Cadmium hydroxide nitrate dihydrate, Cd5(OH)8(NO3)2·2H2O, and zinc hydroxide nitrate diammoniac, Zn5(OH)8(NO3)2·2NH3, have been investigated by means of X-ray powder diffraction. Their unit cell dimensions were found by an indexing program and confirmed by single crystal studies. Precise data collected with strictly monochromatic radiation are reported. The figures of merit are F30=118 (0.0071,36) for the cadmium compound and F30=53 (0.015,38) for the zinc compound. A short discussion of the unit cell parameters compared to those of a related zinc hydroxide nitrate dihydrate is presented.

The crystal structure of the spinel polymorph of Fe2SiO4, synthesized at high temperature (900°C) and high pressure (70 kbar), was studied by the Rietveld analysis of X-ray powder diffraction data collected with a Guinier-Hägg camera. The compound is cubic, space group , with cell dimension: a= 8.2413(6) Å, V= 559.8(1) Å3, Z= 8, Cell Wt. = 1630.2, Dx= 4.835 g·cm−3, Do= 4.75 g·cm−3. The figure of merit is F10= 92(0.011, 10). The final R value is RF= 0.058. The crystal has a mixed normal-inverse spinel structure. The site occupancy refinement showed that 37.9% of the silicon was found in the octahedral site (M site), while 18.9% of the iron occupied the tetrahedral site (T site). Due to the larger displacement of Si4+ion by Fe2+ion, the positional parameter of oxygen atom (0.3689) is smaller than that of X-ray single crystal structure (0.3658), and the average Si-O bond (1.697(1)Å) is longer and Fe-O bond (2.112(1)Å) is shorter than those of X-ray single crystal structure.

Powders of Al and Ti were blended and compacted, the compact then melted in an attempt to produce single phase Al3Ti. Optical microscopy of the cast and homogenized specimen revealed an almost single phase microstructure with minor amounts of a second phase. The composition of the matrix was measured using fully quantitative energy dispersive X-ray analysis. By use of X-ray diffractometry, the interplanar spacings and the associated integrated peak intensities were experimentally measured for the binary DO22 compound, Al3Ti. Using standard structure factor equations, the intensities were calculated for the various reflections. Good agreement was obtained between calculated and observed intensities.

X-ray powder diffraction data for the compound Di-(1-phenylisopropyl)formamide, C19H23NO are reported. The crystals are monoclinic and the space group P21/c, with a = 10.764(2), b = 14.893(2), c = 10.862(2) Å, β= 108.49(1)°, Z = 4, Dx= 1.132, Dm= 1.120(2) gm/cm3.

Observed and calculated X-ray powder diffraction data are reported for ZnGa2S4. After corrections to the observed data, refined tetragonal unit cell parameters ao= 5.2779(2), co= 10.4179(8) Å (λ = 1.54051 Å) were obtained. The powder pattern for ZnGa2S4was calculated in space group Iwith a stoichiometric amount of Zn and Ga randomly distributed amongst the two cation sites.

X-Ray powder diffraction data and unit cell parameters of industrially produced, as well as bench scale prepared, ammonium paratungstate tetrahydrate are reported and compared with current Powder Data File (PDF) (1989) patterns. A least-squares refinement resulted in two slightly different unit cells. Both cells are monoclinic with S.G. = P21/n(14), Z = 2. The density, 4.639(2)kg/m3, calculated from one of these unit cells corresponds reasonably well with a measured value of 4.61 (2). It has, however, not been possible to determine at present why ammonium paratungstate tetrahydrate has two unit cells. No relation between the crystalline form and the method of preparation nor the exact water content could be established.

A new X-ray powder diffraction pattern for α-Si3N4is presented and compared with the current PDF pattern. The necessity for an updated pattern is discussed.

Arsenic molybdate, As4Mo3015, has been investigated by means of X-ray powder diffraction. The diffraction data were collected with a focussing (Guinier-type) transmission diffractometer equipped with a primary-beam monochromator (Ge 111) for CuKα radiation and a scanning position-sensitive detection system. A monoclinic unit cell was determined using an indexing program.

X-ray powder diffraction data for Bi2Mo3O12·nH2O (n = 4.75) were obtained. The crystal system was determined to be monoclinic with space group P21or P21/m. The unit cell parameters were refined to a = 6.334(2) Å, b = 11.593(2) Å, c = 5.777(2) Å, and β= 113.166(8)°.

Notwithstanding expectations of a pure pyrochlore structure (cubic space group Fd3m (227) with Z=8) terbium titanate turns out, like many pyrochlore compounds, to be slightly disordered in the cation and the oxygen lattice so that it partially (for 10%) resembles a structure with fluorite properties (space group Fm3m (225) with Z = 2).