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Experiment 27 - Experiments for compressibility and vapor pressure

Published online by Cambridge University Press:  05 June 2012

R. A. Gaggioli
Affiliation:
Georgia Institute of Technology
W. J. Wepfer
Affiliation:
University of Lowell
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Summary

Principle

An experiment that involves the measurement of thermostatic properties is described. Temperatures and pressures of a real gas are measured in order that v(T, P) can be constructed. In addition the saturation pressure as a function of temperature Ps(T) is measured so that heats of vaporization can be evaluated.

Object

The primary objective of this experiment is the determination of v(T, P) and Ps(T) over a specified range of temperatures and pressures. In addition, other goals include the: (1) comparison of the measured v(T, P) data with published data and with v(T, P) functions obtained from the principle of corresponding states, and (2) comparison of the measured Ps(T) data with published data and the approximation ln (Ps(T)) = m/T + b.

Background

Most processes, devices, and systems built by engineers utilize gases and liquids. Such analysis and design invariably requires the evaluation of various thermostatic properties. For gases all thermostatic properties can be determined from knowledge of the “mechanical” equation of state v(T, P) and either the “thermal or caloric” equation of state (U = f(T, P)) or cp(T), which is the perfect-gas heat capacity. In addition to these functions, knowledge of Ps(T) provides a means of evaluating the thermostatic properties for two-phase materials. Finally, excursions into the liquid region also require that the heat capacity of the liquid be known.

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Publisher: Cambridge University Press
Print publication year: 1994

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