Hostname: page-component-76fb5796d-2lccl Total loading time: 0 Render date: 2024-04-26T20:59:19.928Z Has data issue: false hasContentIssue false

Structural characterization of a new zinc phosphate: (ZnPO4)4(H3PO4)2(C4N2H14)2

Published online by Cambridge University Press:  05 March 2012

Adriana Echavarría
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia
Luz Amparo Palacio
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia
Carlos Saldarriaga
Affiliation:
Department of Chemical Engineering, University of Antioquia, A. A. 1226, Medellín, Colombia

Abstract

A new zinc phosphate was synthesized by the hydrothermal reaction of zinc oxide and phosphoric acid in the presence of 1,4-diaminebutane. The formula of the product is (ZnPO4)4(H3PO4)2(C4N2H14)2 and crystallizes in the triclinic system with a=8.6590(3) Å, b=10.3467(3) Å, c=8.3910(3) Å, α=102.180(2)°, β=93.676(2)°, and γ=88.203(2)°.

Type
Technical Articles
Copyright
Copyright © Cambridge University Press 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Altamore, A., Burla, M. C., Giacovazzo, C., Guagliardi, A., Moliterni, A., and Polidori, G. (1995). “EXTRA: A program for extracting Structure Factor Amplitudes from Powder Diffraction Data,” J. Appl. Crystallogr. JACGAR 28, 842846. acr, JACGAR CrossRefGoogle Scholar
Boultif, A., and Loue¨r, D. (1991). “Indexing of powder diffraction patterns for low-symmetry lattices by the successive dichotomy method,” J. Appl. Crystallogr. JACGAR 24, 987993. acr, JACGAR CrossRefGoogle Scholar
Echavarría, A., and Saldarriaga, C. (1997). “Nuevo me´todo para la síntesis de fosfatos de zinc microporosos,” Revista Colombiana de Química, Bogota´ (Colombia) RCLQAY 26, 5156., RCLQAY Google Scholar
Echavarría, A., and Saldarriaga, C. (2000). “A zinc phosphate with laminar structure: (ZnPO4)4(H2PO4)2(C4N2H14)2,Microporous and Mesoporous Materials MIMMFJ 42, 5964., MIMMFJ CrossRefGoogle Scholar
Harrison, W., Martin, T., Gier, T., and Stucky, G. (1992). “Tetrahedral-atom Zincophosphate Structures: Synthesis and Structural Characterization of Two Novel Anionic Eight-ring Frameworks containing Cationic 1,4-Diazabicyclo[2,2,2]octane Guests,” J. Mater. Chem. JMACEP 2, 175181. jtc, JMACEP CrossRefGoogle Scholar
Shirley, R. (1999). “The CRYSFIRE System for Automatic Powder Indexing: User’s Manual,” The Lattice Press, 41 Guildford Park Avenue, Guildford, Surrey GU2 5NL, England.Google Scholar
Visser, J. W. (1969). “A Fully Automatic Program for Finding the Unit Cell from Powder Data,” J. Appl. Crystallogr. JACGAR 2, 8995. acr, JACGAR CrossRefGoogle Scholar
Werner, P.-E., Eriksson, L., and Westdahl, M. (1985). “TREOR, a Semi-Exhaustive Trial-and-Error Powder Indexing Program for All Symmetries,” J. Appl. Crystallogr. JACGAR 18, 367370. acr, JACGAR CrossRefGoogle Scholar
WINPLOTR, Thierry Roisnel & Juan Rodríguez-Carvajal, Laboratoire Le´on Brillouin (CEA-CNR), Centre dE´tudes de Saclay, 91191 Gif-sur-Yvette, Cedes (France) and Laboratoire de Chimie du Solide et Inorganique Mole´culaire (UMR6511), Universite´ de Rennes 1, 35042 Rennex cedex (France). http://www-llb.cea.fr/fullweb/winplotr/winplotr.htm.Google Scholar