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Cathodoluminescence Efficiency Dependence on Excitation Density in n-Type Gallium Nitride

Published online by Cambridge University Press:  14 March 2003

Matthew R. Phillips
Affiliation:
Microstructural Analysis Unit, University of Technology, Sydney, Broadway, NSW, 2007, Australia
Hagen Telg
Affiliation:
Microstructural Analysis Unit, University of Technology, Sydney, Broadway, NSW, 2007, Australia Hagen Telg is on leave from Festörperinstitut, Technische Universität, Berlin, Germany
Sergei O. Kucheyev
Affiliation:
Department of Electronic Materials Engineering, RSPhysSE, The Australian National University, Canberra, ACT, 0200, Australia
Olaf Gelhausen
Affiliation:
Microstructural Analysis Unit, University of Technology, Sydney, Broadway, NSW, 2007, Australia
Milos Toth
Affiliation:
Cavendish Laboratory, University of Cambridge, Madingley Road, Cambridge, CB3 0HE, United Kingdom
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Abstract

Cathodoluminescence (CL) spectra from silicon doped and undoped wurtzite n-type GaN have been measured in a SEM under a wide range of electron beam excitation conditions, which include accelerating voltage, beam current, magnification, beam diameter, and specimen temperature. The CL intensity dependence on excitation density was analyzed using a power-law model (ICLJm) for each of the observed CL bands in this material. The yellow luminescence band present in both silicon and undoped GaN exhibits a close to cube root (m = 0.33) dependence on electron beam excitation at both 77 K and 300 K. However, the blue (at 300 K) and donor-acceptor pair (at 77 K) emission peaks observed in undoped GaN follow power laws with exponents of m = 1 and m = 0.5, respectively. As expected from its excitonic character, the near band edge emission intensity depends linearly (m = 1) in silicon doped GaN and superlinearly (m = 1.2) in undoped GaN on the electron beam current. Results show that the intensities of the CL bands are highly dependent not only on the defect concentration but also on the electron-hole pair density and injection rate. Furthermore, the size of the focussed electron beam was found to have a considerable effect on the relative intensities of the CL emission peaks. Hence SEM parameters such as the objective lens aperture size, astigmatism, and the condenser lens setting must also be considered when assessing CL data based on intensity measurements from this material.

Type
PAPERS FROM THE AUSTRALIAN MICROBEAM ANALYSIS SOCIETY
Copyright
© 2003 Microscopy Society of America

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