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11 - Dilute solutions

Published online by Cambridge University Press:  07 September 2011

Alberto Patiño Douce
Affiliation:
University of Georgia
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Summary

The focus of this chapter is on liquid solutions in which one component is present in much greater abundance, say at least one order of magnitude greater, than all others. Examples that underscore the importance of this type of solutions include seawater, and natural terrestrial waters in general, but one can imagine more exotic possibilities, such as hydrocarbon-based solutions on Titan's surface and ammonia-based solutions in its interior. What all of these examples share is the fact that it is convenient to make a distinction between dilute solutes that may not be liquid in their standard states, and a liquid solvent that is generally close to being in its standard state. Depending on the nature of the solvent and of the solutes the latter may exist as electrically neutral chemical species, as ions, or as a combination of both. Solutions in which solutes dissociate into ions are known as electrolyte solutions. Among these, those in which water is the solvent are by far the most important ones, at least in terrestrial environments. The chapter emphasizes aqueous electrolyte solutions, but virtually all of the thermodynamic framework is applicable to any type of dilute solution. We begin with a discussion of dilute solutions in general, and shift the focus to electrolyte solutions in Section 11.3.

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Publisher: Cambridge University Press
Print publication year: 2011

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  • Dilute solutions
  • Alberto Patiño Douce, University of Georgia
  • Book: Thermodynamics of the Earth and Planets
  • Online publication: 07 September 2011
  • Chapter DOI: https://doi.org/10.1017/CBO9780511974854.012
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  • Dilute solutions
  • Alberto Patiño Douce, University of Georgia
  • Book: Thermodynamics of the Earth and Planets
  • Online publication: 07 September 2011
  • Chapter DOI: https://doi.org/10.1017/CBO9780511974854.012
Available formats
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Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Dilute solutions
  • Alberto Patiño Douce, University of Georgia
  • Book: Thermodynamics of the Earth and Planets
  • Online publication: 07 September 2011
  • Chapter DOI: https://doi.org/10.1017/CBO9780511974854.012
Available formats
×