Skip to main content Accessibility help
×
Hostname: page-component-8448b6f56d-c47g7 Total loading time: 0 Render date: 2024-04-23T07:44:45.760Z Has data issue: false hasContentIssue false

14 - Polaronic theory of mid-infrared conductivity: a numerical cluster study

Published online by Cambridge University Press:  24 November 2009

A. S. Alexandrov
Affiliation:
IRC in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 OHE, UK
V. V. Kabanov
Affiliation:
Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France
D. K. Ray
Affiliation:
Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France
E. K. H. Salje
Affiliation:
University of Cambridge
A. S. Alexandrov
Affiliation:
University of Cambridge
W. Y. Liang
Affiliation:
University of Cambridge
Get access

Summary

Abstract

The observed characteristics of mid infrared (MIR) spectra in doped semiconductors are discussed. These characteristics were explained by Reik and coworkers on the basis of hopping motion of small polarons from a localized site to a neighbouring localized site. The success and limitations of this model are pointed out. Emin, on the other hand, showed the importance of large polarons for the conductivity. The recently observed features of MIR spectra in high-Tc cuprates are then summarized. The low-frequency peak in many cuprates with frequency 0.1−0.2 eV has been ascribed by many investigators to polaronic origin. We have undertaken in the present work numerical studies of polaronic conductivity in the two-site and four-site cluster model by diagonalization of the dynamical matrix. Broadening of the phonon spectra due to damping has been taken into account by considering a small but finite phonon lifetime. For intermediate and strong coupling, a number of peaks in the optical conductivity appear due to bound states with different numbers of phonons. We have also studied the importance of Hubbard U by calculating the optical conductivity as a function of U with two electrons in a two-site model. The experimental results of MIR spectra for the cuprates can be better understood on the basis of the present calculations.

Introduction

It was Landau who first introduced the idea of polarons for explaining the F centres in NaCl as due to self-trapping of electrons [1]. Polarons are the quasiparticles formed by the accompanying self-consistent polarization field and are generated due to the dynamical electron–phonon interaction. As a consequence there is extra scattering of the charge carriers, phonon energies are renormalized and the charge carriers are heavy [2].

Type
Chapter
Information
Publisher: Cambridge University Press
Print publication year: 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Save book to Kindle

To save this book to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

  • Polaronic theory of mid-infrared conductivity: a numerical cluster study
    • By A. S. Alexandrov, IRC in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 OHE, UK, V. V. Kabanov, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France, D. K. Ray, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France
  • Edited by E. K. H. Salje, University of Cambridge, A. S. Alexandrov, University of Cambridge, W. Y. Liang, University of Cambridge
  • Book: Polarons and Bipolarons in High-Tc Superconductors and Related Materials
  • Online publication: 24 November 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511599811.015
Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

  • Polaronic theory of mid-infrared conductivity: a numerical cluster study
    • By A. S. Alexandrov, IRC in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 OHE, UK, V. V. Kabanov, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France, D. K. Ray, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France
  • Edited by E. K. H. Salje, University of Cambridge, A. S. Alexandrov, University of Cambridge, W. Y. Liang, University of Cambridge
  • Book: Polarons and Bipolarons in High-Tc Superconductors and Related Materials
  • Online publication: 24 November 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511599811.015
Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • Polaronic theory of mid-infrared conductivity: a numerical cluster study
    • By A. S. Alexandrov, IRC in Superconductivity, University of Cambridge, Madingley Road, Cambridge CB3 OHE, UK, V. V. Kabanov, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France, D. K. Ray, Laboratoire des Propriétés Mécaniques et Thermodynamiques des Matériaux, CNRS Université Paris-Nord, 93430 Villetaneuse, France
  • Edited by E. K. H. Salje, University of Cambridge, A. S. Alexandrov, University of Cambridge, W. Y. Liang, University of Cambridge
  • Book: Polarons and Bipolarons in High-Tc Superconductors and Related Materials
  • Online publication: 24 November 2009
  • Chapter DOI: https://doi.org/10.1017/CBO9780511599811.015
Available formats
×