Peroxide speciation and formaldehyde measurements have been made on ice cores retrieved from Law Dome, Antarctica. Measurements were made for ice deposited during four different periods: modern, pre-industrial Holocene, early Holocene and Last Glacial Maximum (LGM). The data show modern peroxide levels >50% above pre-industrial levels (at ∼1.6 μmol L−1) and an absence of methyl hydroperoxide (down to a detection threshold of 0.003 μmol L−1). Formaldehyde levels show a 40% increase from pre-industrial to modern times (rising from ∼0.07 μmol L−1 to ∼0.10 μmol L−1), with a further increase and possible seasonality near the surface which we associate with post-depositional processes. Peroxide levels in LGM ice are low, but formaldehyde concentrations are high (at ∼0.13 μmol L−1) relative to modern levels. Similar high levels of formaldehyde are seen in early Holocene ice (∼6900 years BP).

We have used ground-based radio-echo sounding (RES) profiles to reveal the spatial distribution of basal and internal ice properties across Siple Dome, West Antarctica, and under the dormant ice streams on its flanks. The RES-detected bed-reflection power, corrected for the effects of instrumentation and ice-thickness variation, is nearly constant across Siple Dome at a value suggesting spatially homogeneous basal properties of ice frozen to bedrock. Till, if present under the dome, must be thin (<0.1 m). The high basal reflectivity measured under now dormant “Siple Ice Stream” (SIS) and Ice Stream C suggests that they are underlain by either a thin (<0.05 m) water layer or a thick (>1 m) thawed or frozen till layer. The evidence that the dormant SIS is not frozen directly to underlying bedrock (but is separated by a water or till layer) is a further indication that it was once an active ice stream, and suggests that streaming motion may have ceased before the basal layer was frozen. The absence of a thick till layer beneath Siple Dome is consistent with its apparent stability as an inter-ice-stream ridge in the past and may suggest that it will remain as a stable limitation of ice-stream width in the future.