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APPENDIX: The Electrolysis of Steam

Published online by Cambridge University Press:  05 August 2011

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Summary

In Art. 201 of the text there is a description of Perrot's experiments on the electrolysis of steam. As these experiments throw a great deal of light on the way in which electrical discharges pass through gases I have, while this work has been passing through the press, made a series of experiments on the same subject.

The apparatus I used was the same in principle as Perrot's. I made some changes, however, in order to avoid some inconveniences to which it seemed to me Perrot's form was liable. One source of doubt in Perrot's experiments arose from the proximity of the tubes surrounding the electrodes to the surface of the water, and their liability to get damp in consequence. These tubes were narrow, and if they got damp the sparks instead of passing directly through the steam might conceivably have passed from one platinum electrode to the film of moisture on the adjacent tube, then through the steam to the film of moisture on the other tube and thence to the other electrode. If anything of this kind happened it might be urged that since the discharge passed through water in its passage from one terminal to the other, some of the gases collected in the tubes gg (Fig. 84) might have been due to the decomposition of the water and not to that of the steam.

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Notes on Recent Researches in Electricity and Magnetism
Intended as a Sequel to Professor Clerk-Maxwell's Treatise on Electricity and Magnetism
, pp. 559 - 570
Publisher: Cambridge University Press
Print publication year: 2010
First published in: 1893

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