der Warmetheorie [A new relationship between black body radiation and the second law of thermodynamics], Sitzungsberichte der Königlichen Preußischen Akademie der Wissenschaften zu Berlin, 55–62Google Scholar
[Wei-74] Weiss, R. F. (1974), Carbon Dioxide inWater and Seawater: The Solubility of a Nonideal Gas, Marine Chemistry 2, 203–215.Google Scholar
[Whi-11] Whiteley, N. (2011), Physiological and EcologicalResponses of Crustaceans to Ocean Acidification, Marine Ecology Progress Series 430, 257–271.Google Scholar
[You-94] Young, A. T. (1994), Air Mass and Refraction, Applied Optics 33, 1108–1110.Google Scholar
[Zdu-07] Zdunkowski, W., T., Trautman and A., Bott (2007), Radiation in the Atmosphere: A Course in Theoretical Meteorology, Cambridge University Press.
[Zee-06] Zeebe, R. (Lead Author) and J.-P., Gattuso (Topic Editor) (2006), Marine Carbonate Chemistry, in Encyclopedia of Earth, C. J., Cleveland, editor, Environmental Information Coalition, National Council for Science and the Environment, available online at http://www.eoearth.org/article/Marine_carbonate_chemistry.

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×