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New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part II. Zadovite, BaCa6[(SiO4)(PO4)](PO4)2F and aradite, BaCa6[(SiO4)(VO4)](VO4)2F, from paralavas of the Hatrurim Basin, Negev Desert, Israel

Published online by Cambridge University Press:  02 January 2018

E. V. Galuskin ,
F. Gfeller ,
I. O. Galuskina ,
A. Pakhomova ,
T. Armbruster ,
Y. Vapnik ,
R. Włodyka ,
P. Dzierżanowski  and
M. Murashko
E. V. Galuskin*
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
F. Gfeller
Affiliation:
Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
I. O. Galuskina
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
A. Pakhomova
Affiliation:
Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
T. Armbruster
Affiliation:
Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
Y. Vapnik
Affiliation:
Department of Geological and Environmental Sciences, Ben-Gurion University of the Negev, POB 653, Beer-Sheva 84105, Israel
R. Włodyka
Affiliation:
Faculty of Earth Sciences, Department of Geochemistry, Mineralogy and Petrography, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
P. Dzierżanowski
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, Warsaw University, al. Żwirki i Wigury 93, 02-089 Warsaw, Poland
M. Murashko
Affiliation:
Saint Petersburg State University, Faculty of Geology, 7-9 Universitetskaya nab., St Petersburg, 199034, Russia
*
*E-mail: evgeny.galuskin@us.edu.pl
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Abstract

Zadovite, BaCa6[(SiO4)(PO4)](PO4)2F (R3m, a = 7.0966(1) Å, c = 25.7284(3), V = 1122.13(3) Å3, Z = 3) and aradite, BaCa6[(SiO4)(VO4)] (VO4)2F (R3m, a = 7.1300(1), c = 26.2033(9) Å, V = 1153.63(6) Å3, Z = 3) are two new mineral species of a novel modular structure type related closely to the structure of nabimusaite, KCa12(SiO4)4(SO4)2O2F. Both minerals occur in paralavas enclosed in pyrometamorphic rocks of the Hatrurim Complex, Negev desert, Israel. Zadovite and aradite are colourless, transparent with a white streak, have a vitreous lustre and an uneven fracture. Both minerals are uniaxial (–) with refractive indices (589 nm) ω = 1.711(2), ε = 1.708(2) (zadovite) and ω = 1.784(3), ε = 1.780(3) (aradite). The zadovite structure type comprises two tetrahedral sites, which may host a broad compositional range of atoms such as Si, P, V and S. Results of electron microprobe analyses show a correlation between excess Si4+ and S6+ contents, suggesting the substitution scheme 2(P,V)5+ = Si4+ + S6+ at the tetrahedral sites. This points to the possibility of new minerals isostructural with zadovite with end-member formulae BaCa6(SiO4)2[(PO4)(SO4)]F, BaCa6(SiO4)2[(VO4)(SO4)]F, BaCa6[(SiO4)1.5(SO4)0.5](PO4)2F and BaCa6[(SiO4)1.5(SO4)0.5](VO4)2F. The Raman spectra of aradite and zadovite reflect the varying PO4 (e.g. change of band intensity at ∼1031 cm–1) and VO4 contents (e.g. change of band intensity at ∼835 cm–1). The presence of SO4 leads to an additional Raman band at ∼997 cm–1. The structure of zadovite-series minerals belonging to the nabimusaite group is characterized by a 1:1 alternation of antiperovskite-like {[FCa6](TO4)2}4+ modules and Ba(TO4)2–4 modules.

Keywords

zadovitearaditenew mineralsmodular structureantiperovskite structureRaman spectroscopyHatrurim ComplexIsrael
Type
Research Article
Information
Mineralogical Magazine , Volume 79 , Issue 5 , October 2015 , pp. 1073 - 1087
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

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