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Impact of pressure on the structure of glass and its material properties

Published online by Cambridge University Press:  10 October 2017

Philip S. Salmon  and
Liping Huang
Philip S. Salmon
Affiliation:
University of Bath, UK; p.s.salmon@bath.ac.uk
Liping Huang
Affiliation:
Rensselaer Polytechnic Institute, USA; huangl5@rpi.edu
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Abstract

High pressures have a significant impact on the structure-related properties of glass and are encountered in scenarios ranging from fracture mechanics, where stresses in the gigapascal regime are easily generated by sharp-contact loading, to the manufacture of permanently densified materials with tuned physical characteristics. Here, we consider pressure-induced structural changes that occur in glass and show that, for oxide materials, the oxygen-packing fraction plays a key role in determining when these changes are likely to occur. Fivefold coordinated Si atoms appear as important intermediaries in the pressure-induced deformation of silica glass.

Keywords

amorphousoxidedensificationelastic propertiesnanoindentationsimulationstructural
Type
Research Article
Information
MRS Bulletin , Volume 42 , Issue 10: Materials Under Pressure , October 2017 , pp. 734 - 737
Copyright
Copyright © Materials Research Society 2017 

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