The development of particle detectors practically starts with the discovery of radioactivity by Henri Becquerel in the year 1896. He noticed that the radiation emanating from uranium salts could blacken photosensitive paper. Almost at the same time X rays, which originated from materials after the bombardment by energetic electrons, were discovered by Wilhelm Conrad Röntgen.

The first nuclear particle detectors (X-ray films) were thus extremely simple. Also the zinc-sulfide scintillators in use at the beginning of the last century were very primitive. Studies of scattering processes – e.g. of α particles – required tedious and tiresome optical registration of scintillation light with the human eye. In this context, it is interesting to note that Sir William Crookes experimenting in 1903 in total darkness with a very expensive radioactive material, radium bromide, first saw flashes of light emitted from the radium salt. He had accidentally spilled a small quantity of this expensive material on a thin layer of activated zinc sulfide (ZnS). To make sure he had recovered every single speck of it, he used a magnifying glass when he noticed emissions of light occurring around each tiny grain of the radioactive material.